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Unimolecular Precursors to Binary Metal Sulfides: Mechanistic and Structural Correlations

Published online by Cambridge University Press:  10 February 2011

Rodney D. Schluter
Affiliation:
School of Chemistry and Biochemistry, School of Materials Science and Engineering, and the Molecular Design Institute, Georgia Institute of Technology, Atlanta, GA 30332-0400
Gertrude Kräuter
Affiliation:
School of Chemistry and Biochemistry, School of Materials Science and Engineering, and the Molecular Design Institute, Georgia Institute of Technology, Atlanta, GA 30332-0400
William S. Rees Jr
Affiliation:
School of Chemistry and Biochemistry, School of Materials Science and Engineering, and the Molecular Design Institute, Georgia Institute of Technology, Atlanta, GA 30332-0400
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Abstract

The roles which ligand size and stability play in influencing solid-state thermolyses products and phases are developed for a group of metal thiolate compounds. The exploration includes Pb(SR)2 [R = t-Bu, i-Bu, s-Bu], Cd(SR*)2 [ R* = i-Pr, I-Bu, Bz], ClHgSR** [ R** = i- Pr, neo-Pent, Bz] and In(SR***)3 [R*** = 2,4,6-(i-Pr)3C6H2, 2-CH3O-5-CH3C6H3, o- C6H4CH2N(CH3)2]. In several examples, the precursors have been characterized by single crystal X-ray diffraction. In most cases, solid-state decomposition products have been identified by XRPD, and volatile decomposition products have been identified by GC/MS. All precursors have been studied by TGA.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

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References

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