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V2O5 Nanorods with Improved Cycling Stability for Li Intercalation

Published online by Cambridge University Press:  31 January 2011

Alexey M Glushenkov ,
Vladimir I. Stukachev ,
Mohd Faiz Hassan ,
Gennady G. Kuvshinov ,
Hua Kun Liu  and
Ying Ian Chen
Alexey M Glushenkov
Affiliation:
alexey.glushenkov@deakin.edu.au, Deakin University, Institute for Technology Reaseach and Innovation, Geelong, Victoria, Australia
Vladimir I. Stukachev
Affiliation:
vovkne@mail.ru, Novosibirsk State Technical University, Department of Chemical Engineering, Novosibirsk, Russian Federation
Mohd Faiz Hassan
Affiliation:
mfh125@uow.edu.au, University of Wollongong, Institute for Superconducting and Electronic Materials, Wollongong, New South Wales, Australia
Gennady G. Kuvshinov
Affiliation:
kuvshinov_g@mail.ru, Novosibirsk State Technical University, Department of Chemical Engineering, Novosibirsk, Russian Federation
Hua Kun Liu
Affiliation:
hua@uow.edu.au, University of Wollongong, Institute for Superconducting and Electronic Materials, Wollongong, New South Wales, Australia
Ying Ian Chen
Affiliation:
ian.chen@deakin.edu.au, Deakin University, Institute for Technology Research and Innovation, Waurn Ponds, Victoria, Australia
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Abstract

We have recently reported a solid-state, mass-quantity transformation from V2O5 powders to nanorods via a two-step approach [1]. In this paper we present detailed investigation of the growth process using x-ray diffraction, scanning/transmission electron microscopy and electron spin resonance. The growth of nanorods at intermediate stages has been examined. Oxidation, surface energy minimization and surface diffusion play important roles in the growth mechanism.

Keywords

crystal growthnanostructureenergy storage
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1170: Symposium R – Materials for Renewable Energy at the Society and Technology Nexus , 2009 , 1170-R06-03
Copyright
Copyright © Materials Research Society 2009

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References

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