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Wetting Pattern on TiO2 Nanostructure Films and its Application as a Template for Selective Materials Growth

  • Y. K. Lai (a1) (a2), Y. Yang (a2), Y. X. Huang (a2), Z. Q. Lin (a2), Y. X. Tang (a1), D. G. Gong (a1), C. J. Lin (a2) and Z. Chen (a1)...


The present paper describes an unconventional approach to fabricate superhydrophilic-superhydrophobic template on the TiO2 nanotube structured film by a combination of electrochemical anodization and photocatalytic lithography. Based on template with extreme wetting contrast, various functional nanostructures micropattern with high resolution have been successfully fabricated. The resultant micropattern has been characterized with scanning electron microscopy, optical microscopy, X-ray photoelectron spectroscopy. It is shown that functional nanostructures can be selectively grown at superhydrophilic areas which are confined by the hydrophobic regions, indicating that the combined process of electrochemically self-assembly and photocatalytic lithography is a very promising approach for constructing well-defined templates for various functional materials growth.



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1. Wang, R., Hashimoto, K., Fujishima, A., Chikuni, M., Kojima, E., Kitamura, A., Shimohigoshi, M., and Watanabe, T., Nature 388, 431 (1997).
2. Ichimura, K., Oh, S.K., and Nakagawa, M., Science 288, 1624 (2000).
3. Lai, Y.K., Gao, X.F., Zhuang, H.F., Huang, J.Y., Lin, C.J., and Jiang, L., Adv. Mater. 21, 3799 (2009).
4. Gao, X.F., and Jiang, L., Nature 432, 36 (2004).
5. Lafuma, A., and Quéré, D., Nat. Mater. 2, 457 (2003).
6. Liu, X.J., Ye, Q.A., Yu, B., Liang, Y.M., Liu, W.M., and Zhou, F., Langmuir 26, 12377 (2010).
7. Kumar, A., Biebuyck, H.A., Abbott, N.L., and Whitesides, G.M., J. Am. Chem. Soc. 114, 9188 (1992).
8. Yang, Y., Lai, Y.K., Zhang, Q.Q., Wu, K., Zhang, L.H., Lin, C.J., and Tang, P.F., Colloids Surf. B 79, 309 (2010).
9. Lai, Y.K., Chen, Y.C., Tang, Y.X., Gong, D.G., Chen, Z., and Lin, C.J., Electrochem. Commun. 11, 2268 (2009).
10. Jae, P.L., and Myung, M.S., J. Am. Chem. Soc. 126, 28 (2004).
11. Xu, S., and Liu, G.Y., Langmuir 13, 127 (1997).
12. Zhang, X.T., Sato, O., and Fujishima, A., Langmuir 20, 6065 (2004).
13. Teshima, K., Sugimura, H., Takano, A., Inoue, Y., and Takai, O., Chem. Vapor Depos. 11, 347 (2005).
14. Tadanaga, K., Morinaga, J., Matsuda, A., and Minami, T., Chem. Mater. 12, 590 (2000).
15. Balaur, E., Macak, J.M., Taveira, L., and Schmuki, P., Electrochem. Commun. 7, 1066 (2005).
16. Zhao, J.C., Wu, T.X., Wu, K.Q., Oikawa, K., Hidaka, H., and Serpone, N., Environ. Sci. Technol. 32, 2394 (1998).
17. Lai, Y.K., Sun, L., Chen, Y.C., Zhuang, H.F., Lin, C.J., and Chin, J.W., J. Electrochem. Soc. 153, D123 (2006).
18. Zhuang, H.F., Lin, C.J., Lai, Y.K., Sun, L., and Li, J., Environ. Sci. Technol. 41, 4735 (2007).
19. Li, F.B., and Li, X.Z., Appl. Catal. A 228, 15 (2002).
20. Sirghi, L., Nakamura, M., Hatanaka, Y., and Takai, O., Langmuir 17, 8199 (2001).
21. Yoshitake, H., Sugihara, T., and Tatsumi, T., Chem. Mater. 14, 1023 (2002).
22. Foong, T.R.B., Shen, Y.D., Hu, X., and Sellinger, A., Adv. Funct. Mater. 20, 1390 (2010).
23. Zwilling, V., Aucouturier, M., and Darque-Ceretti, E., Electrochim. Acta 45, 921 (1999).
24. Gong, D.W., Grimes, C.A., and Varghese, O.K., J. Mater. Res. 16, 3331 (2001).
25. Lai, Y.K., Zhuang, H.F., Xie, K.P., Gong, D.G., Tang, Y.X., Sun, L., Lin, C.J., and Chen, Z., New J. Chem. 34, 1335 (2010).
26. Lai, Y.K., Huang, J.Y., Zhuang, H.F., Subramaniam, V.P., Tang, Y.X., Gong, D.G., Sundar, L., Sun, L., Chen, Z., and Lin, C.J., J. Hazard. Mater. 184, 855 (2010).
27. Lin, Z.Q., Lai, Y.K., Hu, R.G., Li, J., Du, R.G., and Lin, C.J., Electrochim. Acta 55, 8717 (2010).
28. Lai, Y.K., Sun, L., Chen, C., Nie, C.G., Zuo, J., and Lin, C. J., Appl. Surf. Sci. 252, 1101 (2005).
29. Lai, Y.K., Lin, C.J., Huang, J.Y., Zhuang, H.F., Sun, L., and Nguyen, T., Langmuir 24, 3867 (2008).
30. Lai, Y.K., Lin, C.J., Wang, H., Huang, J.Y., Zhuang, H.F., and Sun, L., Electrochem. Commun. 10, 387 (2008).
31. Hu, R., Lin, C.J., and Shi, H.Y., J. Biomed. Mater. Res. Part A 80, 687 (2007).
32. Wang, H., Lin, C.J., and Hu, R., Appl. Surf. Sci. 255, 4074 (2009).
33. Lai, Y.K., Huang, J.Y., Gong, J.J., Huang, Y.X., Wang, C.L., Chen, Z., and Lin, C.J., J. Electrochem. Soc. 156, D480 (2009).
34. Lai, Y.K., Zhuang, H.F., Sun, L., Chen, Z., and Lin, C.J., Electrochim. Acta 54, 6536 (2009).
35. Lee, J.P., Kim, H.K., Park, C.R., Park, G., Kwak, H.T., Koo, S.M., and Sung, M.M., J. Phys. Chem. B 107, 8997 (2003).
36. Lai, Y.K., Lin, Z.Q., Huang, J.Y., Sun, L., Chen, Z., and Lin, C.J., New J. Chem. 34, 44 (2010).
37. Yasuda, K., Macak, J.M., Berger, S., Ghicov, A., and Schmuki, P., J. Electrochem. Soc. 154, C472 (2007).
38. Lai, Y.K., Lin, Z.Q., Chen, Z., Huang, J.Y., and Lin, C.J., Mater. Lett. 64, 1309 (2010).
39. Huang, Y.X., Lai, Y.K., Lin, L.X., Sun, L., and Lin, C.J., Acta Phys. -Chim. Sin. 26, 2057 (2010).
40. Lai, Y.K., Huang, Y.X., Huang, J.Y., Wang, H., Chen, Z., and Lin, C.J., Colliods Surf. B 76, 117 (2010)



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