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Synthesis and X-ray diffraction data of dichloro-dioxido-(4,4′-dimethyl-2,2′-bipyridyl) molybdenum (VI)

Published online by Cambridge University Press:  20 February 2023

Jose L. Pinto ,
Hernando Camargo  and
Nelson J. Castellanos Open the ORCID record for Nelson J. Castellanos [Opens in a new window]
Jose L. Pinto
Affiliation:
Grupo de Investigación de Materiales de Interés Geológico y Geotécnico, Dirección de Laboratorios, Servicio Geológico Colombiano SGC, Diagonal 53 No. 34-53, Bogotá́, Colombia
Hernando Camargo
Affiliation:
Grupo de Investigación de Materiales de Interés Geológico y Geotécnico, Dirección de Laboratorios, Servicio Geológico Colombiano SGC, Diagonal 53 No. 34-53, Bogotá́, Colombia
Nelson J. Castellanos*
Affiliation:
Laboratorio de Diseño y Reactividad de Estructuras Sólidas (Lab-DRES, 125), Departamento de Química, Facultad de Ciencias, Universidad Nacional de Colombia, Carrera 30 No. 45-03, Bogotá́ 111321, Colombia
*
a)Author to whom correspondence should be addressed. Electronic mail: njcastellanosm@unal.edu.co
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Abstract

The dichloro-dioxide-(4,4′-dimethyl-2,2′-bipyridyl)-molybdenum (VI) complex was prepared from molybdenum(VI)-dichloride-dioxide and 4,4′-dimethyl-2,2′-bipyridyl in CH2Cl2 obtaining a clear green solution. The molybdenum complex was precipitated using ethyl ether, separated by filtration and the light green solid washed with ethyl ether. The XRPD pattern for the new compound showed that the crystalline compound belongs to the monoclinic space group P21/n (No.14) with refined unit-cell parameters a = 12.0225(8) Å, b = 10.3812(9) Å, c = 11.7823(9) Å, β = 103.180(9)°, unit-cell volume V = 1431.79 Å3, and Z = 4.

Keywords

dioxomolybdenum (VI) complexX-ray powder diffractionbiomimetic compounds
Type
New Diffraction Data
Information
Powder Diffraction , Volume 38 , Issue 2 , June 2023 , pp. 152 - 157
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Copyright
Copyright © The Author(s), 2023. Published by Cambridge University Press on behalf of International Centre for Diffraction Data

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