Hostname: page-component-76fb5796d-22dnz Total loading time: 0 Render date: 2024-04-27T06:40:02.923Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and XRPD studies of new barium dicarboxylates

Published online by Cambridge University Press:  05 March 2012

M. Grzesiak ,
A. Rafalska-Łasocha  and
W. Łasocha
M. Grzesiak
Affiliation:
Catalysis and Surface Chemistry, PAS, ul. Niezapominajek 8, 30-329 Krakow, Poland
A. Rafalska-Łasocha
Affiliation:
Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Krakow, Poland
W. Łasocha*
Affiliation:
Faculty of Chemistry, Jagiellonian University, ul. Ingardena 3, 30-060 Krakow, Poland and Institute of Catalysis and Surface Chemistry, PAS, ul. Niezapominajek 8, 30-239 Krakow, Poland
*
a)Author to whom correspondence should be addressed. Electronic mail: lasocha@chemia.uj.edu.pl
Get access Rights & Permissions [Opens in a new window]

Abstract

New salts of barium with dicarboxylic acids (glutaric, adipic, pimelic, suberic, sebacic, and dodecanedioic) were synthesized and characterized by powder diffraction techniques. In addition to the basic crystallographic data and chemical analyses of barium glutarate hexahydrate {1}, barium adipate {2}, barium pimelate {3}, barium disuberate {4}, barium sebacate {5}, and barium dodecanedioate {6}, the processes of their thermal decomposition were investigated by XRPD. All the compounds decompose to barium carbonate at temperatures between 400 and 500 °C.

Keywords

XRPDhigh-temperature XRPDindexing of powder pattern
Type
New Diffraction Data
Information
Powder Diffraction , Volume 26 , Issue 1 , March 2011 , pp. 53 - 65
Copyright
Copyright © Cambridge University Press 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Borkowski, L. A. and Cahill, C. L. (2006). “Crystal engineering with the uranyl cation I. Aliphatic carboxylate coordination polymers: Synthesis, crystal structures, and fluorescent properties,” Cryst. Growth Des.CGDEFU 6 (10), 2241–2247.10.1021/cg060329hCrossRefGoogle Scholar
de Wolff, P. M. (1968). “A simplified criterion for the reliability of a powder pattern indexing,” J. Appl. Crystallogr.JACGAR 1, 108–113.10.1107/S002188986800508XCrossRefGoogle Scholar
Grzesiak, M., Nitek, W., and Łasocha, W. (2011). “New barium dicarboxylates crystal structures and selected properties,” Z. Krystallogr. (submitted).Google Scholar
Łasocha, W. and Lewiński, K. (1994). “PROSZKI—A system of programs for powder diffraction data analysis,” J. Appl. Crystallogr.JACGAR 27, 437–438.10.1107/S002188989400066XCrossRefGoogle Scholar
Smith, G. S. and Snyder, R. L. (1979). “FN: A criterion for rating powder diffraction patterns and evaluating the reliability of powder-pattern indexing,” J. Appl. Crystallogr.JACGAR 12, 60–65.10.1107/S002188987901178XCrossRefGoogle Scholar
Sonneveld, E. J. and Visser, J. W. (1975). “Automatic collection of powder data from photographs,” J. Appl. Crystallogr.JACGAR 8, 1–7.10.1107/S0021889875009417CrossRefGoogle Scholar