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X-ray diffraction data for the new ferroelectric tetragonal tungsten bronze phases, Ba2RETi2M3O15:M=Nb and RE=La, Pr, Nd, Sm, Gd, Dy, (Bi);M=Ta and RE=La, Nd

Published online by Cambridge University Press:  01 March 2012

Gabrielle C. Miles ,
Martin C. Stennett ,
David Pickthall ,
Caroline A. Kirk ,
Ian M. Reaney  and
Anthony R. West
Gabrielle C. Miles
Affiliation:
Department of Engineering Materials, The University of Sheffield, Mappin Street, Sheffield, S1 3JD, United Kingdom
Martin C. Stennett
Affiliation:
Department of Engineering Materials, The University of Sheffield, Mappin Street, Sheffield, S1 3JD, United Kingdom
David Pickthall
Affiliation:
Department of Engineering Materials, The University of Sheffield, Mappin Street, Sheffield, S1 3JD, United Kingdom
Caroline A. Kirk
Affiliation:
Department of Engineering Materials, The University of Sheffield, Mappin Street, Sheffield, S1 3JD, United Kingdom
Ian M. Reaney
Affiliation:
Department of Engineering Materials, The University of Sheffield, Mappin Street, Sheffield, S1 3JD, United Kingdom
Anthony R. West
Affiliation:
Department of Engineering Materials, The University of Sheffield, Mappin Street, Sheffield, S1 3JD, United Kingdom
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Abstract

X-ray powder diffraction data are presented for nine new phases with the tetragonal tungsten bronze structure. By comparison with the structure of the M=Nb,RE=La analogue, these contain Ba in the large pentagonal sites with coordination number 15, a range of large rare-earth cations and Bi in the twelve coordinate sites, and the smaller cations, Ti and either Nb or Ta, in the octahedral framework sites. The a lattice parameter data of the tetragonal unit cell show an approximately linear variation with trivalent ion radius, apart from Dy, whose value appears to be anomalous; data for c show little variation with trivalent ion radius.

Type
New Diffraction Data
Information
Powder Diffraction , Volume 20 , Issue 1 , March 2005 , pp. 43 - 46
Copyright
Copyright © Cambridge University Press 2005

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References

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