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X-ray diffraction studies of solid solutions of Cr-, Mn-, Fe-, Co-, and Ni-containing transition metal spinel oxides

Published online by Cambridge University Press:  10 January 2013

G. C. Allen ,
K. R. Hallam  and
J. A. Jutson
G. C. Allen
Affiliation:
University of Bristol, Interface Analysis Centre, Oldbury House, 121 St Michael's Hill, Bristol BS2 8BS, England
K. R. Hallam
Affiliation:
University of Bristol, Interface Analysis Centre, Oldbury House, 121 St Michael's Hill, Bristol BS2 8BS, England
J. A. Jutson
Affiliation:
BICC Cables Ltd, Wrexham Technology Centre, Wrexham, Clwyd LL13 9XP, Wales
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Abstract

A wide range of transition metal oxide solid solutions have been prepared and characterised using powder X-ray diffraction (MnxCo1−xFe2O4, FexCo1−xFe2O4, NixCo1−xFe2O4, FeFexCr2−xO4, MnFexCr2−xO4, MnxFe1−xCr2O4, MnxFe1−xFe2O4, NixFe1−xFe2O4). Calibration curves have been obtained relating oxide composition to unit cell parameter or d spacing. From these curves it is possible to identify the composition of oxides formed on steel surfaces in varied industrial environments. Even when poor diffraction patterns are obtained and little sample is available, an estimate of composition can be made.

Keywords

transition metal oxidespinelsteel oxidationcalibration curve
Type
Research Article
Information
Powder Diffraction , Volume 10 , Issue 3 , September 1995 , pp. 214 - 220
Copyright
Copyright © Cambridge University Press 1995

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References

Allen, G. C., and Jutson, J. A. (1989). “Effect of Spinel Oxide Composition on Rate of Carbon Deposition,” J. Chem. Soc, Faraday Trans., 1, 85(1), 55–64.CrossRefGoogle Scholar
Allen, G. C., and Jutson, J. A. (1990). “Carbon Deposition on Nickel Ferrites and Nickel-Magnetite Surfaces,” J. Chem. Soc, Faraday Trans., 86(5), 867–873.CrossRefGoogle Scholar
Allen, G. C., Jutson, J. A., and Tempest, P. A. (1988). “Characterisation of Nickel-Chromium-Iron Spinel-Type Oxides,” J. Nuclear. Mat. 158, 96–107.CrossRefGoogle Scholar
Di Cerbo, R. K., and Seybolt, A. G. (1959). “Lattice Parameters of the X-Fe2O3-Cr2O3 Solid Solution,” J. Am. Ceram. Soc. 42, 430–431.CrossRefGoogle Scholar
JCPDS (1980). International Centre for Diffraction Data, Newtown Square, Pennsylvania, USA.Google Scholar
Pickart, S. J., and Nathans, R. (1959). “Neutron Study of the Crystal and Magnetic Structures of MnFe2−tCrtO4,” Phys. Rev. 116, 317–322.CrossRefGoogle Scholar
Tempest, P. A. (1977). “The Influence of Specimen Absorption and Beam Divergence on the Accurate Determination of Lattice Parameters by the Debye-Scherrer Method,” J. Appl. Cryst. 10, 238–246.CrossRefGoogle Scholar
Yearian, H. J., Kortright, J. M., and Langenheim, R. H. (1954). “Lattice Parameters of the FeFe(2−x))CrxO4 Spinel System,” J. Chem. Phys. 22, 1196–1198.CrossRefGoogle Scholar