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X-ray powder diffraction data for some transition metal phosphites and hypophosphites

Published online by Cambridge University Press:  10 January 2013

M. Dolores Marcos ,
Pedro Amorós ,
Daniel Beltrán  and
Aurelio Beltrán
M. Dolores Marcos
Affiliation:
UIBCM, Departament de Química Inorgánica, Facultat de Químiques, Universitat de València, Dr. Moliner n°50, 46100-Burjassot (València), Spain
Pedro Amorós
Affiliation:
UIBCM, Departament de Química Inorgánica, Facultat de Químiques, Universitat de València, Dr. Moliner n°50, 46100-Burjassot (València), Spain
Daniel Beltrán
Affiliation:
UIBCM, Departament de Química Inorgánica, Facultat de Químiques, Universitat de València, Dr. Moliner n°50, 46100-Burjassot (València), Spain
Aurelio Beltrán
Affiliation:
UIBCM, Departament de Química Inorgánica, Facultat de Químiques, Universitat de València, Dr. Moliner n°50, 46100-Burjassot (València), Spain
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Abstract

A set of nine transition metal oxophosphorous compounds, consisting of four hypophosphites and five phosphites has been synthesized and studied using X-ray powder diffraction techniques. The compounds are α-Mn(H2PO2)2·H2O, Co(H2PO2)2 ·0.53H2O, MCl(H2PO2)2·H2O (M = Co2+, Ni2+), M2(HPO3)2·2H2O (M = Co2+, Ni2+), and M11 (HPO3)8(OH)6 (M = Zn2+, Co2+, Ni2+). Unit cells and X-ray powder patterns are reported.

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Type
Research Article
Information
Powder Diffraction , Volume 9 , Issue 1 , March 1994 , pp. 15 - 20
Copyright
Copyright © Cambridge University Press 1994

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