The SIM (Planet Quest) mission is a space-based long-baseline stellar interferometer designed for ultra-precise astrometry. This paper describes how SIM can be used for double star research. There are several regimes of operation. For binary stars separated by more than 1″.5, SIM treats these as distinct objects. Double stars less than ∼10 milliarcsec in separation are seen as a single object and SIM measures the photocenter of the composite object. Between 10 mas and 1″.15, SIM is able to see the double star as two distinct objects, but because photons from both stars are detected there is the possibility of increased noise and measurement bias. This paper describes how double stars are observed with SIM and what information can be derived.