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Depositional Processes of Organic Matter in the Rhône River Delta (Gulf of Lions, France) Traced by Density Fractionation Coupled with Δ14C and δ13C

Published online by Cambridge University Press:  09 February 2016

Flora Toussaint*
Affiliation:
Laboratoire des Sciences du Climat et de l'Environnement UMR 8212, CEA-CNR-UVSQ Gif-sur-Yvette, France
Nadine Tisnérat-Laborde
Affiliation:
Laboratoire des Sciences du Climat et de l'Environnement UMR 8212, CEA-CNR-UVSQ Gif-sur-Yvette, France
Cécile Cathalot
Affiliation:
Laboratoire des Sciences du Climat et de l'Environnement UMR 8212, CEA-CNR-UVSQ Gif-sur-Yvette, France
Roselyne Buscail
Affiliation:
Centre de Formation et de Recherche sur les Environnements Méditerranéens, UMR 5110, CNRS, Perpignan, France
Philippe Kerhervé
Affiliation:
Centre de Formation et de Recherche sur les Environnements Méditerranéens, UMR 5110, CNRS, Perpignan, France
Christophe Rabouille
Affiliation:
Laboratoire des Sciences du Climat et de l'Environnement UMR 8212, CEA-CNR-UVSQ Gif-sur-Yvette, France
*
2Corresponding author. Email: flora.toussaint@lsce.ipsl.fr.

Abstract

As a main source of freshwater and particles, the Rhône River plays a major role in the biogeochemical cycle of organic carbon (OC) in the Mediterranean Sea. To better understand the origin of organic matter and the processes leading to its export to the coastal sea near the Rhône River, we measured radiocarbon (Δ14C) and stable carbon isotopes (δ13C) in the sediments of the delta, after density fractionation. In April 2007, 3 sites located along an offshore transect (A, C, and E) were sampled for surface sediments, and bulk sediment was separated into 4 fractions of different densities (<1.6, 1.6–2, 2–2.5, and >2.5 g cm−3). In order to better understand the evolution of the OC along the transect, we investigated the OC sources and their evolution for each density fraction. Bulk OC shows a large increase in δ13C from −27.2′ nearshore to −24.5′ at offshore stations while Δ14C decreased from 59′ to −320′. The distribution of δ13C with density displayed a convex pattern at all stations. Except for fraction >2.5 g cm−3, δ13C increases by 2.5′ between stations A and E, indicating a loss of terrestrial signature. The distribution of Δ14C versus density had a concave pattern at all stations: at a single station, it showed a large heterogeneity with a difference of 500–600′ between the <1.6 and 2–2.5 g cm−3 fractions. A decrease in Δ14C of −400′ among the different density fractions was observed along the offshore transect. The density fraction >2.5 g cm−3 had less variability, with an average δ13C of −24.6 ± 0.4′ and Δ14C of −370 ± 115′. Several processes may explain this distribution: retention in the prodelta of large particles; mineralization of all fractions during the transport and deposition in the delta and shelf sediments; and dilution of terrestrial particles in continental shelf pool.

Type
Articles
Copyright
Copyright © 2013 by the Arizona Board of Regents on behalf of the University of Arizona 

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