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AMS-14C determination of the biogenic-fossil fractions in flue gases

  • Gianluca Quarta (a1), Lucio Calcagnile (a1), Domenico Cipriano (a2), Marisa D’Elia (a1), Lucio Maruccio (a1), Giovanni Ciceri (a2) and Valter Martinotti (a2)...
Abstract

The determination of the proportion between the biogenic and the fossil-derived fraction in carbon dioxide emissions from industrial stationary sources is a relevant aspect in the frame of the worldwide efforts to reduce greenhouse gas emissions into the atmosphere. In this field the 14C-based method has gained importance over the years and has been included in standard protocols accepted at both the national and international levels. The advantages of the method, based on the large difference in terms of 14C signature between fossil and biogenic carbon, are reviewed as well as some critical aspects related to its application. In particular the results of a study aimed at validating the method by analyzing synthetic gas mixtures produced in a dedicated plant and with a tuneable proportion between fossil and biogenic carbon dioxide are presented.

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*Corresponding author. Email: gianluca.quarta@unisalento.it.
References
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Calcagnile, L, Quarta, G, D’Elia, M, Rizzo, A, Gottdang, A, Klein, M, Mous, DJW. 2004. A new accelerator mass spectrometry facility in Lecce, Italy. Nuclear Instruments and Methods in Physics Research B 223–224:1620.
Calcagnile, L, Quarta, G, D’Elia, M. 2005. High resolution accelerator-based mass spectrometry: precision, accuracy and background. Applied Radiation and Isotopes 62(4):623629.
Calcagnile, L, Quarta, G, D’Elia, M, Ciceri, G, Martinotti, W. 2011. Radiocarbon AMS determination of the biogenic component in CO2 emitted from waste incineration. Nuclear Instruments and Methods in Physics Research B 269:31583162.
Cipriano, D, Fialdini, L, Guandalini. 2015. Campagne sperimentali (intercomparison) su test facility Loop per lo sviluppo e la validazione di metodi di misura alle emissioni, Ricerca sul Sistema Energetico – RSE S.p.A. p 1–86 (available at: http://doc.rse-web.it/doc/doc-sfoglia/15000902-316079/15000902-316079.html)
D’Elia, M, Calcagnile, L, Quarta, G, Rizzo, A, Sanapo, C,Laudisa, M, Toma, U, Rizzo, A. 2004. Sample preparation and blank values at the AMS radiocarbon facility of the University of Lecce. Nuclear Instruments and Methods in Physics Research B 223–224:278283.
European Union. 2008. Communication from the Commission to the European Parliament, the Council, the European Economic and Social Committee and the Committee of the Regions, 20 20 by 2020 Europe’s Climate Change Opportunity, Brussels.
Hämäläinen, KM, Jungner, H, Antson, O, Räsänen, J, Tormonen, K, Roine, J. 2007. Measurement of biocarbon in flue gases using 14C. Radiocarbon 49(2):325330.
International Organisation for Standardisation, ISO 13833:2013. 2013. Stationary source emissions -- Determination of the ratio of biomass (biogenic) and fossil-derived carbon dioxide -- Radiocarbon sampling and determination. p 1–36
Jou, RM, Macario, KD, Carvalho, C, Dias, RS, Brum, MC, Cunha, FR, Ferreira, CG, Chanca, IS. 2015. Biogenic fraction in the synthesis of polyethylene terephthalate. International Journal of Mass Spectrometry 388:6568.
Mohn, J, Szidat, S, Fellner, J, Rechberger, H, Quartier, R, Buchmann, B, Emmenegger, L. 2008. Determination of biogenic and fossil CO2 emitted by waste incineration based on 14CO2 and mass balances. Bioresour. Technol. 99(14):64716479.
Palstra, SWL, Meijer, HAJ. 2010. Carbon-14 based determination of the biogenic fraction of industrial CO2 emissions – application and validation. Bioresource Technology 101(10):37023710.
Palstra, SWL, LPLM, Rabou, Meijer, HAJ. 2015. Radiocarbon-based determination of biogenic and fossil carbon partitioning in the production of synthetic natural gas. Fuel 157:177182.
Quarta, G, Ciceri, G, Martinotti, V, D’Elia, M, Calcagnile, L. 2015. Bringing AMS radiocarbon into the Anthropocene: Potential and drawbacks in the determination of the bio-fraction in industrial emissions and in carbon-based products. Nuclear Instruments and Methods in Physics Research B 361(15):521555.
Quarta, G, Calcagnile, L, Giffoni, M, Braione, E, D’Elia, M. 2013. Determination of the biobased content in plastics by radiocarbon. Radiocarbon 55(2–3): 18341844.
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Radiocarbon
  • ISSN: 0033-8222
  • EISSN: 1945-5755
  • URL: /core/journals/radiocarbon
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