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Evaluation of Sample Preparation Protocols for the 14C Dating of Tupiguarani Pottery in Southeastern Brazil

  • Fabiana M Oliveira (a1), Kita D Macario (a1), Bruna B Pereira (a1), Angela Buarque (a2), David Chivall (a3), Eduardo Q Alves (a3) and Christopher Bronk Ramsey (a3)...

This study evaluates the radiocarbon dating of ceramic samples from Tupiguarani sites in Brazil, a settlement type dating up to 3000 cal BP. In this work, residues from ceramic samples from four archaeological sites in Rio de Janeiro (Morro Grande, Serrano, Barba Couto, and Bananeiras) were analyzed. In order to identify the most suitable sample preparation protocols, the humic fraction was isolated from the bulk material at the Oxford Radiocarbon Accelerator Unit (ORAU), whereas the acid-base-acid (ABA) residue fraction method was applied at the Radiocarbon Laboratory of the Fluminense Federal University (LAC-UFF). The dating results were compared to the current knowledge about the occupational periods of the sites. For the Morro Grande site, the results of humic and ABA residue fractions show a difference of more than 1500 yr. For the Serrano site, the 14C ages obtained from the two pretreatments are identical, and as with the Barba Couto and Bananeiras sites, indicate an occupation during the Brazilian colonial period of the 16th century AD and are compatible with the archaeological data.

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Selected Papers from the 2015 Radiocarbon Conference, Dakar, Senegal, 16–20 November 2015

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Batten, RJ, Gillespie, R, Gowlett, JAJ, Hedges, REM. 1986. The AMS dating of separate fractions in archaeology. Radiocarbon 28(2A):698701.
Beauclair, M, Scheel-Ybert, R, Bianchini, GF, Buarque, A. 2009. Fire and ritual: bark hearths in South-American Tupiguarani mortuary rites. Journal of Archaeological Science 36(7):14091415.
Boaretto, E, Wu, X, Yuan, J, Bar-Yosef, O, Chu, V, Pan, Y, Liu, K, Cohen, D, Jiao, T, Li, S, Gu, H, Goldberg, P, Weiner, S. 2009. Radiocarbon dating of charcoal and bone collagen associated with early pottery at Yuchanyan Cave, Hunan Province, China. Proceedings of the National Academy of Sciences of the USA 106(24):95959600.
Bonsall, C, Cook, G, Manson, J, Sanderson, D. 2002. Direct dating of Neolithic pottery: progress and prospects. Documenta Praehistorica 29:4759.
Brochado, JP. 1973. Migraciones que difundieran la Tradición Alfarera Tupiguarani. Relaciones, Sociedad Argentina de Antropología, Buenos Aires 7(a):739.
Brock, F, Higham, T, Ditchfield, P, Bronk Ramsey, C. 2010. Current pretreatment methods for AMS radiocarbon dating at the Oxford Radiocarbon Accelerator Unit (ORAU). Radiocarbon 52(1):103112.
Bronk Ramsey, C. 2009. Bayesian analysis of radiocarbon dates. Radiocarbon 51(1):337360.
Bronk Ramsey, C. 2013. OxCal software v 4.2.4. Available at
Bronk Ramsey, C, Higham, T, Leach, P. 2004. Towards high-precision AMS: progress and limitations. Radiocarbon 46(1):1724.
Buarque, A. 1999. A cultura tupinambá no Estado do Rio de Janeiro. In: Tenório MC, editor. Pré-História da Terra Brasilis. Rio de Janeiro: EDUFRJ. p 307320.
Buarque, A. 2009. Pesquisas arqueológicas em sítios Tupinambá em Araruama, in Estado da Arte das pesquisas arqueológicas sobre a Tradição Tupiguarani. In: Loures de Oliveira AP, editor. As pesquisas arqueológicas em sítios Tupiguarani no Estado do Rio de Janeiro. Minas Gerais: Editora UFJF. p 3763.
Buarque, A. 2010. As estruturas funerárias das aldeias Tupinambá da região de Araruama, RJ. In: Prous A, Lima TA, editors. Os Ceramistas Tupiguarani Volume III. Minas Gerais: Iphan. p 149172.
Buarque, A, Rodrigues-Carvalho, C, Silva, EC. 2003. Programa Funerário dos Tupinambá em Araruama, RJ – Sítio Bananeiras. Revista do Museu de Arqueologia e Etnologia, MAE 13:3955.
Cezar, GDS, da Rocha, PL, Buarque, A, da Costa, A. 2001. Two Brazilian archaeological sites investigated by GPR: Serrano and Morro Grande. Journal of Applied Geophysics 47(3–4):227240.
Crancio, F. 1987. Ocorrência de cerâmica na camada superior do sambaqui Zé Espinho. In: Kneip L, editor. Coletores e pescadores pré-históricos de Guaratiba-Rio de Janeiro. Minas Gerais: Editora UFRJ e EDUFF. p 156184.
Dee, M, Bronk Ramsey, C. 2000. Refinement of graphite target production at ORAU. Nuclear Instruments and Methods in Physics Research B 172(1–4):449453.
Gaspar, MD, Tenorio, MC, Buarque, A, Barbosa-Guimarães, M, Oliveira, JC, Scheel-Ybert, R. 2004. Histórico e principais resultados do projeto de investigação: o aproveitamento ambiental das populações pré-históricas do Rio de Janeiro. Arquivos do Museu Nacional, Rio de Janeiro 62(2):103129.
Hedges, REM, Tiemei, C, Housley, RA. 1992. Results and methods in the radiocarbon dating of pottery. Radiocarbon 34(3):906915.
Higham, TFG, Jacobi, RM, Bronk Ramsey, C. 2006. AMS radiocarbon dating of ancient bone using ultrafiltration. Radiocarbon 48(2):179195.
Hogg, AG, Hua, Q, Blackwell, PG, Niu, M, Buck, CE, Guilderson, TP, Heaton, TJ, Palmer, JG, Reimer, PJ, Reimer, RW, Turney, CSM, Zimmerman, SRH. 2013. SHCal13 Southern Hemisphere calibration, 0–50,000 years cal BP. Radiocarbon 55(4):18891903.
Hoopes, JW, Barnett, WK. 1995. The Emergence of Pottery: Technology and Innovation in Ancient Societies. Washington, DC: Smithsonian Institution Press.
Jones, S. 1997. The Archaeology of Ethnicity. New York: Routledge.
Linares, R, Macario, KD, Santos, GM, Carvalho, C, dos Santos, HC, Gomes, PR, Castro, MD, Oliveira, FM, Alves, EQ. 2015. Radiocarbon measurements at LAC-UFF: recent performance. Nuclear Instruments and Methods in Physics Research B 361:341345.
Macario, KD, Buarque, A, Scheel-Ybert, R, Anjos, RM, Gomes, PRS, Beauclair, M, Hatté, C. 2009. The long-term Tupiguarani occupation in southeastern Brazil. Radiocarbon 51(3):937946.
Macario, KD, Oliveira, FM, Carvalho, C, Santos, GM, Xu, X, Chanca, IS, Alves, EQ, Jou, RM, Oliveira, MI, Pereira, BB, Moreira, V. 2015. Advances in the graphitization protocol at the Radiocarbon Laboratory of the Universidade Federal Fluminense (LAC-UFF) in Brazil. Nuclear Instruments and Methods in Physics Research B 361:402405.
Macario, KD, Oliveira, FM, Moreira, VN, Alves, EQ, Carvalho, C, Jou, RM, Oliveira, MI, Pereira, BB, Hammerschlag, I, Netto, B, Seixas, AP, Malafaia, JVP, Moreira, L, Cunha, L, Assumpção, A, Paula, PM, Lima, L, Lopes, F, Diaz, M, Chanca, IS, Gomes, PRS. 2016. Optimization of the amount of zinc in the graphitization reaction for radiocarbon AMS measurements at LAC-UFF. Radiocarbon. This issue. DOI:10.1017/RDC.2016.42.
McFadgen, BG. 1982. Dating New-Zealand archaeology by radiocarbon. New Zealand Journal of Science 25(4):379392.
Monteiro, J. 1949. Relação da Província do Brasil, 1610. História da Companhia de Jesus no Brasil. Serafim Leite, S.I., Tomo VIII, Rio de Janeiro: Instituto Nacional do Livro. p 393425.
Nakamura, T, Yasuhiro, T, Sei’ichiro, T, Hirotaka, O. 2001. Radiocarbon dating of charred residues on the earliest pottery in Japan. Radiocarbon 43(2B):11291138.
Noelli, F. 2008. The Tupi expansion. In: Silverman H, Isbell W, editors. Handbook of South American Archaeology. New York: Springer. p 659670.
Nunes, KP, Toyota, RG, Oliveira, PMS, Neves, EG, Soares, EAA, Munita, CS. 2013. Preliminary compositional evidence of provenance of ceramics from Hatahara archaeological site, central Amazonia. Journal of Chemistry 2013:701748.
O’Malley, JM, Kuzmin, YV, Burr, GS, Donahue, DJ, Jull, AJT. 1999. Direct radiocarbon AMS dating of the earliest pottery from the Russian Far East and Transbaikal. Mémories de la Société e Préhistorique Française [Supplément 1999 de la Revue d’Archéometrie] 26:1924.
Prous, A. 1992. Arqueologia Brasileira. Brasília: UNB. 605 p.
Roosevelt, AC, Housley, RA, Da Silveira, MI, Maranca, S, Johnson, R. 1991. Eighth millennium pottery from a prehistoric shell midden in the Brazilian Amazon. Science 254(5038):16211624.
Salvador, FV. 1982. História do Brasil (1500–1627). São Paulo: Editora da Universidade de São Paulo. 437 p.
Sealy, J, Johnson, M, Richards, M, Nehlich, O. 2014. Comparison of two methods of extracting bone collagen for stable carbon and nitrogen isotope analysis: comparing whole bone demineralization with gelatinization and ultrafiltration. Journal of Archaeological Science 47:6469.
Scheel-Ybert, R, Gouveia, SEM, Pessenda, LC, Aravena, R, Coutinho, LM, Boulet, R. 2003. Holocene palaeoenvironmental evolution in the São Paulo State (Brazil), based on anthracology and soil δ13C analysis. The Holocene 13(1):7381.
Scheel-Ybert, R, Macario, K, Buarque, A, Anjos, RM, Beauclair, M. 2008. A new age to an old site: the earliest Tupiguarani settlement in Rio de Janeiro State? Anais da Academia Brasileira de Ciências 80(4):763770.
Scheel-Ybert, R, Beauclair, M, Buarque, A. 2013. The forest people: landscape and firewood use in the Araruama region, southeastern Brazil, during the late Holocene. Vegetation History and Archaeobotany 23(2):97111.
Skibo, JM. 2013. Understanding Pottery Function. Manuals in Archaeological Method, Theory and Technique. New York: Springer.
Staden, H. 1978. Wahrhaftige Historia: und Beschreibung einer Landschaft der wilden, nackten, grimmigen Menschenfresser in der Neuen Welt Amerika gelegen. Kassel: Thiele & Schwarz.
Stäuble, H. 1995. Radiocarbon dates of the earliest Neolithic in Central Europe. Radiocarbon 37(2):227237.
Stott, AW, Berstan, R, Evershed, P, Hedges, REM, Bronk Ramsey, C, Humm, MJ. 2001. Radiocarbon dating of single compounds isolated from pottery cooking vessel residues. Radiocarbon 43(2A):191197.
Talamo, S, Richards, M. 2011. A comparison of bone pretreatment methods for AMS dating of samples >30,000 BP. Radiocarbon 53(3):443449.
Théry-Parisot, I, Chabal, L, Chrzavzez, J. 2010. Anthracology and taphonomy, from wood gathering to charcoal analysis. A review of the taphonomic processes modifying charcoal assemblages, in archaeological contexts. Palaeogeography, Palaeoclimatology, Palaeoecology 291(1):142153.
Tite, MS. 2008. Ceramic production, provenance and use—a review. Archaeometry 50(2):216231.
Zazzo, A, Saliège, J-F, Person, A, Boucher, H. 2009. Radiocarbon dating of calcined bones: Where does the carbon come from? Radiocarbon 51(2):601611.
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