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Ion-Molecule Reaction Studies below 80 K by the CRESU Technique

Published online by Cambridge University Press:  04 August 2017

J. B. Marquette
Affiliation:
Laboratoire d'Aérothermique du CNRS, 4ter route des Gardes, 92190 Meudon France
B. R. Rowe
Affiliation:
Laboratoire d'Aérothermique du CNRS, 4ter route des Gardes, 92190 Meudon France
G. Dupeyrat
Affiliation:
Laboratoire d'Aérothermique du CNRS, 4ter route des Gardes, 92190 Meudon France
G. Poissant
Affiliation:
Laboratoire d'Aérothermique du CNRS, 4ter route des Gardes, 92190 Meudon France

Extract

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The basic principles of the CRESU technique (Cinétique de Réactions en Ecoulement Supersonique Uniforme) are presented. This technique allows ion-molecule reaction rate coefficients under true thermal conditions at interstellar temperatures. Various behaviors of both third-body association and binary reactions with temperature have been observed, including ion-polar molecule reactions whose rate coefficients sharply increase at very low temperatures.

Type
Basic Studies
Copyright
Copyright © Reidel 1987 

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