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New powder diffraction data of some N-derivatives of 4-chloro-3,5-dimethylphenoxyacetamide-potential pesticides

Published online by Cambridge University Press:  05 March 2012

E. Olszewska ,
B. Tarasiuk  and
S. Pikus
E. Olszewska*
Affiliation:
Department of Crystallography, Faculty of Chemistry, Maria Curie Sklodowska University, Maria Curie-Sklodowska Sqr 3, 20-031 Lublin, Poland
B. Tarasiuk
Affiliation:
Department of Organic Chemistry, Faculty of Chemistry, Maria Curie Sklodowska University, Gliniana Str. 33, 20-614 Lublin, Poland
S. Pikus
Affiliation:
Department of Crystallography, Faculty of Chemistry, Maria Curie Sklodowska University, Maria Curie-Sklodowska Sqr 3, 20-031 Lublin, Poland
*
a)Author to whom correspondence should be addressed. Electronic mail: ela_ol@wp.pl
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Abstract

N-derivatives of 4-chloro-3,5-dimethylphenoxyacetamide—2-(4-chloro-3,5-dimethylphenoxy)-N-(4-fluorophenyl)acetamide, 2-(4-chloro-3,5-dimethylphenoxy)-N-(3-chloro-4-fluorophenyl) acetamide, 2-(4-chloro-3,5-dimethylphenoxy)-N-[4-chloro-3-(trifluoromethyl)phenyl] acetamide, 2-(4-chloro-3,5-dimethylphenoxy)-N-[3-chloro-4-methylphenyl]acetamide, 2-(4-chloro-3,5-dimethylphenoxy)-N-(2,4,6-tribromophenyl) acetamide, 2-(4-chloro-3,5-dimethylphenoxy)-N-pyridin-2-ylacetamide, 1-[(4-chloro-3,5-dimethylphenoxy)acetyl]-4-methylpiperazine, and 1-benzyl-4-[(4-chloro-3,5-dimethylphenoxy)acetyl]piperazine—have been characterized by X-ray powder diffraction. These organic compounds are potential pesticides. Experimental 2θ peak positions, relative peak intensities, values of d and Miller indices, and unit-cell parameters are presented.

Keywords

X-ray powder diffractionpesticide4-chloro-3,5-dimethylphenoxyacetamide

Information

Type
New Diffraction Data
Information
Powder Diffraction , Volume 26 , Issue 4 , December 2011 , pp. 337 - 345
Copyright
Copyright © Cambridge University Press 2011

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References

Baker, B. R. and Neenan, J. P. (1972). “Irreversible enzyme inhibitors. 195. Inhibitors of thymidine kinase from Walker 256 carcinoma derived from thymidine 5′-acetate,” J. Med. Chem. 15, 940–944.10.1021/jm00279a016Google Scholar
Berhenke, L. F., Begin, L. E., Williams, B. M. and Beman, F. L. (1951). “Some aryloxyaliphatic acids,” J. Am. Chem. Soc. 73, 4458–4458.10.1021/ja01153a504CrossRefGoogle Scholar
de Wolff, P. M. (1968). ”A simplified criterion for the reliability of a powder pattern indexing,” J. Appl. Crystallogr. 1, 108–113.10.1107/S002188986800508XCrossRefGoogle Scholar
Gruzdyev, G. S., Zinchenko, V. A., Kalinin, V. A. and Slovtsov, R. I. (1988). “Systemic herbicides—Aryloxyalkylcarboxylic acids,” in The Chemical Protection of Plants (Mir Publishers, Moscow), pp. 364–374.Google Scholar
ICDD (2010). PDF-2 Release 2010 (Database), edited by Kabekkodu, Soorya, International Centre for Diffraction Data, Newtown Square, Pennsylvania.Google Scholar
Marciniak, H. and Diduszko, R. (1994). XRAYAN: computer program for X-ray diffraction phase analyzes, version 2.90, (Computer Software), Warsaw, Poland.Google Scholar
Melnikov, N. N. (1987). “Aryloxyalkylcarboxylic acids and their derivatives,” in Pesticide. Khimiya, tekhnologiya i prymenenye, edited by Nowozyw, K. W. (Khimiya, Moscow), pp. 222–245.Google Scholar
Newman, M. S., Fones, W. and Renoll, M. (1947). “New compounds as plant growth regulators,” J. Am. Chem. Soc. 69, 718–723.10.1021/ja01195a604CrossRefGoogle ScholarPubMed
Olszewska, E., Pikus, S. and Tarasiuk, B. (2008). “New powder diffraction data of some derivatives of N-alkyl (aryl)-2,4-dichlorophenoxyacetamide—New potential pesticides,” Powder Diffr. 23, 338–349.10.1154/1.3009636Google Scholar
Olszewska, E., Tarasiuk, B. and Pikus, S. (2009). "New powder diffraction data of some derivatives of N-(hydroxyalkyl)-4-chlorophenoxyacetamide—Potential pesticides,” Powder Diffr. 24, 327–336.10.1154/1.3257637Google Scholar
Smith, G. S., and Snyder, R. L. (1979). “F N: A criterion for rating powder diffraction patterns and evaluating the reliability of powder-pattern indexing,” J. Appl. Crystallogr. 12, 60–65.10.1107/S002188987901178XGoogle Scholar
Tarasiuk, B. (2007). “Syntheses, structures and properties of halogenoanilides derivatives of dichlorophenoxyacetic acids,” Annales Uniwersytet Maria Curie-SkŁodowska, Sectio AA Chemia 62, 234–249.Google Scholar
Tarasiuk, B., Podkościelny, W., Zimińska, Z. and Krawczyk, M. (2000). “1H-1,2,4-Triazoles derivatives of halogenphenoxyalkane acids with herbicidal activity,” Pestycydy 1–2, 5–15.Google Scholar
Werner, P. F. (1984). TREOR: Trial and error program for indexing of unknown powder patterns, Version 4 (Computer Software), University of Stockholm, Stockholm, Sweden.Google Scholar