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Scanning electron microscope observation of endellite from Bedford, Indiana, discloses the existence of globular clusters of quasi-tubular endellite particles radiating from common centers. Individual clusters are of the order of 10 μ in overall diameter. The individual quasi-tubular particles are irregularly flattened in cross section, and some may be plugged at the ends. Conventional oven drying at 105°C results in partial unrolling and incomplete flattening of the quasi-tubular particles of some of the clusters. The globular cluster microstructure is taken to represent the result of in-situ crystallization from solution. If this is so, these hollow tubes cannot have arisen by the mechanism of repeated extrusion of concentric zonal crystallites as postulated by Chukhrov and Zvyagin.
The naturally occurring layered double hydroxides (LDH, or anionic clays) are of particular interest in environmental geochemistry because of their ability to retain hazardous cations and especially anions. However, incorporation of these minerals into predictive models of water-rock interaction in contaminant environments, including radioactive-waste repositories, is hampered by a lack of thermodynamic and stability data. To fill part of this gap the present authors have derived properties of one of the complex multicomponent solid solutions within the LDH family: the hydrotalcite-pyroaurite series, Mg3(Al1−xFex)(OH)8(CO3)0.5·2.5H2O.
Members of the hydrotalcite-pyroaurite series with fixed MgII/(AlIII+FeIII) = 3 and various FeIII/(FeIII+AlIII) ratios were synthesized by co-precipitation and dissolved in long-term experiments at 23±2°C and pH = 11.40±0.03. The chemical compositions of co-existing solid and aqueous phases were determined by inductively coupled plasma-optical emission spectroscopy, thermogravimetric analysis, and liquid scintillation counting of 55Fe tracers; X-ray diffraction and Raman were used to characterize the solids. Based on good evidence for reversible equilibrium in the experiments, the thermodynamic properties of the solid solution were examined using total-scale Lippmann solubility products, ΣΠT. No significant difference was observed between values of SPT from co-precipitation and from dissolution experiments throughout the whole range of Fe/Al ratios. A simple ideal solid-solution model with similar end-member ΣΠT values (a regular model with 0 < WG < 2 kJ mol −1 sufficient to describe the full range of intermediate mineral compositions. In turn, this yielded the first estimate of the standard Gibbs free energy of the pyroaurite end member, G298,Pyro = −3882.60±2.00 kJ/mol, consistent with G298,Htlco = −4339.85 kJ/mol of the hydrotalcite end member, and with the whole range of solubilities of the mixed phases. The molar volumes of the solid-solution at standard conditions were derived from X-ray data. Finally, Helgeson’s method was used to extend the estimates of standard molar entropy and heat capacity of the end members over the pressure-temperature range 0−70°C and 1–100 bar.
Caregivers of patients with cancer are at significant risk for existential distress. Such distress negatively impacts caregivers’ quality of life and capacity to serve in their role as healthcare proxies, and ultimately, contributes to poor bereavement outcomes. Our team developed Meaning-Centered Psychotherapy for Cancer Caregivers (MCP-C), the first targeted psychosocial intervention that directly addresses existential distress in caregivers.
Method
Nine caregivers of patients with glioblastoma multiforme (GBM) enrolled in a pilot randomized controlled trial evaluating the feasibility, acceptability, and effects of MCP-C, and completed in-depth interviews about their experience in the therapy. One focus group with three MCP-C interventionists was also completed.
Results
Four key themes emerged from interviews: (1) MCP-C validated caregivers’ experience of caregiving; (2) MCP-C helped participants reframe their “caregiving identity” as a facet of their larger self-identity, by placing caregiving in the context of their life's journey; (3) MCP-C enabled caregivers to find ways to assert their agency through caregiving; and (4) the structure and sequence of sessions made MCP-C accessible and feasible. Feedback from interventionists highlighted several potential manual changes and overall ways in which MCP-C can help facilitate caregivers’ openness to discussing death and engaging in advanced care planning discussions with the patient.
Significance of results
The overarching goal of MCP-C is to allow caregivers to concurrently experience meaning and suffering; the intervention does not seek to deny the reality of challenges endured by caregivers, but instead to foster a connection to meaning and purpose alongside their suffering. Through in-depth interviews with caregivers and a focus group with MCP interventionists, we have refined and improved our MCP-C manual so that it can most effectively assist caregivers in experiencing meaning and purpose, despite inevitable suffering.
Although the Tax Cut and Jobs Act (TCJA) did not include any environmental tax provisions, numerous tax policy discussions in the United States have considered implementing a carbon tax, giving rise to concerns about such a tax‘s potential negative effects on economic growth and the distribution of income in the US economy. This chapter examines the macroeconomic and distributional effects of implementing a representative carbon tax under several assumptions about recycling resulting tax revenues. It simulates these effects using the Diamond-Zodrow (DZ) dynamic overlapping generations computable general equilibrium (CGE) model. Earlier literature and our results confirm that: (i) the negative effects of a carbon tax are moderate on the level of future GDP and negligible on the rate of economic growth; and (ii) the regressive effects of a carbon tax can easily be offset with judicious use of the resulting revenues. Policies that use carbon tax revenues to finance uniform per-household rebates and to enact policies favorable to capital formation, such as elimination of both personal taxes on dividends and capital gains, and national debt, can have a highly progressive net impact.
This introduction summarizes the nine central chapters that make up this volume. Martin Feldstein examines the structural reasons for relatively high US growth rates, notes fiscal problems inhibiting future growth including in deficits in social insurance programs, and suggests reforms. Flávio Cunha examines how the development of human capital, especially at early ages, affects economic growth. George Borjas analyzes how increased immigration would affect economic growth in the United States. Glenn Hubbard explores the debate between “techno-optimists” and “techno-pessimists” on the growth effects of technological progress, while Timothy Bresnahan examines in detail the commercial applications of Artificial Intelligence Technologies (AITs). Robert Barro estimates the macroeconomic effects of the recently enacted Tax Cuts and Jobs Act, while John Diamond and George Zodrow examine the macroeconomic and distributional effects of a carbon tax. Ross Levine discusses the links between banking and economic prosperity, and Stephen Turnovsky examines the relationships among income, wealth inequality, and economic growth.
The chapters in this volume provide insightful and provocative discussion of many of the issues related to whether the United States is likely to continue on the robust growth path of earlier years or whether economic growth is likely to decelerate or even enter an extended period of “secular stagnation.” In this concluding chapter, the editors of the volume tie together some of the threads that appear in the various chapters, extend the analyses in several directions, and discuss some policy implications. The discussion is organized around three themes: (i) technology and productivity growth; (ii) labor markets and economic growth, including the importance of human capital accumulation and the role of immigration; and (iii) fiscal policy, including both expenditure and tax reform.