Two approaches have been employed in the preparation of hierarchical compositelaminates with a carbon nanotube (CNT) phase. Glass fibers were coated with CNTsusing electrophoretic deposition (EPD) prior to infusion with epoxy resin. TheCNTs were functionalized using an ultrasonicated-ozone process followed byreaction with polyethyleneimine (PEI) to enhance CNT to fiber and matrixadhesion. Chemical vapor deposition (CVD) was also used to grow CNTs onto quartzfibers, prior to infusion with an epoxy resin modified with a thermoplasticnanophase. The mechanical performance of the two CNT laminates types weresimilar, however, the fracture surfaces indicated distinct differences. The EPDlaminates showed fracture in the CNT-rich interphase region, whereas, the CVDlaminates showed that strength was limited by adhesion failure at the CNT-fiberinterface. The electrical conductivity of CVD laminates was 100 times higherthan EPD laminates. For the EPD laminates the PEI functionalization increasesthe CNT-CNT distance resulting in reduced conductivity, while the high CNTpacking density and residual iron catalyst on the fiber surface in the CVDlaminates creates conducting pathways resulting in higher conductivities.