High-power pulsed lasers are used widely nowadays as shock generators. They settle as a complementary technique to the conventional shock generators by the high peak pressure and short duration shocks they deliver. They are used to investigate the feasibility of new industrial processes and to get information on the behavior of matter in specific conditions of extremely high strain rate. In this paper, some studies about typical applications of laser shocks are presented: surface densification of porous materials, spallation in ductile and brittle materials, α-ε phase change in iron, and an estimate of the relaxation time for this transition. Laser shock experiments provide additional data on the dynamic behavior of materials at the nanosecond time scale.