Experimental investigations of heavy-ion-generated shock waves in solid, multilayered targets were performed by applying a Schlieren and a laser-deflection technique. Shock velocity and the corresponding pressures, temporal and spatial density profiles inside the material compressed by multiple shock waves, and details of the shock dynamics were determined. Important for equation-of-state and phase transition studies, such experiments extend their relevance to inertial confinement fusion and astrophysical fundamental research.