This paper is concerned with the numerical approximations of Cauchy problems for one-dimensional nonconservative hyperbolic systems.The first goal is to introduce a general concept of well-balancingfor numerical schemes solving this kind of systems. Once this concept stated, weinvestigate the well-balance properties of numerical schemes based on thegeneralized Roe linearizations introduced by [Toumi, J. Comp. Phys.102 (1992) 360–373]. Next, this general theoryis applied to obtain well-balanced schemes for solving coupled systems of conservation laws withsource terms. Finally, we focus on applications to shallow water systems: the numericalschemes obtained and their properties are compared, in the case of one layer flows, with those introduced by[Bermúdez and Vázquez-Cendón, Comput. Fluids23 (1994) 1049–1071]; in the case of two layer flows, they arecompared with the numerical scheme presented by [Castro, Macías and Parés, ESAIM: M2AN35 (2001) 107–127].