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We have seen in Section 4.5 a full classification of (3, 3)gen-, (3, 4)gen-, and (4, 3)gen polycycles. We have also seen that, for all other (r, q), there is a continuum of (r, q)-polycycles. The purpose of this chapter is to introduce a decomposition of polycycles into elementary components in an analogous way to decompose the molecules into atoms. This method will prove to be very effective but only in the elliptic case, since, for all other cases, we will show that there is a continuum of such elementary components (see Theorem 7.2.1). The first occurrence of the method is in, followed by and.
Decomposition of polycycles
Given an integer q > 3 and a set R ⊂ − {1} (so, 2-gons will be permitted in this chapter), a (R, q)gen-polycycle is a non-empty 2-connected map on a surface S with faces partitioned in two non-empty sets F1 and F2, so it holds that:
(i) all elements of F1 (called proper faces) are combinatorial i-gons with i ∈ R;
(ii) all elements of F2 (called holes, the exterior face(s) are amongst them) are pairwisely disjoint, i.e. have no common vertices;
(iii) all vertices have degree within {2, …, q} and all interior (i.e. not on the boundary of a hole) vertices are q-valent.
The map can be finite or infinite and some holes can be i-gons with i ∈ R. If R = {r}, then the above definition corresponds to (r, q)gen-polycycles.
The discovery of the fullerene molecules and related forms of carbon, such as nanotubes, has generated an explosion of activity in chemistry, physics, and materials science, which is amply documented, for example, in and. In chemistry, the “classical” definition is that a fullerene is an all-carbon molecule in which the atoms are arranged as a map on a sphere made up entirely of 5-gons and 6-gons, which, therefore, necessarily includes exactly 12 5-gonal faces. We are concerned here with the following generalization: what fullerenes are possible if a fullerene is a finite 3-valent map with only 5- and 6-gonal faces embedded in any surface? This seemingly much larger concept leads only to three extensions to the class of spherical fullerenes. Embedding in only four surfaces is possible: the sphere, torus, Klein bottle, and projective plane. In, the spectral properties of those fullerenes are examined. The usual spherical fullerenes have 12 5-gons, projective fullerenes 6, and toroidal and Klein bottle fullerenes none. Klein bottle and projective fullerenes are the antipodal quotients of centrally symmetric toroidal and spherical fullerenes, respectively. Extensions to infinite graphs (plane fullerenes, cylindrical fullerenes) are indicated. Detailed treatment of the concept of the extended fullerenes and their further generalization to higher dimensional manifolds are given in.
Classification of finite fullerenes
Define a 3-fullerene as a 3-valent map embedded on a surface and consisting of only 5-gonal and 6-gonal faces. Each such object has, say, v vertices, e edges, and f faces of which p5 are 5-gons and p 6 are 6-gons.
Platonic solids have been studied since antiquity and in a multiplicity of artistic and scientific contexts. More generally, “polyhedral” maps are ubiquitous in chemistry and crystallography. Their properties have been studied since Kepler. In the present book we are going to study classes of maps on the sphere or the torus and make a catalog of properties that would be helpful and useful to mathematicians and researchers in natural sciences.
In particular, we are studying here two new classes of maps, interesting for applications, especially in chemistry and crystallography (on the sphere or the torus) generalizing Platonic polyhedra. Polycycles are 2-connected plane graphs having prescribed combinatorial type of interior faces and the same degree q for interior vertices, while at the most q for boundary vertices. Two-faced maps are the maps having at most two types of faces and the same degree of vertices. Many examples and various generalizations are given throughout the text. Pictures are given for many of the obtained graphs, especially when a full classification is possible. A lot of the presentation is necessarily compact but we hope to have made it as explicit as possible.
We are interested mainly in enumeration, symmetry, extremal properties, faceregularity, metric embedding and related algorithmic problems. The graphs in this book come from broad areas of geometry, graph theory, chemistry, and crystallography. Many new interesting spheres and tori are presented.
Babai and Sós have asked whether there exists a constant c > 0 such that every finite group G has a product-free subset of size at least c|G|: that is, a subset X that does not contain three elements x, y and z with xy = z. In this paper we show that the answer is no. Moreover, we give a simple sufficient condition for a group not to have any large product-free subset.
The following two conjectures arose in the work of Grimmett and Winkler, and Pemantle: the uniformly random forest F and the uniformly random connected subgraph C of a finite graph G have the edge-negative association property. In other words, for all distinct edges e and f of G, the probability that F (respectively, C) contains e conditioned on containing f is less than or equal to the probability that F (respectively, C) contains e. Grimmett and Winkler showed that the first conjecture is true for all simple graphs on 8 vertices and all graphs on 9 vertices with at most 18 edges. In this paper, we describe an infinite, nontrivial class of graphs and matroids for which a generalized version of both conjectures holds.
We obtain large-deviation approximations for the empirical distribution for a general family of occupancy problems. In the general setting, balls are allowed to fall in a given urn depending on the urn's contents prior to the throw. We discuss a parametric family of statistical models that includes Maxwell–Boltzmann, Bose–Einstein and Fermi–Dirac statistics as special cases. A process-level large-deviation analysis is conducted and the rate function for the original problem is then characterized, via the contraction principle, by the solution to a calculus of variations problem. The solution to this variational problem is shown to coincide with that of a simple finite-dimensional minimization problem. As a consequence, the large-deviation approximations and related qualitative information are available in more-or-less explicit form.
Given a digraph D, let δ0(D) := min{δ+(D), δ−(D)} be the minimum semi-degree of D. We show that every sufficiently large digraph D with δ0(D)≥n/2 + l −1 is l-linked. The bound on the minimum semi-degree is best possible and confirms a conjecture of Manoussakis [17]. We also determine the smallest minimum semi-degree which ensures that a sufficiently large digraph D is k-ordered, i.e., that for every sequence s1, . . ., sk of distinct vertices of D there is a directed cycle which encounters s1, . . ., sk in this order. This result will be used in [16].
Let be a sequence of real numbers satisfying for each k ≥ 0, where M ≥ 1 is a fixed number. We prove that, for any sequence of real numbers , there is a real number ξ such that for each k ≥ 0. Here, denotes the distance from to the nearest integer. This is a corollary derived from our main theorem, which is a more general matrix version of this statement with explicit constants.
We describe a short and easy-to-analyse construction of constant-degree expanders. The construction relies on the replacement product, applied by Reingold, Vadhan and Wigderson (2002) to give an iterative construction of bounded-degree expanders. Here we give a simpler construction, which applies the replacement product (only twice!) to turn the Cayley expanders of Alon and Roichman (1994), whose degree is polylog n, into constant-degree expanders. This enables us to prove the required expansion using a simple new combinatorial analysis of the replacement product (instead of the spectral analysis used by Reingold, Vadhan and Wigderson).
An induced forest of a graph G is an acyclic induced subgraph of G. The present paper is devoted to the analysis of a simple randomized algorithm that grows an induced forest in a regular graph. The expected size of the forest it outputs provides a lower bound on the maximum number of vertices in an induced forest of G. When the girth is large and the degree is at least 4, our bound coincides with the best bound known to hold asymptotically almost surely for random regular graphs. This results in an alternative proof for the random case.
We show that for 0<α<1 and θ>−α, the Poisson–Dirichlet distribution with parameter (α, θ) is the unique reversible distribution of a rather natural fragmentation–coalescence process. This completes earlier results in the literature for certain split-and-merge transformations and the parameter α = 0.
We derive here the Friedland–Tverberg inequality for positive hyperbolic polynomials. This inequality is applied to give lower bounds for the number of matchings in r-regular bipartite graphs. It is shown that some of these bounds are asymptotically sharp. We improve the known lower bound for the three-dimensional monomer–dimer entropy.