Surprisingly high amounts of H2O have recently been reported in the circumstellar envelope around the M-type AGB star W Hya. However, substantial uncertainties remain, as the required radiative transfer modelling is difficult due to high optical depths, sub-thermal excitation and the sensitivity to the combined radiation field from the central star and dust grains.

We have carried out the mid-infrared slit spectroscopic observations of sources in the LMC and in NGC 6946 with AKARI/IRC. We investigate the properties of the UIR bands in terms of the star forming activities. We find systematically larger ratios of UIR bands in 6–9 μm to 11.2 μm band in active star forming regions than in the quiet regions. This behavior is consistent with the photo-ionization model of PAHs. Our results suggest that the ratios of UIR bands in 6–9 μm to 11.2 μm band can be used as more efficient and vigorous tools to measure the extent of on-going star formation in remote galaxies rather than just the presence or absence of the features themselves.

The most intriguing question related to the chemical evolution of protoplanetary disks is the genesis of pre-biotic organic molecules in the planet-forming zone. In this contribution we briefly review current observational knowledge of physical structure and chemical composition of disks and discuss whether organic molecules can be present in large amounts at the verge of planet formation. We predict that some molecules, including CO-bearing species such as H2CO, can be underabundant in inner regions of accreting protoplanetary disks around low-mass stars due to the high-energy stellar radiation and chemical processing on dust grain surfaces. These theoretical predictions are further compared with high-resolution observational data and the limitations of current models are discussed.

Ethylene (C2H4) is a symmetric molecule that is best detected using mid-infrared transitions. We report on observations of the 10.5 μm ν7 band using the cryogenic grating spectrograph TEXES. These confirm the previous ethylene detection in the IRC+10216 circumstellar shell. We detect 18 ethylene lines. The lines are both narrow and weak with depths of no more than ~2%. The ethylene lines suggest an excitation temperature of ~80 K.

The unidentified infrared (UIR) emission bands in the near- to mid-infrared are thought to originate from organic compounds in the interstellar medium. Recent space observations with Spitzer and AKARI have clearly revealed that the UIR bands are commonly seen in external galaxies, including elliptical galaxies, except for very metal-poor dwarf galaxies. They are also detected in extended structures of galaxies, such as extra-planar components and filaments produced by outflows, suggesting that the band carriers are ubiquitous organic compounds in galaxies. Since the UIR bands are prominent features in the infrared spectrum of galaxies and are linked to the star-formation activity, it is highly important to understand the nature, formation, processing, and destruction of the UIR band carriers in galaxies. While there is no systematic variation detected in the UIR spectrum in normal galaxies, significantly low values are derived for the ratio of the 7.7 μm to 11.2 μm bands in elliptical galaxies as well as in galaxies with low-luminosity AGNs compared to normal star-forming galaxies. Relatively low band ratios are also seen in the UIR band spectrum of extended structures in galaxies. If the same mechanism leads to the low band ratio, it would provide important information on the band carrier properties. It should also be noted that the band carriers are believed to be destroyed in a short time scale in environments where low band ratios are detected. The survival and supply processes in these environments are a key to understand the nature of the band carriers.

We are conducting multi-transition observations of circumstellar line emission from common molecules such as HCN, SiO, CS, SiS and CN for a large sample of AGB stars with varying photospheric C/O-ratios and mass-loss charachteristics. Our recently published results for SiO and SiS clearly show that major constraints on the relative roles of non-equilibrium chemistry, dust condensation, and photodissociation can be obtained from the study of circumstellar molecular line emission. Presented here are also preliminary results based on detailed radiative transfer modelling of HCN line emission.

We present high-resolution and high signal-to-noise spectroscopic observations of interstellar molecular lines of C2 towards early-type stars. C2 is particularly interesting because it is the simplest multicarbon molecule and its abundances give information on the chemistry of interstellar clouds, especially on the pathway of formation of (hydro)carbon chains and PAHs which may be considered as possible carriers of diffuse interstellar bands (DIBs). Homonuclear diatomic molecules have negligible dipol moments and hence radiative cooling of excited rotational levels may go only trough the slow quadrupole transitions (van Dishoeck & Black 1982). In C2, pumped by galactic average interstellar field rotational levels are excited effectively much above the gas kinetic temperature and a rotational ladder of electronic transitions is usually observed from high rotational levels. Relations between abundances of the dicarbon and other simple interstellar molecules are considered as well.

The synthesis of organic molecular anions in TMC-1 and IRC+10216 is investigated. Modelled C2H−, CN−, C3N−, C5N− and C7N− column densities are sufficiently great that these species might be observable in IRC+10216. Density-enhanced shells in the outer envelope of IRC+10216 are found to enhance the C2H− and CN− column densities by shielding these anions from destruction by UV radiation. From a newly-derived upper column density limit of 6.6 × 1010 cm−2 for C2H− in IRC+10216 we deduce the primary production mechanism for this anion to be C2H2 + H− ⇒ C2H− + H2. In TMC-1, due to the low radiative electron attachment rates calculated for C2H−, CN− and CH2CN−, these species have modelled column densities below the detection threshold. They could, however, be produced in reactions we have not yet considered.

One of the few carbon-rich environments found in interstellar space is the ejecta of asymptotic giant branch (AGB) stars. Such material, which forms a circumstellar envelope, becomes enriched in carbon due to “dredge-up” phenomena associated with nucleosynthesis. A unique organic synthesis flourishes in the gas phase in these envelopes, and radio and millimeter observations have identified a wide range of C-bearing compounds, including long acetylenic chains such as HC5N, HC7N, C4H, C6H, C8H, C6H−, C8H−, and C3O. Oxygen-rich envelopes also have a non-negligible carbon chemistry, fostering species such as HCN and HCO+. Phosphorus chemistry appears to be active as well in circumstellar shells, as evidenced by the recent detections of HCP, CCP, and PO. Radio observations also indicate that some fraction of the circumstellar molecular material survives into the planetary nebula stage, and then becomes incorporated into diffuse, and eventually, dense clouds. The complex organic molecules found in dense clouds such as Sgr B2(N) may be the products of “seed” material that can be traced back to the carbon-enriched circumstellar gas.

Without accurate data on reaction rates and branching ratios, models of interstellar chemistry are unreliable. Recent research has identified a number of reactions of unusual importance because the rates and branching ratios are unknown or poorly known. Efforts to expand and improve on current databases are underway using a flowing afterglow-selected ion flow tube (FA-SIFT) coupled to a quadrupole mass spectrometer. Our current focus is on the reactions of C+, a major cation in the interstellar medium, with the neutrals O2, H2O, CH4, NH3 and C2H2. Future planned work includes studies of polycyclic aromatic hydrocarbons (PAHs), developing comprehensive pathways for their formation, and identification of those PAHs important to interstellar chemistry. The recent discovery of ISM anions has highlighted the importance of examining mechanisms of anionic chemistry in the interstellar medium, and we plan to obtain data relevant to the formation and destruction processes of molecular anions in space.

Meteorites and Interplanetary Dust Particles (IDPs) are supposed to originate from asteroids and comets, sampling the most primitive bodies in the Solar System. They contain abundant carbonaceous material. Some of this, mostly insoluble organic matter (IOM), likely originated in the protosolar molecular cloud, based on spectral properties and H and N isotope characteristics. Together with cometary material returned with the Stardust mission, these samples provide a benchmark for models aiming to understand organic chemistry in the interstellar medium, as well as for mechanisms that secured the survival of these fragile molecules during Solar System formation. The carrier molecules of the isotope anomalies are largely unknown, although amorphous carbonaceous spheres, so-called nanoglobules, have been identified as carriers. We are using Secondary Ion Mass Spectrometry to identify isotopically anomalous material in meteoritic IOM and IDPs at a ~100-200 nm scale. Organics of most likely interstellar origin are then extracted with the Focused-Ion-Beam technique and prepared for synchrotron X-ray and Transmission Electron Microscopy. These experiments yield information on the character of the H- and N-bearing interstellar molecules: While the association of H and N isotope anomalies with nanoglobules could be confirmed, we have also identified amorphous, micron-sized monolithic grains. D-enrichments in meteoritic IOM appear not to be systematically associated with any specific functional groups, whereas 15N-rich material can be related to imine and nitrile functionality. The large 15N- enrichments observed here (δ15N > 1000 ‰) cannot be reconciled with models using interstellar ammonia ice reactions, and hence, provide new constraints for understanding the chemistry in cold interstellar clouds.

We present an ISOCAM-CVF map of the ρ Oph A region, covering 3′ × 3′. For each 6 arcsec2 pixel, we extract the spectrum from 5–15 μm. We determine the fluxes of the main PAH features by fitting Lorentzian profiles to the spectrum. The peaks of the various PAH components correspond well with the known positions of the PDRs in this vicinity. The spectrum in several pixels exhibits strong rotational lines of molecular hydrogen which can be used to derive the physical properties of the cloud. The H2 emission traces the hot gas of the bipolar CO outflow from VLA1623.

Lightning is considered as one of energy sources for synthesis of biochemical compounds. Numerous theoretical and experimental researches of gas-grain chemistry show that chemical reactions on the gas - ice boundary play a considerable role in such synthesis. In this connection the greatest interest represents studying lightning in gas-dusty atmospheres of water-containing bodies (comets, ice satellites of Jupiter and Saturn).

Carbonaceous extraterrestrial matter is observed in a wide variety of astrophysical environments. The spectroscopic signatures revealed a large variety of chemical structure illustrating the rich carbon chemistry that occurs in space. In order to produce laboratory analogues of carbonaceous cosmic dust, a new chemical reactor has been built in the Laboratoire de Photophysique Moléculaire. It is a low pressure flat burner providing flames of premixed hydrocarbon / oxygen gas mixtures, closely following the model system used by the combustion community. In such a device the flame is a one-dimensional chemical reactor that offers a broad range of combustion conditions and sampling which allows production of many and various by-products. In the present work, we have studied: i) the infrared transmission spectra of thin film deposit samples whose nature ranges from strongly aromatic to strongly aliphatic materials; ii) the resonant two-photon photoionisation spectra of gas phase PAHs formed in the flame.

We present preliminary results of an unbiased spectral survey at 1 mm of the oxygen-rich supergiant, VY CMa. A number of exotic molecules have been detected, including NaCl and PO, and a relatively rich organic chemistry is observed. Results of the survey will be compared with carbon-rich stars.

Cassini RADAR observations now permit an initial assessment of the inventory of two classes, presumed to be organic, of Titan surface materials: polar lake liquids and equatorial dune sands. Several hundred lakes or seas have been observed, of which dozens are each estimated to contain more hydrocarbon liquid than the entire known oil and gas reserves on Earth. Dark dunes cover some 20% of Titan's surface, and comprise a volume of material several hundred times larger than Earth's coal reserves. Overall, however, the identified surface inventories (> 3 × 104 km3 of liquid, and >2 × 105 km3 of dune sands) are small compared with estimated photochemical production on Titan over the age of the Solar System. The sand volume is too large to be accounted for simply by erosion in observed river channels or ejecta from observed impact craters. The lakes are adequate in extent to buffer atmospheric methane against photolysis in the short term, but do not contain enough methane to sustain the atmosphere over geologic time. Thus, unless frequent resupply from the interior buffers this greenhouse gas at exactly the right rate, dramatic climate change on Titan is likely in its past, present and future.

Polycyclic aromatic hydrocarbons (PAHs) and related aromatic materials are thought to be the most abudant class of organic carbon in the universe, being present in virtually all phases of the ISM, and abundant in carbonaceous meteorites and asteroid and comet dust. The basic PAH skeleton is proposed to have formed in outflows of carbon rich stars, and isotopic measurements of extraterrestrial graphitic carbon is consistent with this notion. However, functionalized aromatics bearing oxygen atoms, aliphatic domains, and deuterium enrichments have been extracted from meteorites and more recently been measured in IDPs and Stardust retuned comet samples. Exposure of remnant circumstellar PAHs to energetic processing at low temperature in the presense of H2O is the most parsimonious explanation for these observations.

We will present laboratory infrared spectra of various aromatic species and PAH cations in solid H2O under conditions relevant for comparsion to absorptions attributed to PAHs observed towards objects embedded in dense clouds. In addition, we shall describe the reactions of PAHs under these conditions in the lab when they are exposed to energetic processing. Finally, we will propose a mechanism, and make specific predictions regarding the structures and distribution of deuterium that should be observed in extraterrestrial samples if low temperature ice radiation chemistry is playing a role in the formation of the molecules seen in Solar System materials.

The aim of this work is to study the chemistry of the irradiation of frozen solutions of HCN. This compound has been detected in comets and other icy bodies. The CN group might have made its first appearance in the early stages of chemical evolution. Therefore, is behavior under irradiation at low temperature is relevant for chemical evolution studies and icy bodies.

We present experimental results obtained from photoionization and photodissociation processes of abundant interstellar methanol (CH3OH) as an alternative route for the production of H3+ in dense clouds. The measurements were taken at the Brazilian Synchrotron Light Laboratory (LNLS) employing soft X-ray and time-of-flight mass spectrometry. Mass spectra were obtained using the photoelectron-photoion coincidence techniques. Absolute averaged cross sections for the production of H3+ due to molecular dissociation of methanol by soft X-rays (C1s edge) were determined. The H3+'s photoproduction rate and column density were been estimated adopting a typical soft X-ray luminosity inside dense molecular and the observed column density of methanol. Assuming a steady state scenario, the highest column density value for the photoproduced H3+ was about 1011 cm2, which gives the ratio photoproduced/observed of about 0.05%, as in the case of dense molecular cloud AFGL 2591. Despite the small value, this represent a new and alternative source of H3+ into dense molecular clouds and it is not been considered as yet in interstellar chemistry models.

While gaseous carbon-rich species in cometary comae (coming from the nuclei icy component) are extensively studied by spectroscopic remote observations, so-called CHONs dust particles, i. e. organic compounds coming from the nuclei refractory component, have mostly been studied by dust mass spectrometers flying through the comae of comets 1P/Halley and 81P/Wild 2. However, remote observations of the light scattered by dust in cometary comae and in the interplanetary medium, coupled with both numerical and experimental simulations, have recently allowed us to confirm that such particles harbor a significant fraction of absorbing material, presumably consisting of organic compounds (Levasseur-Regourd et al. PSS 2007, Lasue et al. A&A 2007).

We estimate the fraction of absorbing material present in cometary dust for extensively observed comets (e.g., 1P/Halley, C/1995 O1 Hale-Bopp) and in the interplanetary dust (from zodiacal light observations). We also establish that, besides compact particles, fluffy aggregates are definitely present in these media. The properties (e.g., size distribution, morphology, composition) of the cometary and interplanetary dust particles, as inferred from light scattering data analysis, are compared with those of the IDPS collected in the upper Earth atmosphere and of the unique samples returned by the Stardust mission at Wild 2. The results are discussed in terms of the formation of comets in the protosolar nebula, and of the possible survival, at the epoch of late early bombardment, of cometary organics embedded in fluffy aggregates.