For systems that have some degree of symmetry, full exploitation of that symmetry is desirable. Significant physical results can sometimes be deduced simply by a study of the symmetry properties of the system under investigation. Consequently it becomes important, for such a system, to identify all those operations (rotations, reflections, inversions) that carry the system into a physically indistinguishable copy of itself.

The study of the properties of the complete set of such operations forms one application of group theory. Though this is the aspect of most interest to the physical scientist, group theory itself is a much larger subject and of great importance in its own right. Consequently we leave until the next chapter any direct applications of group theoretical results and concentrate on building up the general mathematical properties of groups.

Groups

As an example of symmetry properties, let us consider the sets of operations, such as rotations, reflections, and inversions, that transform physical objects, for example molecules, into physically indistinguishable copies of themselves, so that only the labelling of identical components of the system (the atoms) changes in the process. For differently shaped molecules there are different sets of operations, but in each case it is a well-defined set, and with a little practice all members of each set can be identified.

As simple examples, consider (a) the hydrogen molecule, and (b) the ammonia molecule illustrated in figure 24.1.

Throughout this book references have been made to results derived from the theory of complex variables. This theory thus becomes an integral part of the mathematics appropriate to physical applications. The difficulty with it, from the point of view of a book such as the present one, is that although it has many practical applications its underlying basis has a distinctly pure mathematics flavour.

Thus, to adopt a comprehensive rigorous approach would involve a large amount of groundwork in analysis, for example formulating precise definitions of continuity and differentiability, developing the theory of sets and making a detailed study of boundedness. Instead, we will be selective and pursue only those parts of the formal theory that are needed to establish the results used elsewhere in this book and some others of general utility.

In this spirit, the proofs that have been adopted for some of the standard results of complex variable theory have been chosen with an eye to simplicity rather than sophistication. This means that in some cases the imposed conditions are more stringent than would be strictly necessary if more sophisticated proofs were used; where this happens the less restrictive results are usually stated as well. The reader who is interested in a fuller treatment should consult one of the many excellent textbooks on this fascinating subject.

One further concession to ‘hand-waving’ has been made in the interests of keeping the treatment to a moderate length.

We have already discussed, in chapter 4, how complicated functions may be expressed as power series. However, this is not the only way in which a function may be represented as a series, and the subject of this chapter is the expression of functions as a sum of sine and cosine terms. Such a representation is called a Fourier series. Unlike Taylor series, a Fourier series can describe functions that are not everywhere continuous and/or differentiable. There are also other advantages in using trigonometric terms. They are easy to differentiate and integrate, their moduli are easily taken and each term contains only one characteristic frequency. This last point is important because, as we shall see later, Fourier series are often used to represent the response of a system to a periodic input, and this response often depends directly on the frequency content of the input. Fourier series are used in a wide variety of such physical situations, including the vibrations of a finite string, the scattering of light by a diffraction grating and the transmission of an input signal by an electronic circuit.

The Dirichlet conditions

We have already mentioned that Fourier series may be used to represent some functions for which a Taylor series expansion is not possible. The particular conditions that a function f(x) must fulfil in order that it may be expanded as a Fourier series are known as the Dirichlet conditions, and may be summarised by the following four points:

1. (i) the function must be periodic;

2. (ii) […]

This chapter introduces space vectors and their manipulation. Firstly we deal with the description and algebra of vectors, then we consider how vectors may be used to describe lines and planes and finally we look at the practical use of vectors in finding distances. Much use of vectors will be made in subsequent chapters; this chapter gives only some basic rules.

Scalars and vectors

The simplest kind of physical quantity is one that can be completely specified by its magnitude, a single number, together with the units in which it is measured. Such a quantity is called a scalar and examples include temperature, time and density.

A vector is a quantity that requires both a magnitude (≥ 0) and a direction in space to specify it completely; we may think of it as an arrow in space. A familiar example is force, which has a magnitude (strength) measured in newtons and a direction of application. The large number of vectors that are used to describe the physical world include velocity, displacement, momentum and electric field. Vectors are also used to describe quantities such as angular momentum and surface elements (a surface element has an area and a direction defined by the normal to its tangent plane); in such cases their definitions may seem somewhat arbitrary (though in fact they are standard) and not as physically intuitive as for vectors such as force. A vector is denoted by bold type, the convention of this book, or by underlining, the latter being much used in handwritten work.

It may seem obvious that the quantitative description of physical processes cannot depend on the coordinate system in which they are represented. However, we may turn this argument around: since physical results must indeed be independent of the choice of coordinate system, what does this imply about the nature of the quantities involved in the description of physical processes? The study of these implications and of the classification of physical quantities by means of them forms the content of the present chapter.

Although the concepts presented here may be applied, with little modification, to more abstract spaces (most notably the four-dimensional space–time of special or general relativity), we shall restrict our attention to our familiar three-dimensional Euclidean space. This removes the need to discuss the properties of differentiable manifolds and their tangent and dual spaces. The reader who is interested in these more technical aspects of tensor calculus in general spaces, and in particular their application to general relativity, should consult one of the many excellent textbooks on the subject.

Before the presentation of the main development of the subject, we begin by introducing the summation convention, which will prove very useful in writing tensor equations in a more compact form. We then review the effects of a change of basis in a vector space; such spaces were discussed in chapter 8. This is followed by an investigation of the rotation of Cartesian coordinate systems, and finally we broaden our discussion to include more general coordinate systems and transformations.

Any student of the physical sciences will encounter the subject of oscillations on many occasions and in a wide variety of circumstances, for example the voltage and current oscillations in an electric circuit, the vibrations of a mechanical structure and the internal motions of molecules. The matrices studied in the previous chapter provide a particularly simple way to approach what may appear, at first glance, to be difficult physical problems.

We will consider only systems for which a position-dependent potential exists, i.e., the potential energy of the system in any particular configuration depends upon the coordinates of the configuration, which need not be be lengths, however; the potential must not depend upon the time derivatives (generalised velocities) of these coordinates. So, for example, the potential —qv. A used in the Lagrangian description of a charged particle in an electromagnetic field is excluded. A further restriction that we place is that the potential has a local minimum at the equilibrium point; physically, this is a necessary and sufficient condition for stable equilibrium. By suitably defining the origin of the potential, we may take its value at the equilibrium point as zero.

We denote the coordinates chosen to describe a configuration of the system by qi, i = 1, 2, …, N. The qi need not be distances; some could be angles, for example.

It is not unusual in the analysis of a physical system to encounter an equation in which an unknown but required function y(x), say, appears under an integral sign. Such an equation is called an integral equation, and in this chapter we discuss several methods for solving the more straightforward examples of such equations.

Before embarking on our discussion of methods for solving various integral equations, we begin with a warning that many of the integral equations met in practice cannot be solved by the elementary methods presented here but must instead be solved numerically, usually on a computer. Nevertheless, the regular occurrence of several simple types of integral equation that may be solved analytically is sufficient reason to explore these equations more fully.

We shall begin this chapter by discussing how a differential equation can be transformed into an integral equation and by considering the most common types of linear integral equation. After introducing the operator notation and considering the existence of solutions for various types of equation, we go on to discuss elementary methods of obtaining closed-form solutions of simple integral equations. We then consider the solution of integral equations in terms of infinite series and conclude by discussing the properties of integral equations with Hermitian kernels, i.e. those in which the integrands have particular symmetry properties.

Obtaining an integral equation from a differential equation

Integral equations occur in many situations, partly because we may always rewrite a differential equation as an integral equation.

It happens frequently that the end product of a calculation or piece of analysis is one or more algebraic or differential equations, or an integral that cannot be evaluated in closed form or in terms of tabulated or pre-programmed functions. From the point of view of the physical scientist or engineer, who needs numerical values for prediction or comparison with experiment, the calculation or analysis is thus incomplete.

With the ready availability of standard packages on powerful computers for the numerical solution of equations, both algebraic and differential, and for the evaluation of integrals, in principle there is no need for the investigator to do other than turn to them. However, it should be a part of every engineer's or scientist's competence to have some understanding of the kinds of procedure that are being put into practice within those packages. The present chapter indicates (at a simple level) some of the ways in which analytically intractable problems can be tackled using numerical methods.

In the restricted space available in a book of this nature it is clearly not possible to give anything like a full discussion, even of the elementary points that will be made in this chapter. The limited objective adopted is that of explaining and illustrating by simple examples some of the basic principles involved. In many cases, the examples used can be solved in closed form anyway, but this ‘obviousness’ of the answers should not detract from their illustrative usefulness, and it is hoped that their transparency will help the reader to appreciate some of the inner workings of the methods described.

Since the publication of the first edition of this book, both through teaching the material it covers and as a result of receiving helpful comments from colleagues, we have become aware of the desirability of changes in a number of areas. The most important of these is that the mathematical preparation of current senior college and university entrants is now less thorough than it used to be. To match this, we decided to include a preliminary chapter covering areas such as polynomial equations, trigonometric identities, coordinate geometry, partial fractions, binomial expansions, necessary and sufficient condition and proof by induction and contradiction.

Whilst the general level of what is included in this second edition has not been raised, some areas have been expanded to take in topics we now feel were not adequately covered in the first. In particular, increased attention has been given to non-square sets of simultaneous linear equations and their associated matrices. We hope that this more extended treatment, together with the inclusion of singular value matrix decomposition, will make the material of more practical use to engineering students. In the same spirit, an elementary treatment of linear recurrence relations has been included. The topic of normal modes has been given a small chapter of its own, though the links to matrices on the one hand, and to representation theory on the other, have not been lost.

Elsewhere, the presentation of probability and statistics has been reorganised to give the two aspects more nearly equal weights.

As indicated at the start of the previous chapter, significant conclusions can often be drawn about a physical system simply from the study of its symmetry properties. That chapter was devoted to setting up a formal mathematical basis, group theory, with which to describe and classify such properties; the current chapter shows how to implement the consequences of the resulting classifications and obtain concrete physical conclusions about the system under study. The connection between the two chapters is akin to that between working with coordinate-free vectors, each denoted by a single symbol, and working with a coordinate system in which the same vectors are expressed in terms of components.

The ‘coordinate systems’ that we will choose will be ones that are expressed in terms of matrices; it will be clear that ordinary numbers would not be sufficient, as they make no provision for any non-commutation amongst the elements of a group. Thus, in this chapter the group elements will be represented by matrices that have the same commutation relations as the members of the group, whatever the group's original nature (symmetry operations, functional forms, matrices, permutations, etc.). For some abstract groups it is difficult to give a written description of the elements and their properties without recourse to such representations. Most of our applications will be concerned with representations of the groups that consist of the symmetry operations on molecules containing two or more identical atoms.

In chapter 7 we discussed the algebra of vectors, and in chapter 8 we considered how to transform one vector into another using a linear operator. In this chapter and the next we discuss the calculus of vectors, i.e. the differentiation and integration both of vectors describing particular bodies, such as the velocity of a particle, and of vector fields, in which a vector is defined as a function of the coordinates throughout some volume (one-, two- or three-dimensional). Since the aim of this chapter is to develop methods for handling multi-dimensional physical situations, we will assume throughout that the functions with which we have to deal have sufficiently amenable mathematical properties, in particular that they are continuous and differentiable.

Differentiation of vectors

Let us consider a vector a that is a function of a scalar variable u. By this we mean that with each value of u we associate a vector a(u). For example, in Cartesian coordinates a(u) = ax(u)i + ay(u)j + az(u)k, where ax(u), ay(u) and az(u) are scalar functions of u and are the components of the vector a(u) in the x-, y- and z- directions respectively. We note that if a(u) is continuous at some point u = u0 then this implies that each of the Cartesian components ax(u), ay(u) and az(u) is also continuous there.

A knowledge of mathematical methods is important for an increasing number of university and college courses, particularly in physics, engineering and chemistry, but also in more general science. Students embarking on such courses come from diverse mathematical backgrounds, and their core knowledge varies considerably. We have therefore decided to write a textbook that assumes knowledge only of material that can be expected to be familiar to all the current generation of students starting physical science courses at university. In the United Kingdom this corresponds to the standard of Mathematics A-level, whereas in the United States the material assumed is that which would normally be covered at junior college.

Starting from this level, the first six chapters cover a collection of topics with which the reader may already be familiar, but which are here extended and applied to typical problems encountered by first-year university students. They are aimed at providing a common base of general techniques used in the development of the remaining chapters. Students who have had additional preparation, such as Further Mathematics at A-level, will find much of this material straightforward.

Following these opening chapters, the remainder of the book is intended to cover at least that mathematical material which an undergraduate in the physical sciences might encounter up to the end of his or her course. The book is also appropriate for those beginning graduate study with a mathematical content, and naturally much of the material forms parts of courses for mathematics students. Furthermore, the text should provide a useful reference for research workers.