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At intervals during the past year I have tried a good many experiments in the hope of throwing further light upon the origin of these figures, especially those due to the passage of a small blow-pipe flame, or of hot sulphuric acid, across the surface of a glass plate on which, before treatment, the breath deposits evenly. The even deposit consists of a multitude of small lenses easily seen with a hand magnifier. In the track of the flame or sulphuric acid the lenses are larger, often passing into flat masses which, on evaporation, show the usual colours of thin plates. When the glass is seen against a dark ground, and is so held that regularly reflected light does not reach the eye, the general surface shows bright, while the track of the flame or acid is by comparison dark or black. It will be convenient thus to speak of the deposit as bright or dark—descriptive words implying no doubtful hypothesis. The question is what difference in the glass surface determines the two kinds of deposit.
In Aitken's view (Proc. Ed. Soc. p. 94, 1893; Nature, June 15, 1911), the flame acts by the deposit of numerous fine particles constituting nuclei of aqueous condensation, and in like manner he attributes the effect of sulphuric (or hydrofluoric) acid to a water-attracting residue remaining in spite of washing. On the other hand, I was disposed to refer the dark deposit to a greater degree of freedom from grease or other water-repelling contamination (Nature, May 25, 1911), supposing that a clean surface of glass would everywhere attract moisture. It will be seen that the two views are sharply contrasted.
The ideal form of Helmholtz resonator is a cavernous space, almost enclosed by a thin, immovable wall, in which there is a small perforation establishing a communication between the interior and exterior gas. An approximate theory, based upon the supposition that the perforation is small, and consequently that the wave-length of the aërial vibration is great, is due to Helmholtz, who arrived at definite results for perforations whose outline is circular or elliptic. A simplified, and in some respects generalised, treatment was given in my paper on “Resonance.” In the extreme case of a wavelength sufficiently great, the kinetic energy of the vibration is that of the gas near the mouth as it moves in and out, much as an incompressible fluid might do, and the potential energy is that of the almost uniform compressions and rarefactions of the gas in the interior. The latter is a question merely of the volume S of the cavity and of the quantity of gas which has passed, but the calculation of the kinetic energy presents difficulties which have been only partially overcome. In the case of simple apertures in the thin wall (regarded as plane), only circular and elliptic forms admit of complete treatment. The mathematical problem is the same as that of finding the electrostatic capacity of a thin conducting plate having the form of the aperture, and supposed to be situated in the open.
The project of a stricter treatment of the problem, in the case of a spherical wall and an aperture of circular outline, has been in my mind more than 40 years, partly with the hope of reaching a closer approximation, and partly because some mathematicians have found the former method unsatisfactory, or, at any rate, difficult to follow.
With all its advantages, the division of labour, so much accentuated in modern times, tends to carry with it a regrettable division of information. Much that is familiar to theorists and experimenters in laboratories percolates slowly into the workshop, and, what is more to my present purpose, much practical knowledge gained in the workshop fails to find its way into print. At the moment I am desirous of further information on two matters relating to the working of glass in which I happen to be interested, and I am writing in the hope that some of your readers may be able to assist.
Almost the only discussion that I have seen of the cutting of glass by the diamond is a century old, by the celebrated W. H. Wollaston (Phil. Trans. 1816, p. 265).
In his recent paper on the Photometry of Lights of Different Colours Mr H. Ives remarks:—“No satisfactory theory of the action of the flicker photometer can be said to exist. What does it actually measure? We may assume the existence of a ‘luminosity sense’ distinct from the colour sense.… If, for instance, there exists a physiological process called into action both by coloured and uncoloured light, a measure of this would be a measure of a common property.”
Very many years ago it occurred to me that the adjustment of the iris afforded just such a “physiological process”. The iris contracts when the eye is exposed to a bright red or to a bright green light. There must therefore be some relative brightness of the two lights which tends equally to close the iris, and this may afford the measure required. The flicker adjustment is complete when the iris has no tendency to alter under the alternating illumination.
This question was brought home to me very forcibly, when in 1875 I fitted the whole area of the window of a small room with revolving sectors after the manner of Talbot. The intention was to observe, more conveniently than when the eye is at a small hole, the movements of vibrating bodies. The apparatus served this purpose well enough; but incidentally I was much struck with the remarkably disagreeable and even painful sensations experienced when at the beginning or end of operations the slits were revolving slowly so as to generate flashes at the rate of perhaps 3 or 4 per second.
I regret that I overlooked Prof. Bayliss's letter in Nature of October 17, in which he made an appeal for my opinion. But, if I rightly understand, the question at issue seems to be mainly one of words. Can we properly speak of the propagation of sound through an incompressible fluid? I should answer, Yes. There may be periodic motion and periodic variation of pressure; the fact that there are no variations of density seems immaterial. Consider plane waves, corresponding with a pure tone, travelling through air. In every thin layer of air—and thin means thin relatively to the wavelength—there are periodic motion and periodic compression, approximately uniform throughout the layer. But the compression is not essential to the travelling of the sound. The substitution of an incompressible fluid of the same density for the gas within the layer would be no hindrance. Although there is no compression, there remain a periodic pressure and a periodic motion, and these suffice to carry on the sound.
The case is even simpler if we are prepared to contemplate an incompressible fluid without mass, for then the layer need not be thin. The interposition of such a layer has absolutely no effect, the motion and pressure at the further side being the same as if the thickness of the layer were reduced to zero. To all intents and purposes the sound is propagated through the layer, though perhaps exception might be taken to the use of the word propagation.
As regards the ear, we have to consider the behaviour of water. From some points of view the difference between air and water is much more one of density than of compressibility.
Modern views respecting mechanical lubrication are founded mainly on the experiments of B. Tower, conducted upon journal bearings. He insisted upon the importance of a complete film of oil between the opposed solid surfaces, and he showed how in this case the maintenance of the film may be attained by the dragging action of the surfaces themselves, playing the part of a pump. To this end it is “necessary that the layer should be thicker on the ingoing than on the outgoing side,” which involves a slight displacement of the centre of the journal from that of the bearing. The theory was afterwards developed by 0. Reynolds, whose important memoir includes most of what is now known upon the subject. In a later paper Sommerfeld has improved considerably upon the mathematics, especially in the case where the bearing completely envelops the journal, and his exposition to be recommended to those who wish to follow the details of the investigation. Reference may also be made to Harrison, who includes the consideration of compressible lubricants (air).
In all these investigations the question is treated as two-dimensional. For instance, in the case of the journal the width—axial dimension—of the bearing must be large in comparison with the arc of contact, a condition not usually fulfilled in practice. But Michell has succeeded in solving the problem for a plane rectangular block, moving at a slight inclination over another plane surface, free from this limitation, and he has developed a system of pivoted bearings with valuable practical results.
It is singular that the explanation of some of the most striking and beautiful of optical phenomena should be still matters of controversy. I allude to the brilliant colours displayed by many birds (e.g. hummingbirds), butterflies, and beetles, colours which vary greatly with the incidence of the light, and so cannot well be referred to the ordinary operation of dyes. In an early paper, being occupied at the time with the remarkable coloured reflexions from certain crystals of chlorate of potash described by Stokes, and which I attributed to a periodic twinning, I accepted, perhaps too hastily, the view generally current among naturalists that these colours were “structurecolours,” more or less like those of thin plates, as in the soap-bubble. Among the supporters of this view in more recent times may be especially mentioned Poulton and Hodgkinson. In Poulton's paper the main purpose was to examine the history of the very remarkable connexion between the metallic colours of certain pupse (especially Vanessa urticce) and the character of the light to which the larvae are exposed before pupation. In a passage describing the metallic colour itself he remarks:
“The Nature of Effects Produced.—The gilded appearance is one of the most metal-like appearances in any non-metallic substance. The optical explanation has never been understood. It has, however, been long known that it depends upon the cuticle, and needs the presence of moisture, and that it can be renewed when the dry cuticle is moistened. Hence it can be preserved for any time in spirit.
That this work should have already reached a fourth edition speaks well for the study of mathematical physics. By far the greater part of it is entirely beyond the range of the books available a generation ago. And the improvement in the style is as conspicuous as the extension of the matter. My thoughts naturally go back to the books in current use at Cambridge in the early sixties. With rare exceptions, such as the notable one of Salmon's Conic Sections and one or two of Boole's books, they were arid in the extreme, with scarcely a reference to the history of the subject treated, or an indication to the reader of how he might pursue his study of it. At the present time we have excellent books in English on most branches of mathematical physics and certainly on many relating to pure mathematics.
The progressive development of his subject is often an embarrassment to the writer of a text-book. Prof. Lamb remarks that his “work has less pretensions than ever to be regarded as a complete account of the science with which it deals. The subject has of late attracted increased attention in various countries, and it has become correspondingly difficult to do justice to the growing literature. Some memoirs deal chiefly with questions of mathematical method and so fall outside the scope of this book; others though physically important hardly admit of a condensed analysis; others, again, owing to the multiplicity of publications, may unfortunately have been overlooked. And there is, I am afraid, the inevitable personal equation of the author, which leads him to take a greater interest in some branches of the subject than in others.”
Having been honoured with an invitation to attend the Conference at Brussels, I feel that the least that I can do is to communicate my views, though I am afraid I can add but little to what has been already said upon the subject.
I wish to emphasize the difficulty mentioned in my paper of 1900 with respect to the use of generalized coordinates. The possibility of representing the state of a body by a finite number of such (short at any rate of the whole number of molecules) depends upon the assumption that a body may be treated as rigid, or incompressible, or in some other way simplified. The justification, and in many cases the sufficient justification, is that a departure from the simplified condition would involve such large amounts of potential energy as could not occur under the operation of the forces concerned. But the law of equi-partition lays it down that every mode is to have its share of kinetic energy. If we begin by supposing an elastic body to be rather stiff, the vibrations have their full share and this share cannot be diminished by increasing the stiffness. For this purpose the simplification fails, which is as much as to say that the method of generalized coordinates cannot be applied. The argument becomes, in fact, self-contradictory.
Perhaps this failure might be invoked in support of the views of Planck and his school that the laws of dynamics (as hitherto understood) cannot be applied to the smallest parts of bodies. But I must confess that I do not like this solution of the puzzle.