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The nature of the clue by which we are able to pronounce whether a sound of low pitch reaches us from the right or from the left was long a mystery, seeing that in such cases the difference of intensities at the two ears, used singly, is inappreciable. By some special laboratory experiments conducted about three years ago, I was able to show that the discrimination depends upon the phase-difference at the two ears, and that the sound is judged to be on that side where the phase is in advance. When the pitch is higher (much above g′) no distinct lateral effect accompanies a phase-difference, and the discrimination of right and left in ordinary hearing undoubtedly depends upon intensities. Commenting on these results, I remarked [p. 356]: “The conclusion, no longer to be resisted, that when a sound of low pitch reaches the two ears with approximately equal intensities, but with a phase-difference of a quarter of a period, we are able so easily to distinguish at which ear the phase is in advance, must have far-reaching consequences in the theory of audition. It seems no longer possible to hold that the vibratory character of sound terminates at the outer ends of the nerves along which the communication with the brain is established.
It is some thirty years ago since I executed a rather extensive series of experiments in order to ascertain more precisely what are the capabilities of the ears in estimating the direction of sounds. It appeared that when the alternative was between right and left, the discrimination could be made with certainty and without moving the head, even although the sounds were pure tones. Nor was any difficulty introduced by the requirement that the ears should be stopped at the moment when the sounds commenced.
On the other hand, if the question was whether a sound were situated in front or behind the observer, no pronouncement could be made in the case of pure tones. The impossibility of distinguishing front and back carries with it further confusions relating to cases where the sound may be obliquely situated. But with sounds of other character and notably with the speaking voice, front and back could often be distinguished. It is understood, of course, that the head was kept still. A slight rotation, bringing a pure tone (originally situated exactly in front or exactly behind) to the right or the left, gives the information that was previously lacking.
The discrimination between right and left is usually supposed to be explicable by the greater intensity of sensation experienced by the ear which lies nearer to the sound. When the pitch is pretty high, there is no doubt that this explanation is adequate.
The importance which these rings have acquired in recent years, owing to the researches of [Lummer], Michelson, and of Fabry and Perot, lends interest to the circumstances of their discovery. It seems to be usually supposed that Haidinger merely observed the rings, without a full appreciation of the mode of formation. Thus Mascart writes: “C'est par ce procédé, que Haidinger les a observées le premier avec une lame de mica, mais sans en donner la véritable explication.” A reference to the original papers will, I think, show that Haidinger, in spite of one or two slips, understood the character of the rings very well, and especially the distinction between them and the rings usually named after Newton and dependent upon a variable thickness in the thin plate.
In the first memoir (Pogg. Ann. LXXVII. p. 219, 1849) the bands formed by reflexion are especially discussed. A spirit-flame with salted wick, seen by reflexion at considerable obliquity in a mica plate, is traversed by approximately straight bands running perpendicularly to the plane of incidence. Talbot had observed phenomena in many respects similar…. But the yellow and black lines, observed by Talbot in thin blown glass, differ in character from the lines from mica, though both are dependent upon the interference of light. In the case of the glass the interference is due to the fact that the thickness of the glass is variable, and the lines are localised at the plate.
Dr Edridge-Green has introduced a method of classifying colour-vision by determining the number of separate parts or divisions in the spectrum within each of which the observer can perceive no colour difference. Movable screens are provided in the focal plane of the spectroscopic telescope, by which the part admitted to the eye is limited and the limits measured in terms of wave-length. Beginning at the extreme visible red, more and more of the spectrum is admitted until a change of colour (not merely of brightness) is just perceptible. This gives the first division. The second division starts from the place just determined, and is limited in the direction of shorter wave-length by the same condition. In this way the whole spectrum is divided into a number of contiguous divisions, or patches, which Dr Edridge-Green terms monochromatic. It will be observed that the delimitation of these patches includes an arbitrary element depending on the point from which the start is made—in this case the extreme red.
In the memoir, above reprinted from the Philosophical Magazine, I discussed the theories of Abbe and Helmholtz, and endeavoured to show their correlation. It appeared that the method of the former, while ingenious and capable of giving interesting results in certain directions, was inapplicable to many of the problems which it is necessary to attack. As an example of this, it may suffice to mention the case of a self-luminous object.
The work of Helmholtz, to which attention has recently been recalled by Mr. J. W. Gordon in a lively criticism (p. 381), was founded upon the processes already developed by Airy, Verdet, and others for the performance of the telescope. The theories both of Abbe and Helmholtz pointed to a tolerably definite limit to the powers of the Microscope, dependent, however, upon the wave-length of the light employed and upon the medium in which the object is imbedded. It appeared that two neighbours, whether constituting a single pair of points or forming part of an extended series of equidistant points, could not be properly distinguished if the distance were less than half the wave-length of the light employed. The importance of this conclusion, as imposing a limit upon our powers of direct observation, can hardly be overestimated; but there has been in some quarters a tendency to ascribe to it a more precise character than it can bear, or even to mistake its meaning altogether.
The boiling-point of argon being intermediate between those of nitrogen and oxygen, it may be expected that any operations of evaporation and condensation which increase the oxygen relatively to the nitrogen will at the same time increase the argon relatively to the nitrogen and diminish it relatively to the oxygen. In the experiments about to be detailed the gas analysed was that given off from liquid air, either freshly collected, or after standing (with evaporation) for some time—from a day to a week. The analyses were for oxygen and for argon, and were made upon different, though similar, samples. Thus after an analysis of a sample for oxygen by Hempel's method with copper and ammonia, 4 or 5 litres would be collected in a graduated holder, and then the first analysis confirmed on a third sample. In no case, except one to be specified later, was the quantity of gas withdrawn sufficient to disturb sensibly the composition. The liquid was held in Dewar's vessels, but the evolution of gas from below was always sufficient to keep the mass well mixed.
The examination for argon was made in a large test-tube inverted over alkali, into which the gas was fed intermittently from the holder. The nitrogen was gradually oxidized by the electric discharge from a Ruhmkorff coil in connexion with the public supply of alternating current, the proportion of oxygen being maintained suitably by additions of oxygen or hydrogen as might be required.
According to the discovery of Kerr, a layer of bisulphide of carbon, bounded by two parallel plates of metal and thus constituting the dielectric of a condenser or leyden, becomes doubly refracting when the leyden is charged. The plates, situated in vertical planes, may be of such dimensions as 18 cm. long, 3 cm. high, and the interval between them may be 0.3 cm., the line of vision being along the length and horizontal. If the polarising and analysing nicols be set to extinction, with their principal planes at 45° to the horizontal, there is revival of light when the leyden is charged. If the leyden remain charged for some time and be then suddenly discharged, and if the light under observation be sensibly instantaneous, it will be visible if the moment of its occurrence be previous to the discharge; if, however, this moment be subsequent to the discharge, the light will be invisible. The question now suggests itself, what will happen if the instantaneous light be that of the spark by which the leyden is discharged? It is evident that the conditions are of extraordinary delicacy, and involve the duration of the spark, however short this may be. The effect requires the simultaneity of light and double refraction, whereas here, until the double refraction begins to fail, there is no light to take advantage of.
Apart from the above and other causes of disturbance, a line in the spectrum of a radiating gas would be infinitely narrow. A good many years ago, in connection with some estimates by Ebert, I investigated the widening of a line in consequence of the motion of molecules in the line of sight, taking as a basis Maxwell's well-known law respecting the distribution of velocities among colliding molecules, and I calculated the number of interference-bands to be expected, upon a certain supposition as to the degree of contrast between dark and bright parts necessary for visibility. In this investigation no regard was paid to the collisions; the vibrations issuing from each molecule being supposed to be maintained with complete regularity for an indefinite time.
Although little is known with certainty respecting the genesis of radiation, it has long been thought that collisions act as another source of disturbance. The vibrations of a molecule are supposed to remain undisturbed while a free path is described, but to be liable to sudden and arbitrary alteration of phase and amplitude when another molecule is encountered. A limitation in the number of vibrations executed with regularity necessarily implies a certain indeterminateness in the frequency, that is a dilatation of the spectrum line. In its nature this effect is independent of the Doppler effect—for example, it will be diminished relatively to the latter if the molecules are smaller; but the problem naturally arises of calculating the conjoint action of both causes upon the constitution of a spectrum line.
The subject of the densities of gases has engaged a large part of my attention for over 20 years. In 1882 in an address to the British Association I suggested that the time had come for a redetermination of these densities, being interested in the question of Prout's law. At that time the best results were those of Regnault, according to whom the density of oxygen was 15·96 times that of hydrogen. The deviation of this number from the integer 16 seemed not to be outside the limits of experimental error.
In my work, as in the simultaneous work of Cooke, the method of Regnault was followed in that the working globe was counterpoised by a dummy globe (always closed) of the same external volume as itself. Under these conditions we became independent of fluctuations of atmospheric density. The importance of this consideration will be manifest when it is pointed out that in the usual process of weighing against brass or platinum weights, it might make more apparent difference whether the barometer were high or low than whether the working globe were vacuous or charged with hydrogen to atmospheric pressure. Cooke's result, as at first announced, was practically identical with that of Regnault, but in the calculations of both these experimenters a correction of considerable importance had been overlooked. It was assumed that the external volume of the working globe was the same whether vacuous or charged to atmospheric pressure, whereas of course the volume must be greater in the latter case.
According to Fresnel's theory the polarization is complete when light is reflected at the Brewsterian angle (tan−1 µ) or, as we may put it, light vibrating in the plane of incidence is not reflected at all at the angle in question. It has long been known that this conclusion is but approximately correct. If we attempt to extinguish with a nicol sunlight reflected from ordinary glass, we find that at no angle of incidence and reflexion can we succeed. It is difficult even to fix upon an angle of minimum reflexion with any precision.
The interpretation of these deviations from Fresnel's laws is complicated by uncertainties as to the nature of surfaces of transition from one medium to another. It is certain that many, if not all, surfaces attract to themselves films of moisture and grease from the surrounding atmosphere, and the opinion has been widely held that even in the absence of moisture and grease solid bodies are still coated with films of condensed air. Other complications depend upon possible or probable residues of the polishing material used in the preparation of optical surfaces. It was mainly for these reasons that I gave much attention some years ago to the case of reflexion from water, where at any rate there was no question of a polishing powder and atmospheric moisture could introduce no complication.
In common with so many distinguished men Sir George Stokes was the son of a clergyman. His father, Gabriel Stokes, who was Rector of Skreen, County Sligo, married Elizabeth Haughton, and by her had eight children of whom George was the youngest. The family can be traced back to Gabriel Stokes, born 1680, a well known engineer in Dublin and Deputy Surveyor General of Ireland, who wrote a treatise on Hydrostatics and designed the Pigeon House Wall in Dublin Harbour. This Gabriel Stokes married Elizabeth King in 1711 and among his descendants in collateral branches there are several mathematicians, a Regius Professor of Greek, two Regius Professors of Medicine, and a large sprinkling of scholars of Trinity College, Dublin. In more recent times Margaret Stokes, the Irish Antiquary, and the Celtic scholar, Whitley Stokes, children of the eminent physician, Dr William Stokes, have, among others, shed lustre on the name.
The home at Skreen was a very happy one. In the excellent sea air the children grew up with strong bodies and active minds. Of course great economy had to be practised to meet the educational needs of the family; but in the Arcadian simplicity of a place where chickens cost sixpence and eggs were five or six a penny, it was easy to feed them. They were all deeply attached to their mother, a beautiful and severe woman who made herself feared as well as loved.
A recent voyage round Africa recalled my attention to interesting problems connected with the colour of the sea. They are not always easy of solution in consequence of the circumstance that there are several possible sources of colour whose action would be much in the same direction. We must bear in mind that the absorption, or proper, colour of water cannot manifest itself unless the light traverse a sufficient thickness before reaching the eye. In the ocean the depth is of course adequate to develop the colour, but if the water is clear there is often nothing to send the light back to the observer. Under these circumstances the proper colour cannot be seen. The much admired dark blue of the deep sea has nothing to do with the colour of water, but is simply the blue of the sky seen by reflection. When the heavens are overcast the water looks grey and leaden; and even when the clouding is partial, the sea appears grey under the clouds, though elsewhere it may show colour. It is remarkable that a fact so easy of observation is unknown to many even of those who have written from a scientific point of view. One circumstance which may raise doubts is that the blue of the deep sea often looks purer and fuller than that of the sky.