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In a recent memoir Mr Love has considered this question among others; but he has not discussed his result {equation (95)}, except in its application to a rather special case involving the existence of a free edge. When the cylinder is regarded as infinitely long, the problem is naturally of a simpler character; and I have thought that it might be worth while to express more fully the frequency equation, as applicable to all vibrations, independent of the thickness of the shell, which are periodic with respect both to the length and the circumference of the cylinder.
In order to prevent misunderstanding, it may be well to premise that the vibrations, whose frequency is to be determined, do not include the gravest of which a thin shell is capable. If the middle surface be simply bent, the potential energy of deformation is of a higher order of magnitude than in the contrary case, and according to the present method of treatment the frequency of vibration will appear to be zero. It is known, however, that the only possible modes of bending of a cylindrical shell are such as are not periodic along the length, or rather have the wave-length in this direction infinitely long. When the middle surface is stretched, as well as bent, the potential energy of bending may be neglected, except in certain very special cases.
Since the time of Young the tendency of a liquid surface to contract has always been attributed to the mutual attraction of the parts of the liquid, acting through a very small range,—to the same forces in fact as those by which the cohesion of liquids and solids is to be explained. It is sometimes asserted that Laplace was the first to look at the matter from this point of view, and that Young contented himself with calculations of the consequences of superficial tension. Such an opinion is entirely mistaken, although the authority of Laplace himself may be quoted in its favour. In the introduction to his first paper, which preceded the work of Laplace, Young writes:—“It will perhaps be more agreeable to the experimental philosopher, although less consistent with the strict course of logical argument, to proceed in the first place to the comparison of this theory [of superficial tension] with the phenomena, and to inquire afterwards for its foundation in the ultimate properties of matter.” This he attempts to do in Section VI., which is headed Physical Foundation of the Law of Superficial Cohesion. The argument is certainly somewhat obscure; but as to the character of the “physical foundation” there can be no doubt.
The motion upon the surface of water of small camphor scrapings, a phenomenon which had puzzled several generations of inquirers, was satisfactorily explained by Van der Mensbrugghe as due to the diminished surface-tension of water impregnated with that body. In order that the rotations may be lively, it is imperative, as was well shown by Mr Tomlinson, that the utmost cleanliness be observed. It is a good plan to submit the internal surface of the vessel to a preliminary treatment with strong sulphuric acid. A touch of the finger is usually sufficient to arrest the movements by communicating to the surface of the water a film of grease. When the surface-tension is thus lowered, the differences due to varying degrees of dissolved camphor are no longer sufficient to produce the effect.
It is evident at once that the quantity of grease required is excessively small, so small that under the ordinary conditions of experiment it would seem likely to elude our methods of measurement. In view, however, of the great interest which attaches to the determination of molecular magnitudes, the matter seemed well worthy of investigation; and I have found that by sufficiently increasing the water surface the quantities of grease required may be brought easily within the scope of a sensitive balance.
In the present experiments the only grease tried is olive oil. It is desirable that the material which is to be spread out into so thin a film should be insoluble, involatile, and not readily oxidised, requirements which greatly limit the choice.
The interest of the subject which I propose to bring before you this evening turns principally upon the connection or analogy between light and sound. It has been known for a very long time that sound is a vibration; and every one here knows that light is a vibration also. The last piece of knowledge, however, was not arrived at so easily as the first; and one of the difficulties which retarded the acceptance of the view that light is a vibration was that in some respects the analogy between light and sound seemed to be less perfect than it should be. At the present time many of the students at our schools and universities can tell glibly all about it; yet this difficulty is one not to be despised, for it exercised a determining influence over the great mind of Newton. Newton, it would seem, definitely rejected the wave theory of light on the ground that according to such a theory light would turn round the corners of obstacles, and so abolish shadows, in the way that sound is generally supposed to do. The fact that this difficulty seemed to Newton to be insuperable is, from the point of view of the advancement of science, very encouraging. The difficulty which stopped Newton two centuries ago is no difficulty now. It is well known that the question depends upon the relative wave-lengths in the two cases.
During the past year I have continued the work described in a former communication on the relative densities of hydrogen and oxygen, in the hope of being able to prepare lighter hydrogen than was then found possible. To this end various modifications have been made in the generating apparatus. Hydrogen has been prepared from potash in place of acid. In one set of experiments the gas was liberated by aluminium. In this case the generator consisted of a large closed tube sealed to the remainder of the apparatus; and the aluminium was attached to an iron armature so arranged that by means of an external electro-magnet it was possible to lower it into the potash, or to remove it therefrom. The liberated gas passed through tubes containing liquid potash, corrosive sublimate, finely powdered solid potash, and, lastly, a long length of phosphoric anhydride. But the result was disappointing; for the hydrogen proved to be no lighter than that formerly obtained from sulphuric acid.
I have also tried to purify hydrogen yet further by absorption in palladium. In his recent important memoir, “On the Combustion of weighed Quantities of Hydrogen and the Atomic Weight of Oxygen,” Mr Keiser describes experiments from which it appears that palladium will not occlude nitrogen—a very probable impurity in even the most carefully prepared gas. My palladium was placed in a tube sealed, as a lateral attachment, to the middle of that containing the phosphoric anhydride; so that the hydrogen was submitted in a thorough manner to this reagent both before and after absorption by the palladium.
Under this head may conveniently be considered not only the apparent displacement of the stars discovered by Bradley, but other kindred phenomena dependent upon the velocity of light bearing but a finite ratio to that of the earth in its orbit round the sun, and to other astronomical velocities.
The explanation of stellar aberration, as usually given, proceeds rather upon the basis of the corpuscular than of the wave theory. In order to adapt it to the principles of the latter theory, Fresnel found it necessary to follow Young in assuming that the æther in any vacuous space connected with the earth (and therefore practically in the atmosphere) is undisturbed by the earth's motion of 19 miles per second. Consider for simplicity the case in which the direction of the star is at right angles to that of the earth's motion, and replace the telescope, which would be used in practice, by a pair of perforated screens, on which the light falls perpendicularly. We may further imagine the luminous disturbance to consist of a single plane pulse. When this reaches the anterior screen, so much of it as coincides with the momentary position of the aperture is transmitted, and the remainder is stopped. The part transmitted proceeds upon its course through the æther independently of the motion of the screens. In order, therefore, that the pulse may be transmitted by the aperture in the posterior screen, it is evident that the line joining the centres of the apertures must not be perpendicular to the screens and to the wave front, as would have been necessary in the case of rest.
Allow me to suggest to such of your readers as are interested in this subject the following experiment. Cut out of cardboard two annular strips, each of somewhat more than a quadrant, the inner radius being, say, 7 inches, and the outer radius 9 inches. Along the middle of each strip—that is, along the circle of 8 inches radius—cut the boards half through, so as to render them flexible, and then join the two strips together with gum paper at the inner and outer edges. In this way we obtain a curved tube whose section is a rhombus, and whose curvature is connected with the magnitudes of the angles of the rhombus. The manipulation of such a tube gives definiteness to one's ideas, and enables one to recognize that internal pressure, tending to augment the included volume, and therefore to make the section square, must also cause the curvature of the axis to approach a definite associated value. In this case the deformations are practically by bending, principally indeed at the hinges; and I cannot doubt that in its main features the mechanism of an ordinary Bourdon gauge may be looked at in the same light.
The gratitude with which we receive these fine volumes is not unmingled with complaint. During the eleven years which have elapsed since the master left us, the disciples have not been idle, but their work has been deprived, to all appearance unnecessarily, of the assistance which would have been afforded by this collection of his works. However, it behoves us to look forward rather than backward; and no one can doubt that for many years to come earnest students at home and abroad will derive inspiration from Maxwell's writings, and will feel thankful to Mr Niven and the committee of friends and admirers for the convenient and handsome form in which they are here presented.
Under the modest title of preface, the editor contributes a sketch of Maxwell's life, which will be valued even by those who are acquainted with the larger work of Profs. Lewis Campbell and W. Garnett; and while abstaining from entering at length into a discussion of the relation which Maxwell's work bears historically to that of his predecessors, or attempting to estimate the effect which it had upon the scientific thought of the present day, he points out under the various heads what were the leading advances made.
In the body of the work the editor's additions reduce themselves to a few useful footnotes, placed in square brackets. Doubtless there is some difficulty in knowing where to stop, but the number of these footnotes might, I think, have been increased.
The subject of this memoir is of especial interest at the present time, when the skill of a distinguished inventor is understood to be engaged in attacking the many practical difficulties which lie in the way of artificial flight upon a large scale. For a long time the resistance of fluids formed an unsatisfactory chapter in our treatises on hydrodynamics. According to the early suggestions of Newton, the resistances are (1) proportional to the surfaces of the solid bodies acted upon, to the densities of the fluids, and to the squares of the velocities: while (2) “the direct impulse of a fluid on a plane surface is to its absolute oblique impulse on the same surface as the square of the radius to the square of the sine of the angle of incidence.” The author of the work from which these words are quoted, in comparing the above statements with the experimental results available in his time (1822), remarks:—“(1) It is very consonant to experiment that the resistances are proportional to the squares of the velocities.… (2) It appears from a comparison of all the experiments, that the impulses and resistances are very nearly in the proportion of the surfaces.… (3) The resistances do by no means vary in the duplicate ratio of the sines of the angle of incidence.” And he subsequently states that for small angles the resistances are more nearly proportional to the sines of incidence than to their squares.
In his interesting Address to the American Association for the Advancement of Science, Prof. Langley sketches the development of the modern doctrine of Radiant Energy, and deduces important lessons to be laid to heart by all concerned in physical investigation. This is a most useful undertaking; but in the course of it there occur one or two statements which, in the interest of scientific history, ought not to be allowed to pass without a protest.
After quoting Melloni's very unequivocal conclusion of 1843, that “Light is merely a series of calorific indications sensible to the organs of sight; or, vice versâ, the radiations of obscure heat are veritable invisible radiations of light,” Prof. Langley goes on to say, “So far as I know, no physicist of eminence reasserted Melloni's principle with equal emphasis till J. W. Draper, in 1872. Only sixteen years ago, or in 1872, it was almost universally believed that there were three different entities in the spectrum, represented by actinic, luminous, and thermal rays.”
These words struck me strangely as I first read them. My own scientific ideas were formed between 1860 and 1866, and I certainly never believed in the three entities. Having on a former occasion referred to this question as an illustration of the difference of opinion which is sometimes to be found between the theoretical and experimental schools of workers, I was sufficiently interested in the matter to look up a few references, with results which are, I think, difficult to reconcile with Prof. Langley's view.
The investigations, of which a part is here presented, had their origin in a conviction that the present rather unsatisfactory position of the Theory of Gases is due in some degree to a want of preparation in the mind of readers, who are confronted suddenly with ideas and processes of no ordinary difficulty. For myself, at any rate, I may confess that I have found great advantage from a more gradual method of attack, in which effort is concentrated upon one obstacle at a time. In order to bring out fundamental statistical questions, unencumbered with other difficulties, the motion is here limited to one dimension, and in addition one set of impinging bodies is supposed to be very small relatively to the other. The simplification thus obtained in some directions allows interesting extensions to be made in others. Thus we shall be able to follow the whole process by which the steady state is attained, when heavy masses originally at rest are subjected to bombardment by projectiles fired upon them indifferently from both sides. The case of pendulums, or masses moored to fixed points by elastic attachments, is also considered, and the stationary state attained under a one-sided or a two-sided bombardment is directly calculated.
In former papers I have investigated the character of the equilibrium of a cylindrical fluid column under the action of capillary force. If the column become varicose with wave-length λ, the equilibrium is unstable, provided λ exceed the circumference (2πα) of the cylinder; and the degree of instability, as indicated by the value of q in the exponential eqt to which the motion is proportional, depends upon the value of λ, reaching a maximum when λ = 4·51 × 2a. In these investigations the external pressure is supposed to be constant; and this is tantamount to neglecting the inertia of the surrounding fluid.
When a column of liquid is surrounded by air, the neglect of the inertia of the latter will be of small importance; but there are cases where the situation is reversed, and where it is the inertia of the fluid outside rather than of the fluid inside the cylinder which is important. The phenomenon of the disruption of a jet of air delivered under water, easily illustrated by instantaneous photography [Vol. III. p. 443], suggests the consideration of the case where the inside inertia may be neglected; and to this the present paper is specially directed. For the sake of comparison the results of the former problem are also exhibited.
These photographs were taken by the light of the electric spark. A battery of Leyden jars was charged by a Wimshurst machine, and discharged itself between brass balls, held half an inch apart, in the optical lantern. By means of a large condenser a good proportion of light was concentrated upon the lens of the camera. The jet of water, regularized by a tuning-fork, fell in front of the condenser, and was focused upon the photographic plate.
In the absence of anything to diffuse the light, the pictures are simple shadows, such as have been obtained without any optical appliances by Mr Bell and Mr Boys. The only detail is due to the lens-like action of the jets and the drops into which it is resolved. This arrangement is quite sufficient to illustrate the behaviour of electrified jets. But the interposition of a plate of ground glass close to the condenser effects a great improvement in the pictures by bringing out half-tones, and the results printed on aristotype paper are now very good. The only difficulty is that due to loss of light. In some of the experiments it was found advantageous to diminish the diffusion by slightly oiling the ground glass.
The degree of instantaneity required depends upon circumstances. In some cases the outlines would have lost their sharpness had the exposure exceeded second. It is probable that the actual duration of the principal illumination was decidedly less than this.
In the first part of the paper published under the above title (Phil. Mag. Oct. and Dec. 1890 [Vol. iii. p. 397]) the theory of Young and Laplace was considered, and further developed in certain directions. The two leading assumptions of this theory are (1) that the range of the cohesive forces, though very small in comparison with the dimensions of ordinary bodies, is nevertheless large in comparison with molecular distances, so that matter may be treated as continuous; and (2) that the fluids considered are incompressible. So far as I am aware, there is at present no reason to suppose that the applicability of the results to actual matter is greatly prejudiced by imperfect fulfilment of (1); but, on the other hand, the assumption of incompressibility is a somewhat violent one, even in the cases of liquids, and altogether precludes the application of the theory to gases and vapours. In the present communication an attempt is made to extend the theory to compressible fluids, and especially to the case of a liquid in contact with its own vapour, retaining the first assumption of continuity, or rather of ultimate homogeneity. There will not be two opinions as to the advantage of the extension to compressible fluids; but some may perhaps be inclined to ask whether it is worth while to spend labour upon a theory which ignores the accumulated evidence before us in favour of molecular structure.