Hostname: page-component-76fb5796d-2lccl Total loading time: 0 Render date: 2024-04-28T23:56:42.412Z Has data issue: false hasContentIssue false

On the possibility of complete condensation shock waves in retrograde fluids

Published online by Cambridge University Press:  29 March 2006

Philip A. Thompson
Affiliation:
School of Engineering, Rensselaer Polytechnic Institute, Troy, New York Present address: Max-Planck-Institut für Strömungsforschung, Göttingen, West Germany.
Daniel A. Sullivan
Affiliation:
Gas Turbine Division, General Electric Company, Schenectady, New York

Abstract

Shock discontinuities for which the upstream state is vapour and the downstream state is liquid are considered. The possibility of such shock waves is associated with a large number of molecular degrees of freedom: it is necessary that the ideal-gas specific heat cv [ges ] 24R at the critical temperature, a condition which is met by several common fluids. Shock properties are found from a corresponding-states thermodynamic model and from several calculations based on data for particular fluids. Condensation shock waves satisfy the usual stability conditions and should be found in laboratory experiments.

Type
Research Article
Copyright
© 1975 Cambridge University Press

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Barker, J. A., Leonard, P. J. & Pompe, A. 1966 Fifth virial coefficients. J. Chem. Phys. 44, 42064211.Google Scholar
Bethe, H. A. 1942 The theory of shock waves for an arbitrary equation of state. Office Sci. Res. & Dev., Washington, Rep. no. 545, p. 57.Google Scholar
Canjar, L. N. & Manning, F. S. 1967 Thermodynamic Properties and Reduced Correlations of Gases. Gulf Publishing Co.
Das, T. R. & Kuloor, N. R. 1967 Thermodynamic properties of hydrocarbons: part IV, N-octane. Indian J. Tech. 5 (2), 51–57.Google Scholar
Keenan, J. H., Keyes, F. G., Hill, P. G. & Moore, J. G. 1969 Steam Tables. Wiley.
Landau, L. D. & Lifshitz, E. M. 1959 Fluid Mechanics, p. 496. Pergamon.
Planck, M. 1903 Treatise on Thermodynamics, pp. 150–152. Longmans-Green.
Rackett, H. G. 1970 Equation of state for saturated liquids. J. Chem. Engng Data, 15, 514517.Google Scholar
Riedel, L. 1954 Eine neue universelle Dampfdruckformel. Chem.-Ing.-Tech. 26, 8389.Google Scholar
Saltanov, G. A., Tsiklauri, G. V. & Shanin, V. K. 1970 Shock waves in a flow of wet vapor with a high liquid phase content. High Temperature, 8, 533539.Google Scholar
Starling, K. E. 1973 Fluid Thermodynamic Properties for Light Petroleum Systems. Gulf Publishing Co.
Stever, H. G. 1958 Condensation phenomena in high speed flows. In Fundamentals of Gasdynamics (ed. H. W. Emmons), pp. 526–573. Princeton University Press.
Tsonopoulos, C. 1974 An empirical correlation of second virial coefficients. A.I.Ch.E. J. 20, 263272.Google Scholar
Zel-Dovich, Ya. B. & Raizer, Yu. P. 1967 Physics of Shock Waves and High-Temperature Hydrodynamic Phenomena, vol. 2 (ed. W. D. Hayes & R. F. Probstein), pp. 750–756. Academic.
Zellner, M. G., Claitor, L. C. & Prausnitz, J. M. 1970 Prediction of vapour—liquid equilibria and enthalpies of mixtures at low temperatures. Ind. Engng Chem. Fund. 9, 549564.Google Scholar