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Thermodynamics of liquids in capillary medium

Published online by Cambridge University Press:  03 November 2020

Ilyas Al-Kindi  and
Tayfun Babadagli Open the ORCID record for Tayfun Babadagli [Opens in a new window]
Ilyas Al-Kindi
Affiliation:
Department of Civil and Environmental Engineering, School of Mining and Petroleum, University of Alberta, 7-277 Donadeo Innovation Centre for Engineering, 9211 – 116th Street, Edmonton, Alberta, CanadaT6G 1H9
Tayfun Babadagli*
Affiliation:
Department of Civil and Environmental Engineering, School of Mining and Petroleum, University of Alberta, 7-277 Donadeo Innovation Centre for Engineering, 9211 – 116th Street, Edmonton, Alberta, CanadaT6G 1H9
*
†Email address for correspondence: tayfun@ualberta.ca
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Abstract

The phase behaviour of fluids at capillary conditions differs from that in bulk media. Therefore, understanding the thermodynamics of solvents in confined media is essential for modelling non-isothermal and non-isobaric engineering applications in porous media – including enhanced oil and heavy-oil recovery. The Thomson equation states that pore sizes have control over the boiling points of liquids in capillary channels. As pore spaces get smaller, boiling temperatures become lower than the normal boiling temperatures of the same liquids. The objective of this paper is to inspect this phenomenon by physically measuring the boiling points of different liquids at capillary conditions and comparing them with the values at bulk conditions and boiling temperatures obtained from the Thomson equation. Several types of microfluidic chips were used as capillary media to observe the phase-change behaviour of heptane, heptane–decane mixture and naphtha. Additionally, vaporization of water, heptane and decane was investigated in Berea sandstone, Indiana limestone, tight sandstone and shale. Pore size distribution analysis was performed to identify the pore diameter variations in each rock sample, and how the existence of extended nanopores in the rocks could impact the phase alteration.

JFM classification

Drops and Bubbles: Bubble dynamics Drops and Bubbles: Thermocapillarity
Type
JFM Papers
Information
Journal of Fluid Mechanics , Volume 905 , 25 December 2020 , A32
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Copyright
© The Author(s), 2020. Published by Cambridge University Press

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References

Al-Bahlani, A. M. & Babadagli, T. 2009 Laboratory and field scale analysis of steam over solvent injection in fractured reservoirs (SOS FR) for heavy oil recovery. In SPE's Annual Technical Conference and Exhibition, New Orleans, Louisiana. SPE-124047-MS. Society of Petroleum Engineers.CrossRefGoogle Scholar
Al-Bahlani, A. M. & Babadagli, T. 2011 Steam-over-solvent injection in fractured reservoirs (SOS-FR) technique as a new approach for heavy-oil and bitumen recovery: an overview of the method. Energy Fuels 25, 4528–4539.CrossRefGoogle Scholar
Al-Kindi, I. & Babadagli, T. 2018 Thermodynamics of hydrocarbon solvents at the pore scale during hybrid solvent-thermal application for heavy-oil recovery. In SPE EOR Conference at Oil and Gas West Asia, Muscat, Oman. SPE-190469-MS. Society of Petroleum Engineers.CrossRefGoogle Scholar
Al-Kindi, I. & Babadagli, T. 2019 a Revisiting Kelvin equation for accurate modeling of pore scale thermodynamics of different solvent gases. In SPE Western Regional Meeting, San Jose, California. SPE-195319-MS. Society of Petroleum Engineers.CrossRefGoogle Scholar
Al-Kindi, I. & Babadagli, T. 2019 b Revisiting Thomson equation for accurate modeling of pore scale thermodynamics of hydrocarbon solvents. Phys. Fluids 31 (12), 122004.CrossRefGoogle Scholar
Al-Kindi, I. & Babadagli, T. 2020 Effect of wettability on vaporization of hydrocarbon solvents in nano capillaries. In SPE Annual Technical Conference and Exhibition, Denver, Colorado. SPE-201258-MS. Society of Petroleum Engineers.CrossRefGoogle Scholar
Bao, B., Zandavi, S. H., Li, H., Zhong, J., Jatukaran, A., Mostowfi, F. & Sinton, D. 2017 Bubble nucleation and growth in nanochannels. Phys. Chem. Chem. Phys. 19 (12), 8223–8229.CrossRefGoogle ScholarPubMed
Barsotti, E., Tan, S. P., Saraji, S. & Chen, J. 2016 A review on capillary condensation in nanoporous media: implications for hydrocarbon recovery from tight reservoirs. Fuel 184, 344–361.CrossRefGoogle Scholar
Berg, J. C. 2009 Fluid interfaces and capillarity, an introduction to interfaces and colloids. World Sci. 936, 23–106.Google Scholar
Kolodzie, S. Jr. 1980 Analysis of pore throat size and use of the Waxman-Smits equation to determine OOIP in Spindle Field, Colorado. In SPE's Annual Technical Conference and Exhibition, Dallas, Texas. SPE-9382-MS. Society of Petroleum Engineers.CrossRefGoogle Scholar
Leyva-Gomez, H. & Babadagli, T. 2016 Efficiency of heavy oil/bitumen recovery from fractured carbonates by hot-solvent injection. In SPE Heavy Oil Conference and Exhibition, Kuwait City, Kuwait. SPE-184095-MS. Society of Petroleum Engineers.CrossRefGoogle Scholar
Leyva-Gomez, H. & Babadagli, T. 2018 Efficiency of heavy-oil/bitumen recovery from fractured carbonates by hot-solvent injection. J. Petrol. Sci. Eng. 165, 752–764.CrossRefGoogle Scholar
Lucia, F. J. 2007 Petrophysical rock properties. In Carbonate Reservoir Characterization: An Integrated Approach, pp. 1–27. Springer.Google Scholar
Marciales, A. & Babadagli, T. 2016 Pore scale visual investigations on solvent retrieval during oil recovery at elevated temperatures: a micromodel study. Chem. Engng Res. Des. 106, 59–73.CrossRefGoogle Scholar
Nasr, T. N., Beaulieu, G., Golbeck, H. & Heck, G. 2003 Novel expanding solvent-SAGD process “ES-SAGD. J. Can. Petrol. Technol. 42 (1), 13–16.CrossRefGoogle Scholar
Pathak, V., Babadagli, T. & Edmunds, N. 2012 Mechanics of heavy-oil and bitumen recovery by hot solvent injection. SPE Reserv. Eval. Engng 15 (2), 182–194.CrossRefGoogle Scholar
Tai, K. 2005 NanoFab glass microfludic device fabrication manual: complete process description and trouble-shooting guide (version 1.0). NanoFab, University of Alberta. Available at: https://www.nanofab.ualberta.ca/wp-content/uploads/downloads/2017/02/nanoFAB-Microfluidics-Manual-v-1.0.pdf.Google Scholar
Thome, J. R. 2004 Boiling in microchannels: a review of experiment and theory. Intl J. Heat Fluid Flow 25 (2), 128–139.CrossRefGoogle Scholar
Thomson, W. 1872 4. On the equilibrium of vapour at a curved surface of liquid. Proc. R. Soc. Edin. 7, 63–68.CrossRefGoogle Scholar
Tsukahara, T., Maeda, T., Hibara, A., Mawatari, K. & Kitamori, T. 2012 Direct measurements of the saturated vapor pressure of water confined in extended nanospaces using capillary evaporation phenomena. RSC Adv. 2 (8), 3184–3186.CrossRefGoogle Scholar
Zhong, J., Riordon, J., Zandavi, S. H., Xu, Y., Persad, A. H., Mostowfi, F. & Sinton, D. 2018 Capillary condensation in 8 nm deep channels. Phys. Chem. Lett. 9 (3), 497–503.CrossRefGoogle ScholarPubMed