Hostname: page-component-76fb5796d-25wd4 Total loading time: 0 Render date: 2024-04-28T21:40:03.371Z Has data issue: false hasContentIssue false
  • English
  • Français

Combustion synthesis and characterization of BaTiO3

Published online by Cambridge University Press:  03 March 2011

Zhimin Zhong  and
Patrick K. Gallagher
Zhimin Zhong
Affiliation:
Departments of Chemistry and Materials Science and Engineering, The Ohio State University, Columbus, Ohio 43210-1173
Patrick K. Gallagher
Affiliation:
Departments of Chemistry and Materials Science and Engineering, The Ohio State University, Columbus, Ohio 43210-1173
Get access

Abstract

An important, somewhat novel procedure for the bulk synthesis of finely divided crystalline BaTiO3 powder has been studied and is applicable to the synthesis of other compounds in the BaO-TiO2 system as well. An aqueous solution of Ba(NO3)2, TiO(NO3)2, and alanine is spray dried. A combustion reaction occurs when heating the product to 300 °C. The reaction converts the spray-dried mixture to BaTiO3. This BaTiO3 powder and its sinterability have been characterized by thermal analysis, XRD, SEM, dielectric, and particle size measurements. The powder resulting from the thermal runaway reaction is finely divided and sinters more readily than the conventionally prepared high purity BaTiO3.

Type
Articles
Information
Journal of Materials Research , Volume 10 , Issue 4 , April 1995 , pp. 945 - 952
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Xu, Y., Ferroelectric Materials and Their Applications (Elsevier, The Netherlands, 1991).Google Scholar
2Phule, P. P. and Risbud, S. H., J. Mater. Sci. 25, 1169 (1990).CrossRefGoogle Scholar
3Rhine, W. E., Hallock, R. B., Davis, W. M., and Wong-Ng, W., Chem. Mater. 4, 1208 (1992).CrossRefGoogle Scholar
4(a)Kourtakis, K., Robbins, M., and Gallagher, P. K., J. Solid State Chem. 82, 290 (1989); (b) 83, 230 (1989); (c) 84, 88 (1990); (d)Kourtakis, K., Robbins, M., Gallagher, P. K., and Tiefel, T., J. Mater. Res. 4, 1289 (1989).CrossRefGoogle Scholar
5Filkova, I. and Mujumdar, A. S., in Handbook of Industrial Drying: Industrial Spray Drying System, edited by Mujumdar, A. S. (Marcel Dekker Inc., New York, 1987), p. 243.Google Scholar
6(a)Merzhanov, A. G., in Combustion and Plasma Synthesis of High-Temperature Materials: Self-Propagating High-Temperature Synthesis: Twenty Years of Search and Findings, edited by Munir, Z. A. and Holt, J. B. (VCH, New York, 1990), p. 1. (b) H. C. Yi and J. J. Moore, J. Mater. Sci. 25, 1159 (1990).Google Scholar
7Yamamura, H., Watanabe, A., Shirasaki, S., Moriyoshi, Y., and Tanada, M., Ceram. Int. 11, 17 (1985).CrossRefGoogle Scholar
8Sekar, M.M. A. and Patil, K. C., J. Mater. Chem. 2, 739 (1992).CrossRefGoogle Scholar
9Suresh, K., Kumar, N. R. S., and Patil, K. C., Adv. Mater. 3, 148 (1991).CrossRefGoogle Scholar
10Grammatico, J. P. and Lopez, J. M. P., J. Mater. Sci.: Mater. Elec. 3, 82 (1992).Google Scholar
11Puhle, P. P. and Risbud, S. H., in Ultrastructure Processing of Advanced Materials: Synthesis and Processing of Alkaline Earth Metal, Titanate Gels, Powders, and Thin Films, edited by Uhlmann, D. R. and Ulrich, D. R. (John Wiley and Sons, New York, 1992), p. 277Google Scholar
12Dutta, P. K., Gallagher, P. K., and Twu, J., Chem. Mater. 5, 1739 (1993).CrossRefGoogle Scholar
13Yan, M. F., in Engineered Materials Handbook: Solid-State Sintering, Vol. 4, Ceramics and Glasses, edited by Lampman, S. R., Woods, M. S., and Zorc, T. B. (ASM INTERNATIONAL, Metals Park, OH, 1987), p. 270.Google Scholar
14Arlt, G., Hennings, D., and de With, G., J. Appl. Phys. 58, 1619 (1985).CrossRefGoogle Scholar
15Yen, F., Chang, C. T., and Chang, Y., J. Am. Ceram. Soc. 73, 3422 (1990).CrossRefGoogle Scholar
16Cullity, B. D., Elements of X-ray Diffraction, 2nd. ed. (Addison-Wesley, Reading, MA, 1978), pp. 102, 103, 284Google Scholar
17Allen, T., Particle Size Measurement, 3rd ed. (Chapman and Hall, New York, 1981), pp. 414, 606.CrossRefGoogle Scholar
18Carbone, T. J. and Reed, J. S., Am. Ceram. Soc. Bull. 58, 512 (1979).Google Scholar
19(a)Ozawa, T., Bull. Chem. Soc. Jpn. 38, 1881 (1965). (b) W.W. Wendlandt, Thermal Analysis, 3rd ed. (John Wiley and Sons, New York, 1986), p. 69.CrossRefGoogle Scholar
20Stein, A., Keller, S. W., and Mallouk, T. E., Science 259, 1558 (1993).CrossRefGoogle Scholar
21Lide, D. R., CRC Handbook of Chemistry and Physics, 74th ed. (CRC Press, Boca Raton, FL, 1993–1994), pp. 12–19, 12–20, etc.Google Scholar
22Kanata, T., Yoshikawa, T., and Kubota, K., Solid State Commun. 62, 765 (1987).CrossRefGoogle Scholar
23Zhong, Z. and Gallagher, P. K., unpublished.Google Scholar