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New insights on the crystalline forms in binary systems of n-alkanes: Characterization of the solid ordered phases in the phase diagram tricosane + pentacosane

Published online by Cambridge University Press:  31 January 2011

F. Rajabalee ,
V. Métivaud ,
D. Mondieig ,
Y. Haget  and
M. A. Cuevas-Diarte
F. Rajabalee*
Affiliation:
Centre de Physique Moléculaire Optique et Hertzienne, UMR 5798 au CNRS Université Bordeaux I, F-33405 Talence Cedex, France
V. Métivaud
Affiliation:
Centre de Physique Moléculaire Optique et Hertzienne, UMR 5798 au CNRS Université Bordeaux I, F-33405 Talence Cedex, France
D. Mondieig
Affiliation:
Centre de Physique Moléculaire Optique et Hertzienne, UMR 5798 au CNRS Université Bordeaux I, F-33405 Talence Cedex, France
Y. Haget
Affiliation:
Centre de Physique Moléculaire Optique et Hertzienne, UMR 5798 au CNRS Université Bordeaux I, F-33405 Talence Cedex, France
M. A. Cuevas-Diarte
Affiliation:
Departament de Cristal.lografia, Universitat de Barcelona, Marti i Franquès, E-08028 Barcelona, Spain
*
a)Address all correspondence to this author. e-mail: frajabal@frbdx11.cribx1.u-bordeaux.fr
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Abstract

X-ray diffraction analyses of the pure components n-tricosane and n-pentacosane and of their binary mixed samples have enabled us to characterize the crystalline phases observed at “low temperature.” Contrary to what was announced in literature on the structural behavior of mixed samples in odd-odd binary systems with Δn = 2, the three domains are not all orthorhombic. This work has enabled us to show that two of the domains are, in fact, monoclinic (Aa, Z = 4), and the other one is orthorhombic (Pca21, Z = 4). The conclusions drawn in this work can easily be transposed to other binary systems of n-alkanes.

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Journal of Materials Research , Volume 14 , Issue 6 , June 1999 , pp. 2644 - 2654
Copyright
Copyright © Materials Research Society 1999

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References

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