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Synthesis and characterization of PbTiO3 powders and heteroepitaxial thin films by hydrothermal synthesis

Published online by Cambridge University Press:  31 January 2011

A. T. Chien ,
J. Sachleben ,
J. H. Kim ,
J. S. Speck  and
F. F. Lange
A. T. Chien
Affiliation:
Materials Department and Materials Research Laboratory, University of California, Santa Barbara, California 93106
J. Sachleben
Affiliation:
Materials Department and Materials Research Laboratory, University of California, Santa Barbara, California 93106
J. H. Kim
Affiliation:
Materials Department and Materials Research Laboratory, University of California, Santa Barbara, California 93106
J. S. Speck
Affiliation:
Materials Department and Materials Research Laboratory, University of California, Santa Barbara, California 93106
F. F. Lange
Affiliation:
Materials Department and Materials Research Laboratory, University of California, Santa Barbara, California 93106
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Abstract

PbTiO3 powders and heteroepitaxial thin films were produced by the hydrothermal method at 110–200 °C using different bases (Na–, K–, Rb–, Cs–, TMA–, and TBA–OH). Microstructural characterization showed that the tetragonal perovskite films were epitaxial on the SrTiO3 substrates, with a c-axis out-of-plane orientation. Sequential growth experiments showed that the growth initiates by the formation of 100 nm {100} faceted PbTiO3 islands followed by coalescence. Small cation bases (Na–, K–, Rb–OH) produced 1.5-μm {100} faceted blocky powders, whereas larger cation bases (Cs–, TMA–, and TBA–OH) formed fewer 500-nm interpenetrating platelets. Nuclear magnetic resonance results showed cation incorporation in the perovskite structure with local disorder on the Pb sites increasing cation size.

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Articles
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Journal of Materials Research , Volume 14 , Issue 8 , August 1999 , pp. 3303 - 3311
Copyright
Copyright © Materials Research Society 1999

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