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Thermal conductivity of tunable lamellar aluminum oxide/polymethyl methacrylate hybrid composites

Published online by Cambridge University Press:  09 May 2012

Ran Chen ,
Michel B. Johnson ,
Kevin P. Plucknett  and
Mary Anne White
Ran Chen
Affiliation:
Department of Chemistry, and Institute for Research in Materials, Dalhousie University, Halifax, Nova Scotia, Canada, B3H 4R2
Michel B. Johnson
Affiliation:
Institute for Research in Materials, Dalhousie University, Halifax, Nova Scotia, Canada, B3H 4R2
Kevin P. Plucknett
Affiliation:
Institute for Research in Materials, and Department of Process Engineering and Applied Science, Dalhousie University, Halifax, Nova Scotia, Canada, B3H 4R2
Mary Anne White*
Affiliation:
Departments of Chemistry, and Physics and Atmospheric Science, and Institute for Research in Materials, Dalhousie University, Halifax, Nova Scotia, Canada, B3H 4R2
*
a)Address all correspondence to this author. e-mail: Mary.Anne.White@dal.ca
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Abstract

We prepared hybrid aluminum oxide (Al2O3)/polymethyl methacrylate (PMMA) composites with tunable lamellae, produced through a two-step synthetic method: fabrication of inorganic scaffolds via ice-templating, followed by organic infiltration polymerization as a substitute for the sublimed ice. The final lamellar hybrid products show anisotropic physical properties. The thermal conductivity in both principal directions was determined for three different samples as a function of temperature (∼3 K–300 K). Typical room temperature thermal conductivities are in the range of 0.5–2.5 W/(m K), depending on the composition and direction. Across the lamellae, the thermal conductivity is well modeled by a linear series of thermal resistors, and along the lamellae it is well represented by parallel thermal resistors of continuous slabs of PMMA and ∼200-μm long slabs of Al2O3, joined by PMMA. From the thermal conductivity perspective, the Al2O3/PMMA composite is a nacre mimic.

Keywords

compositethermal conductivitybiomimetic (assembly)
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 14 , 28 July 2012 , pp. 1869 - 1876
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

1.Maria, V.R., Montserrat, C., and Blanca, G.: Medical applications of organic-inorganic hybrid materials within the field of silica-based bioceramics. Chem. Soc. Rev. 40(2), 596–607 (2011).Google Scholar
2.Ferreira, R.A.S., Andre, P.S., and Carlos, L.D.: Organic-inorganic hybrid materials towards passive and active architectures for the next generation of optical networks. Opt. Mater. 32(11), 1397–1409 (2010).Google Scholar
3.Kumar, P. and Guliants, V.V.: Periodic mesoporous organic-inorganic hybrid materials: Applications in membrane separations and adsorption. Microporous Mesoporous Mater. 132(1–2), 1–14 (2010).Google Scholar
4.Tsuru, K., Hayakawa, S., and Osaka, A.: Cell proliferation and tissue compatibility of organic-inorganic hybrid materials. Key Eng. Mater. 377, 167–180 (2008).CrossRefGoogle Scholar
5.Schubert, U.: Catalysts made of organic-inorganic hybrid materials. New J. Chem. 18(10), 1049–1058 (1994).Google Scholar
6.Combarieu, G.D., Morcrette, M., Millange, F., Guillou, N., Cabana, J., Grey, C.P., Margiolaki, I., Ferey, G., and Tarascon, J.M.: Influence of benzoquinone sorption on the structure and electrochemical performance of the MIL-53(Fe) hybrid porous material in a lithium-ion battery. Chem. Mater. 21(8), 1602–1611 (2009).CrossRefGoogle Scholar
7.Sanchez, C., Arribart, H., and Guille, M.M.G.: Biomimetism and bioinspiration as tools for the design of innovative materials and systems. Nat. Mater. 4, 277–288 (2005).CrossRefGoogle ScholarPubMed
8.Suchanek, W. and Yoshimura, M.: Processing and properties of hydroxyapatite-based biomaterials for use as hard tissue replacement implants. J. Mater. Res. 13(1), 94–117 (1998).Google Scholar
9.Yamamoto, H., Kojima, Y., Okuyama, T., Abasolo, W.P., and Gril, J.: Origin of the biomechanical properties of wood related to the fine structure of the multilayered cell wall. J. Biomech. Eng. 124, 432–440 (2002).Google Scholar
10.Estevez, L., Kelarakis, A., Gong, Q.M., Da’as, E.H., and Emmanuel, P.G.: Multifunctional graphene/platinum/nafion hybrids via ice templating. J. Am. Chem. Soc. 133, 6122–6125 (2011).Google Scholar
11.Nayar, S., Pramanick, A.K., Guha, A., Mahato, B.K., Gunjan, M., and Sinha, A.: Biomimetic synthesis of hybrid nanocomposite scaffolds by freeze-thawing and freeze-drying. Bull. Mater. Sci. 31(3), 429–432 (2008).Google Scholar
12.Deville, S., Saiz, E., Nalla, R.K., and Tomsia, A.P.: Freezing as a path to build complex composites. Science 311, 515–518 (2006).Google Scholar
13.Moon, Y-W., Shin, K-H., Koh, Y-H., Choi, W-Y., and Kim, H-E.: Production of highly aligned porous alumina ceramics by extruding frozen alumina/camphene body. J. Eur. Ceram. Soc. 31, 1945–1950 (2011).CrossRefGoogle Scholar
14.Gutierrez, M.C., Ferrer, M.L., and de Mon, F.: Ice-templated materials: Sophisticated structures exhibiting enhanced functionalities obtained after unidirectional freezing and ice-segregation-induced self-assembly. Chem. Mater. 20, 634–648 (2008).Google Scholar
15.Suwanchawalit, C., Patil, A.J., Kumar, R.K., Wongnawa, S., and Mann, S.: Fabrication of ice-templated macroporous TiO2-chitosan scaffolds for photocatalytic applications. J. Mater. Chem. 19, 8478–8483 (2009).Google Scholar
16.Jakubinek, M.B., Samarasekera, C., and White, M.A.: Elephant ivory: A low thermal conductivity, high strength nanocomposite. J. Mater. Res. 21, 287–292 (2006).Google Scholar
17.Tremblay, L.P., Johnson, M.B., Werner-Zwanziger, U., and White, M.A.: Relationship between thermal conductivity and structure of nacre from Haliotis fulgens. J. Mater. Res. 26(10), 1216–1224 (2011).CrossRefGoogle Scholar
18.Munch, E., Launey, M.E., Alsem, D.H., Saiz, E., Tomsia, A.P., and Ritchie, R.O.: Tough, bioinspired hybrid materials. Science 322, 1516–1520 (2008).Google Scholar
19.Launey, M.E., Munch, E., Alsem, D.H., Barth, H.B., Saiz, E., Tomsia, A.P., and Ritchie, R.O.: Designing highly toughened hybrid composites through nature-inspired hierarchical complexity. Acta Mater. 57, 2919–2932 (2009).CrossRefGoogle Scholar
20.Zhan, B-Z., White, M.A., and Lumsden, M.: Bonding of organic amino, vinyl, and acryl groups to nanometer-sized NaX zeolite crystal surfaces. Langmuir 19, 4210 (2003).CrossRefGoogle Scholar
21.Maldonado, O.: Pulse method for simultaneous measurement of electric thermopower and heat conductivity at low temperatures. Cryogenics 32, 912 (1992).CrossRefGoogle Scholar
22.Yin, Z.J., Tao, S.Y., Zhou, X.M., and Ding, C.X.: Evaluating microhardness of plasma sprayed Al2O3 coatings using vickers indentation. J. Phys. D: Appl. Phys. 40, 7090–7096 (2007).CrossRefGoogle Scholar
23.Deville, S., Saiz, E., and Tomsia, A.P.: Freeze casting of hydroxyapatite scaffolds for bone tissue engineering. Biomaterials 27, 5480–5489 (2006).Google Scholar
24.Deville, S.: Freeze-casting of porous ceramics: A review of current achievements and issues. Adv. Eng. Mater. 10, 169 (2008).Google Scholar
25.Zhang, H.F., Hussain, I., Brust, M., Butler, M.F., Rannard, S.P., and Cooper, A.I.: Aligned two- and three-dimensional structures by directional freezing of polymers and nanoparticles. Nature 4, 787–793 (2005).Google Scholar
26.Lu, K., Kessler, C.S., and Davis, R.M.: Optimization of a nanoparticle suspension for freeze-casting. J. Am. Ceram. Soc. 89(8) 2459–2465 (2006).Google Scholar
27.Munro, C.D. and Plucknett, K.P.: Aqueous colloidal characterization and forming of multimodal barium titanate powders. J. Am. Ceram. Soc. 92, 2537–2543 (2009).Google Scholar
28.Deville, S., Maire, E., Bernard-Granger, G., Lasalle, A., Bogner, A., Gauthier, C., Leloup, J., and Guizard, C.: Metastable and unstable cellular solidification of colloidal suspensions. Nat. Mater. 8(12), 966–972 (2009).Google Scholar
29.Zhang, B. and Blum, F.D.: Thermogravimetric study of ultra thin PMMA films on silica: Effect of tacticity. Thermochim. Acta 396, 211–217 (2003).CrossRefGoogle Scholar
30.Yang, W., Kashani, N., Li, X.W., Zhang, G.P., and Meyers, M.A.: Structural characterization and mechanical behavior of a bivalve shell (Saxidomus purpuratus). Mat. Sci. Eng. C 1–6 (2010).Google Scholar
31.Ziv, V., Wagner, H.D., and Weiner, S.: Microstructure-microhardness relations in parallel-fibered and lamellar bone. Bone 18(5), 417–428 (1996).CrossRefGoogle ScholarPubMed
32.Sachs, C., Fabritius, H., and Raabe, D.: Hardness and elastic properties of dehydrated cuticle from the lobster Homarus americanus obtained by nanoindentation. J. Mater. Res. 21(8), 1987–1995 (2006).CrossRefGoogle Scholar
33.White, M.A.: Physical Properties of Materials (CRC Press, Boca Raton, FL, 2012).Google Scholar
34.Cahill, D.G., Lee, S-M., and Selinder, T.I.: Thermal conductivity of κ-Al2O3 and α-Al2O3 wear-resistant coatings. J. Appl. Phys. 83(11), 5783–5786 (1998).Google Scholar
35.Chu, D., Touzelbaev, M., Goodson, K.E., Babin, S., and Pease, R.F.: Thermal conductivity measurements of thin-film resist. J. Vac. Sci. Technol. B 19(6), 2874–2877 (2011).Google Scholar
36.Bruggeman, D.A.G.: Calculation of various physics constants in heterogeneous substances. Ann. Phys. 24, 636–679 (1935).CrossRefGoogle Scholar
37.Wong, C.P. and Bollampally, R.S.: Thermal conductivity, elastic modulus, and coefficient of thermal expansion of polymer filled with ceramic particles for electronic packaging. J. Appl. Polym. Sci. 74, 3396–3403 (1999).3.0.CO;2-3>CrossRefGoogle Scholar
38.Hojo, F., Kagawa, H., and Takezawa, Y.: Synthesis of a polymer composite with networked α-alumina fiber and evaluation of its thermal conductivity. J. Ceram. Soc. Jpn. 119(7), 601–604 (2011).CrossRefGoogle Scholar
39.Moreira, D.C., Sphaier, L.A., Reis, J.M.L., and Nunes, L.C.S.: Experimental investigation of heat conduction in polyester-Al2O3 and polyester-CuO nanocomposites. Expt. Thermal Fluid Sci. 35, 1458–1462 (2011).Google Scholar