Hostname: page-component-7dd5485656-zlgnt Total loading time: 0 Render date: 2025-10-30T08:02:39.381Z Has data issue: false hasContentIssue false
  • English
  • Français

Formation of TiO2 nanomaterials via titanium ethylene glycolide decomposition

Published online by Cambridge University Press:  27 July 2012

Ting Xia ,
Joseph W. Otto ,
Tanmoy Dutta ,
James Murowchick ,
Anthony N. Caruso ,
Zhonghua Peng  and
Xiaobo Chen
Ting Xia
Affiliation:
Department of Chemistry, University of Missouri—Kansas City, Kansas City, Missouri 64110
Joseph W. Otto
Affiliation:
Department of Physics, University of Missouri—Kansas City, Kansas City, Missouri 64110
Tanmoy Dutta
Affiliation:
Department of Chemistry, University of Missouri—Kansas City, Kansas City, Missouri 64110
James Murowchick
Affiliation:
Department of Geosciences, University of Missouri—Kansas City, Kansas City, Missouri 64110
Anthony N. Caruso
Affiliation:
Department of Physics, University of Missouri—Kansas City, Kansas City, Missouri 64110
Zhonghua Peng
Affiliation:
Department of Chemistry, University of Missouri—Kansas City, Kansas City, Missouri 64110
Xiaobo Chen*
Affiliation:
Department of Chemistry, University of Missouri—Kansas City, Kansas City, Missouri 64110
*
a)Address all correspondence to this author. e-mail: chenxiaobo@umkc.edu
Get access

Abstract

Titanium dioxide (TiO2) nanomaterials, as important photocatalysis materials, have been synthesized with many approaches. In this study, we reported the synthesis of TiO2 nanomaterials by reacting titanium isopropoxide with ethylene glycol under basic condition followed by calcination at high temperatures. The structural, optical, and photocatalytic properties of the TiO2 nanomaterials were studied with x-ray diffraction, Raman spectroscopy, transmission electron microscopy, differential scanning calorimetry, Fourier-transformed infrared spectroscopy, x-ray and ultraviolet (UV) photoemission spectroscopy, UV–vis diffusive reflectance, and photocatalytic decomposition of methylene blue. We found that the titanium ethylene glycolide decomposes at 330 °C and transforms into pure anatase TiO2 around 400 °C. The anatase phase further transforms into core/shell rutile/anatase TiO2 composite at 550 °C and displays the highest photocatalytic activity among the samples prepared. The high photocatalytic activity can be attributed to the improved charge separation at the rutile/anatase n/n junction interface and the high crystallinity of the sample after calcination.

Information

Type
Articles
Information
Journal of Materials Research , Volume 28 , Issue 3: Focus Issue: Titanium Dioxide Nanomaterials , 14 February 2013 , pp. 326 - 332
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Article purchase

Temporarily unavailable

References

REFERENCES

Pfaff, G. and Reynders, P.: Angle-dependent optical effects deriving from submicron structures of films and pigments. Chem. Rev. 99, 1963 (1999).Google Scholar
Salvador, A., Pascual-Marti, M.C., Adell, J.R., Requeni, A., and March, J.G.: Analytical methodologies for atomic spectrometric determination of metallic oxides in UV sunscreen creams. J. Pharm. Biomed. Anal. 22, 301 (2000).Google Scholar
Zallen, R. and Moret, M.P.: The optical absorption edge of brookite TiO2. Solid State Commun. 137, 154 (2006).Google Scholar
Braun, J.H., Baidins, A., and Marganski, R.E.: Titanium dioxide pigment technology: A review. Prog. Org. Coat. 20, 105 (1992).Google Scholar
Yuan, S.A., Chen, W.H., and Hu, S.S.: Fabrication of TiO2 nanoparticles/surfactant polymer complex film on glassy carbon electrode and its application to sensing trace dopamine. Mater. Sci. Eng., C C25, 479 (2005).Google Scholar
Fujishima, A. and Honda, K.: Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37 (1972).Google Scholar
Oregan, B. and Gratzel, M.: A low-cost, high-efficiency solar cell based on dye-sensitized colloidal titanium dioxide films. Nature 353, 737 (1991).Google Scholar
Linsebigler, A.L., Lu, G., and Yates, J.T. Jr.: Photocatalysis on TiO2 surfaces: Principles, mechanisms, and selected results. Chem. Rev. 95, 735 (1995).Google Scholar
Fujishima, A., Rao, T.N., and Tryk, D.A.: Titanium dioxide photocatalysis. J. Photochem. Photobiol., C 1, 1 (2000).Google Scholar
Chen, X. and Mao, S.S.: Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications. Chem. Rev. 107, 2891 (2007).Google Scholar
Trentler, T.J., Denler, T.E., Bertone, J.F., Agrawal, A., and Colvin, V.L.: Synthesis of TiO2 nanocrystals by nonhydrolytic solution-based reactions. J. Am. Chem. Soc. 121, 1613 (1999).Google Scholar
Bessekhouad, Y., Robert, D., and Weber, J.V.: Synthesis of photocatalytic TiO2 nanoparticles: Optimization of the preparation conditions. J. Photochem. Photobiol., A 157, 47 (2003).CrossRefGoogle Scholar
Kim, K.D., Kim, S.H., and Kim, H.T.: Applying the Taguchi method to the optimization for the synthesis of TiO2 nanoparticles by hydrolysis of TEOT in micelles. Colloids Surf., A 254, 99 (2005).Google Scholar
Yang, J., Mei, S., and Ferreira, J.M.F.: Hydrothermal synthesis of TiO2 nanopowders from tetra alkylammonium hydroxide peptized sols. Mater. Sci. Eng., C C15, 183 (2001).Google Scholar
Kim, C.S., Moon, B.K., Park, J.H., Chung, S.T., and Son, S.M.: Synthesis of nanocrystalline TiO2 in toluene by a solvothermal route. J. Cryst. Growth 254, 405 (2003).Google Scholar
Wu, J.M.: Low-temperature preparation of titania nanorods through direct oxidation of titanium with hydrogen peroxide. J. Cryst. Growth 269, 347(2004).Google Scholar
Seifried, S., Winterer, M., and Hahn, H.: Nanocrystalline titania films and particles by chemical vapor synthesis. Chem. Vap. Deposition 6, 239 (2000).Google Scholar
Xiang, B., Zhang, Y., Wang, Z., Luo, X.H., Zhu, Y.W., Zhang, H.Z., and Yu, D.P.: Field-emission properties of TiO2 nanowire arrays. J. Phys. D: Appl. Phys. 38, 1152 (2005).Google Scholar
Lei, Y., Zhang, L.D., and Fan, J.C.: Fabrication, characterization and Raman study of TiO2 nanowire arrays prepared by anodic oxidative hydrolysis of TiCl3. Chem. Phys. Lett. 338, 231 (2001).Google Scholar
Huang, W., Tang, X., Wang, Y., Koltypin, Y., and Gedanken, A.: Selective synthesis of anatase and rutile via ultrasound irradiation. Chem. Commun. 15, 1415 (2000).Google Scholar
Yamamoto, T., Wada, Y., Yin, H., Sakata, T., Mori, H., and Yanagida, S.: Microwave-driven polyol method for preparation of TiO2 nanocrystallites. Chem. Lett. 10, 964 (2002).Google Scholar
Oskam, G., Nellore, A., Penn, R.L., and Searson, P.C.: The growth kinetics of TiO2 nanoparticles from titanium (IV) alkoxide at high water/titanium ratio. J. Phys. Chem. B 107, 1734 (2003).Google Scholar
Jenkins, R. and Snyder, R.L.: Introduction to X-rap Powder Diffractometry (John Wiley & Sons Inc., New York, 1996).Google Scholar
Zhang, J., Li, M., Feng, Z., Chen, J., and Li, C.: UV Raman spectroscopic study on TiO2. I. Phase transformation at the surface and in the bulk. J. Phys. Chem. B 110, 927 (2006).Google Scholar
Chen, X. and Burda, C.: The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials. J. Am. Chem. Soc. 130, 5018 (2008).CrossRefGoogle Scholar
Chen, X., Liu, L., Yu, P.Y., and Mao, S.S.: Increasing solar absorption for photocatalysis with black hydrogenated titanium dioxide nanocrystals. Science 331, 746 (2011).Google Scholar
Diebold, U.: The surface science of titanium dioxide. Surf. Sci. Rep. 48, 53 (2003).Google Scholar
Thompson, T.L. and Yates, J.T. Jr.: TiO2-based photocatalysis: Surface defects, oxygen and charge transfer. Top. Catal. 35, 197 (2005).Google Scholar
Park, Y.R. and Kim, K.J.: Structural and optical properties of rutile and anatase TiO2 thin films: Effects of Co doping. Thin Solid Films 484, 34 (2005).Google Scholar
Zhang, J., Xu, Q., Feng, Z., Li, M., and Li, C.: Importance of the relationship between surface phases and photocatalytic activity of TiO2. Angew. Chem. Int. Ed. 47, 1766 (2008).Google Scholar