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Greatly enhanced photocatalytic activity and mechanism of H3PW12O40/polymethylmethacrylate/polycaprolactam sandwich nanofibrous membrane prepared by electrospinning

Published online by Cambridge University Press:  09 September 2016

Wei Li ,
Tingting Li ,
Ce Liu ,
Libao An ,
Yuqing Li ,
Weiwei Zhang ,
Lu Liu  and
Zhiming Zhang
Wei Li
Affiliation:
College of Material Science and Engineering, Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, North China University of Science and Technology, Tangshan 063009, China
Tingting Li*
Affiliation:
College of Material Science and Engineering, Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, North China University of Science and Technology, Tangshan 063009, China
Ce Liu
Affiliation:
College of Chemical Engineering, North China University of Science and Technology, Tangshan 063009, China
Libao An*
Affiliation:
College of Mechanical Engineering, North China University of Science and Technology, Tangshan 063009, China
Yuqing Li
Affiliation:
College of Material Science and Engineering, Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, North China University of Science and Technology, Tangshan 063009, China
Weiwei Zhang*
Affiliation:
College of Material Science and Engineering, Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, North China University of Science and Technology, Tangshan 063009, China
Lu Liu
Affiliation:
College of Material Science and Engineering, Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, North China University of Science and Technology, Tangshan 063009, China
Zhiming Zhang*
Affiliation:
College of Material Science and Engineering, Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, North China University of Science and Technology, Tangshan 063009, China
*
a) Address all correspondence to these authors. e-mail: litingting2046@163.com
b) e-mail: zhangzhiming1942@163.com
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Abstract

H3PW12O40/polymethylmethacrylate (PMMA)/polycaprolactam (PA6) nanofibrous membrane with a sandwich structure was prepared by electrospinning. Characterization with Fourier transformation infrared spectroscopy (FT-IR), energy-dispersive x-ray spectroscopy (EDX), and x-ray photoelectron spectroscopy (XPS) indicated that H3PW12O40 has been successfully loaded into the upper and bottom layers of the sandwich membrane and its Keggin structure was not destroyed. The photocatalytic efficiency of the sandwich membranes were much higher (≥87.2%) than that of H3PW12O40 only (15.6%) and H3PW12O40/PMMA composite nanofibrous membrane (11.6%) in the degradation of methyl orange (MO) under ultraviolet irradiation. It may be caused by two factors: one was the photoreduction mechanism induced by the electron donating from PA6 to H3PW12O40, the other was the double contact area between H3PW12O40 and MO due to the sandwich structure of the laminated membrane. What is noteworthy is that the sandwich membranes were stable in water, so that they could be easily separated from the aqueous MO solution and reused without appreciable losses in photocatalytic activity after three photocatalytic cycles. In view of this, H3PW12O40/PMMA/PA6 sandwich nanofibrous membrane is promising as a photocatalyst to remove organic pollutants from practical wastewater.

Keywords

sandwich nanofibrous membraneelectrospinningH3PW12O40photocatalytic activityreusability

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Type
Articles
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Journal of Materials Research , Volume 31 , Issue 19 , 14 October 2016 , pp. 3060 - 3068
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Copyright © Materials Research Society 2016 

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References

REFERENCES

Liu, J. and Zhang, J.: Photocatalytic activity enhancement of TiO2 nanocrystalline thin film with surface modification of poly-3-hexylthiophene by in situ polymerization. J. Mater. Res. 31(10), 1448 (2016).CrossRefGoogle Scholar
Kozhevnikov, I.V.: Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions. Chem. Rev. 98(1), 171 (1998).CrossRefGoogle ScholarPubMed
Zhang, X., Wu, W., Wang, J., Liu, C., and Qian, S.: Molybdenum polyoxometalate impregnated amino-functionalized mesoporous silica thin films as multifunctional materials for photochromic and electrochemical applications. J. Mater. Res. 23(1), 18 (2008).Google Scholar
Yamase, T.: Photoredox chemistry of polyoxometalates as a photocatalyst. Catal. Surv. Asia 7(4), 203 (2003).CrossRefGoogle Scholar
Ismail, S., Ng, C.Y., Ahmadi, E., Razak, K.A., and Lockman, Z.: Segmented nanoporous WO3 prepared via anodization and their photocatalytic properties. J. Mater. Res. 31(6), 721 (2016).Google Scholar
Feng, W., Zhang, T., Liu, J., Lu, R., Zhao, Y., and Yao, J.: Ultrasound-induced change of microstructure and photochromic properties of polyacrylamide thin films containing a polyoxometalate. J. Mater. Res. 18(3), 709 (2003).CrossRefGoogle Scholar
Gkika, E., Kormali, P., Antonaraki, S., Dimoticali, D., Papaconstantinou, E., and Hiskia, A.: Polyoxometalates as effective photocatalysts in water purification from pesticides. Int. J. Photoenergy 6(4), 227 (2004).Google Scholar
Hori, H., Takano, Y., Koike, K., Takeuchi, K., and Einaga, H.: Decomposition of environmentally persistent trifluoroacetic acid to fluoride ions by a homogeneous photocatalyst in water. Environ. Sci. Technol. 37(2), 418 (2003).Google Scholar
Molinari, A., Amadelli, R., Carassiti, V., and Maldotti, A.: Photocatalyzed oxidation of cyclohexene and cyclooctene with (nBu4N)4W10O32 and (nBu4N)4W10O32/FeIII[meso-tetrakis(2,6-dichlorophenyl)porphyrin] in homogeneous and heterogeneous systems. Eur. J. Inorg. Chem. 2000(1), 91 (2000).3.0.CO;2-J>CrossRefGoogle Scholar
Nikbakht, E., Yadollahi, B., and Farsani, M.R.: Green oxidation of alcohols in water by a polyoxometalate nano capsule as catalyst. Inorg. Chem. Commun. 55, 135 (2015).Google Scholar
Yue, B., Zhou, Y., Xu, J., Wu, Z., Zhang, X., Zou, Y., and Jin, S.: Photocatalytic degradation of aqueous 4-chlorophenol by silica-immobilized polyoxometalates. Environ. Sci. Technol. 36(6), 1325 (2002).Google Scholar
Verhoef, M.J., Kooyman, P.J., Peters, J.A., and van Bekkum, H.: A study on the stability of MCM-41-supported heteropoly acids under liquid- and gas-phase esterification conditions. Microporous Mesoporous Mater. 27(2–3), 365 (1999).Google Scholar
Ozer, R.R. and Ferry, J.L.: Photocatalytic oxidation of aqueous 1,2-dichlorobenzene by polyoxometalates supported on the NaY zeolite. J. Phys. Chem. B 106(16), 4336 (2002).Google Scholar
Molinari, A., Amadelli, R., Andreotti, L., and Maldotti, A.: Heterogeneous photocatalysis for synthetic purposes: Oxygenation of cyclohexane with H3PW12O40 and (nBu4N)4W10O32 supported on silica. J. Chem. Soc., Dalton Trans. 578(8), 1203 (1999).CrossRefGoogle Scholar
Bonchio, M., Carraro, M., Scorrano, G., Fontananova, E., and Drioli, E.: Heterogeneous photooxidation of alcohols in water by photocatalytic membranes incorporating decatungstate. Adv. Synth. Catal. 345(9–10), 1119 (2003).CrossRefGoogle Scholar
Reddy, P.G., Satyanarayana, V.S.V., Dubey, V., Ghosh, A.R., and Pradeep, C.P.: [P2V3W15O62]9− cluster based covalent polyoxometalate-organic hybrid: Synthesis, structure, self-assembly and in vitro antioxidant activities. Inorg. Chem. Commun. 56, 65 (2015).Google Scholar
Gao, S., Pan, D., and Cao, R.: Layer-by-layer self-assembly polytungstogermanate multilayer films and their photocatalytic properties under sunlight irradiation. J. Colloid Interface Sci. 358(2), 593 (2011).Google Scholar
Zhao, X., Lv, L., Pan, B., Zhang, W., Zhang, S., and Zhang, Q.: Polymer-supported nanocomposites for environmental application: A review. Chem. Eng. J. 170(2–3), 381 (2011).Google Scholar
Jing, X., Mi, H-Y., Salick, M.R., Cordie, T., McNulty, J., Peng, X-F., and Turng, L-S.: In vitro evaluations of electrospun nanofiber scaffolds composed of poly(ɛ-caprolactone) and polyethylenimine. J. Mater. Res. 30(11), 1808 (2015).Google Scholar
Sui, C., Li, C., Guo, X., Cheng, T., Gao, Y., Zhou, G., Gong, J., and Du, J.: Facile synthesis of silver nanoparticles-modified PVA/H4SiW12O40 nanofibers-based electrospinning to enhance photocatalytic activity. Appl. Surf. Sci. 258(18), 7105 (2012).Google Scholar
Saeed, K., Haider, S., Oh, T-J., and Park, S-Y.: Preparation of amidoxime-modified polyacrylonitrile (PAN-oxime) nanofibers and their applications to metal ions adsorption. J. Membr. Sci. 322(2), 400 (2008).Google Scholar
Abdal-hay, A., Mousa, H.M., Khan, A., Vanegas, P., and Lim, J.H.: TiO2 nanorods coated onto nylon 6 nanofibers using hydrothermal treatment with improved mechanical properties. Colloids Surf., A 457, 275 (2014).Google Scholar
Guo, Z., Shao, C., Mu, J., Zhang, M., Zhang, Z., Zhang, P., Chen, B., and Liu, Y.: Controllable fabrication of cadmium phthalocyanine nanostructures immobilized on electrospun polyacrylonitrile nanofibers with high photocatalytic properties under visible light. Catal. Commun. 12(10), 880 (2011).Google Scholar
Zhang, S., Zhao, G., Gao, S., Xi, Z., and Xu, J.: Secondary alcohols oxidation with hydrogen peroxide catalyzed by [n-C16H33N(CH3)3]3PW12O40: Transform-and-retransform process between catalytic precursor and catalytic activity species. J. Mol. Catal. A: Chem. 289(1–2), 22 (2008).CrossRefGoogle Scholar
Feng, C. and Shang, H.: Hydrothermal synthesis of H3PW12O40/TiO2 nanometer photocatalyst and its catalytic performance for methyl orange. Chem. Res. Chin. Univ. 28(3), 366 (2012).Google Scholar
Berry, F.J., Derrick, G.R., Marco, J.F., and Mortimer, M.: Silica-supported silicotungstic acid: A study by x-ray photoelectron spectroscopy. Mater. Chem. Phys. 114(2–3), 1000 (2009).Google Scholar
Turchi, C.S. and Ollis, D.F.: Photocatalytic degradation of organic water contaminants: Mechanisms involving hydroxyl radical attack. J. Catal. 122(1), 178 (1990).Google Scholar
Lee, M.S., Park, S.S., Lee, G-D., Ju, C-S., and Hong, S-S.: Synthesis of TiO2 particles by reverse microemulsion method using nonionic surfactants with different hydrophilic and hydrophobic group and their photocatalytic activity. Catal. Today 101(3–4), 283 (2005).Google Scholar
Troupis, A., Triantis, T.M., Gkika, E., Hiskia, A., and Papaconstantinou, E.: Photocatalytic reductive–oxidative degradation of acid orange 7 by polyoxometalates. Appl. Catal., B 86(1–2), 98 (2009).CrossRefGoogle Scholar
Zhang, P., Shao, C., Li, X., Zhang, M., Zhang, X., Sun, Y., and Liu, Y.: In situ assembly of well-dispersed Au nanoparticles on TiO2/ZnO nanofibers: A three-way synergistic heterostructure with enhanced photocatalytic activity. J. Hazard. Mater. 237–238, 331 (2012).Google Scholar
Velegraki, T., Poulios, I., Charalabaki, M., Kalogerakis, N., Samaras, P., and Mantzavinos, D.: Photocatalytic and sonolytic oxidation of acid orange 7 in aqueous solution. Appl. Catal., B 62(1–2), 159 (2006).CrossRefGoogle Scholar
Guo, Y. and Hu, C.: Heterogeneous photocatalysis by solid polyoxometalates. J. Mol. Catal. A: Chem. 262(1–2), 136 (2007).Google Scholar
Hiskia, A., Mylonas, A., and Papaconstantinou, E.: Comparison of the photoredox properties of polyoxometalates and semiconducting particles. Chem. Soc. Rev. 30(1), 62 (2001).Google Scholar
Wang, Y., Lu, K., and Feng, C.: Influence of inorganic anions and organic additives on photocatalytic degradation of methyl orange with supported polyoxometalates as photocatalyst. J. Rare Earths 31(4), 360 (2013).Google Scholar
Troupis, A., Gkika, E., Triantis, T., Hiskia, A., and Papaconstantinou, E.: Photocatalytic reductive destruction of azo dyes by polyoxometalates: Naphthol blue black. J. Photochem. Photobiol., A 188(2–3), 272 (2007).Google Scholar
Arslan-Alaton, I. and Ferry, J.L.: Near-UV–VIS light induced acid orange 7 bleaching in the presence of SiW12O40 4− catalyst. J. Photochem. Photobiol., A 152(1–3), 175 (2002).Google Scholar
Li, T., Zhang, Z., Li, W., Liu, C., Wang, J., and An, L.: H4SiW12O40/polymethylmethacrylate/polyvinyl alcohol sandwich nanofibrous membrane with enhanced photocatalytic activity. Colloids Surf., A 489, 289 (2016).Google Scholar
Liu, Y. and Wang, Q.: The investigation on the flame retardancy mechanism of nitrogen flame retardant melamine cyanurate in polyamide 6. J. Polym. Res. 16(5), 583 (2009).Google Scholar
Hill, C.L. and Bouchard, D.A.: Catalytic photochemical dehydrogenation of organic substrates by polyoxometalates. J. Am. Chem. Soc. 107(18), 5148 (1985).CrossRefGoogle Scholar
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