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Growth and structures of C60 shells

Published online by Cambridge University Press:  31 January 2011

H. Sakuma ,
M. Tachibana ,
H. Sugiura ,
K. Kojima ,
S. Ito ,
T. Sekiguchi  and
Y. Achiba
H. Sakuma
Affiliation:
Graduate School of Integrated Science, Yokohoma City University, 22–2 Seto, Kanazawa-ku, Yokohama 236, Japan
M. Tachibana*
Affiliation:
Department of Physics, Faculty of Science, Yokohama City University, 22–2 Seto, Kanazawa-ku, Yokohama 236, Japan
H. Sugiura
Affiliation:
Department of Physics, Faculty of Science, Yokohama City University, 22–2 Seto, Kanazawa-ku, Yokohama 236, Japan
K. Kojima
Affiliation:
Department of Physics, Faculty of Science, Yokohama City University, 22–2 Seto, Kanazawa-ku, Yokohama 236, Japan
S. Ito
Affiliation:
Research Institute for Materials, Tohoku University, 2-1 Katahira-machi, Aoba-ku, Sendai 980, Japan
T. Sekiguchi
Affiliation:
Research Institute for Materials, Tohoku University, 2-1 Katahira-machi, Aoba-ku, Sendai 980, Japan
Y. Achiba
Affiliation:
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Minami-Ohsawa, Hachioji, Tokyo 192–03, Japan
*
a)Address all correspondence to this author.
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Abstract

The growth of the shells of C60 crystals was carried out under various conditions. The detailed structures of the grown shells were investigated by transmission electron microscopy and Raman spectroscopy. The shells were formed during thermal sublimation of the C60 crystals, which were irradiated with white light in air. The shells were mainly composed of a kind of amorphous carbon. From these results, it is suggested that the oxygen-induced disintegration of C60 cages is responsible for the shell formation.

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Type
Articles
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Journal of Materials Research , Volume 12 , Issue 6 , June 1997 , pp. 1545 - 1550
Copyright
Copyright © Materials Research Society 1997

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References

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