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High-temperature plasticity of cubic bismuth oxide

Published online by Cambridge University Press:  31 January 2011

Anne Vilette
Affiliation:
Department of Materials Science and Engineering, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061–0237
S. L. Kampe
Affiliation:
Department of Materials Science and Engineering, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061–0237
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Abstract

Cubic (δ) bismuth oxide (Bi2O3) has been subjected to high temperature deformation over a wide range of temperatures and strain rates. Results indicate that bismuth oxide is essentially incapable of plastic deformation at temperatures below the monoclithic to cubic phase transformation which occurs at approximately 730 °C. Above the transformation temperature, however, Bi2O3 is extensively deformable. The variability of flow stress to temperature and strain rate has been quantified through the determination of phenomenological-based constitutive equations to describe its behavior at these high temperatures. Analysis of the so-determined deformation constants indicate an extremely strong sensitivity to strain rate and temperature, with values of the strain-rate sensitivity approaching values commonly cited as indicative of superplastic behavior.

Type
Articles
Copyright
Copyright © Materials Research Society 1996

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References

REFERENCES

1.Johnson, C. A., Bradt, R. C., and Hoke, J.H., J. Am. Ceram. Soc. 58 (1–2), 3740 (1975).CrossRefGoogle Scholar
2.Maehara, Y. and Langdon, T. G., J. Mater. Sci. 25, 22752286 (1990).CrossRefGoogle Scholar
3.Nieh, T. G., Wadsworth, J., and Wakai, F., Int. Mater. Rev. 36, 146 (1991).CrossRefGoogle Scholar
4.Langdon, T. G., JOM 42 (7), 813 (1990).CrossRefGoogle Scholar
5.Nieh, T. G. and Wadsworth, J., Annu. Rev. Mater. Sci. 20, 117140 (1990).CrossRefGoogle Scholar
6.Nieh, T. G., McNally, C. M., and Wadsworth, J., JOM 41 (9), 3135 (1989).CrossRefGoogle Scholar
7.Pilling, J. and Ridley, N., Superplasticity in Crystalline Solids (The Institute of Metals, London, UK, 1989), pp. 4864.Google Scholar
8.CRC Handbook of Chemistry and Physics, 56th ed. (CRC Press, Cleveland, OH, 1975), p. B77.Google Scholar
9.Smyth, J. R., Bradt, R. C., and Hoke, J. H., J. Am. Ceram. Soc. 58 (9–10), 381384 (1975).CrossRefGoogle Scholar
10.Frost, H. J. and Ashby, M.F., Deformation-Mechanism Maps (Pergamon, New York, 1982).Google Scholar
11.Kingery, W. D., Bowen, H. K., and Uhlmann, D. R., Introduction to Ceramics, 2nd ed. (John Wiley and Sons, Inc., New York, 1976), pp. 449468.Google Scholar
12.Sabinash, C. M., Sastry, S. M. L., and Jerina, K. L., Scripta Metall et Mater. 32, 13811386 (1995).CrossRefGoogle Scholar