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The influences of reactant composition and substrate material on the combustion synthesis of diamond

Published online by Cambridge University Press:  26 July 2012

Colin A. Wolden ,
Charles E. Draper ,
Z. Sitar  and
J. T. Prater
Colin A. Wolden
Affiliation:
Department of Chemical Engineering, Colorado School of Mines, Golden, Colorado 80401-1887
Charles E. Draper
Affiliation:
Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695-7919
Z. Sitar
Affiliation:
Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695-7919
J. T. Prater
Affiliation:
Army Research Office, Research Triangle Park, North Carolina 27709-2211
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Extract

It has been observed that diamond deposition by flat flame chemical vapor deposition is achieved over a very narrow range of reactant composition. We demonstrate that this diamond deposition window is strongly determined by the nature of the substrate material. Furthermore, once a continuous diamond film is formed, the window appears to be independent of the original material. Substrates examined include silicon, glass, titanium, tungsten, nickel, and molybdenum. The dependence of growth rate, morphology, and quality on reactant composition has been quantified using scanning electron microscopy, Raman spectroscopy, and secondary ion mass spectroscopy (SIMS). It was found that the highest quality diamond was grown at conditions where diamond does not nucleate on ultrasonically scratched silicon. Thus, the production of high quality diamond on silicon by combustion synthesis requires different conditions for nucleation and growth.

Type
Articles
Information
Journal of Materials Research , Volume 14 , Issue 1 , January 1999 , pp. 259 - 269
Copyright
Copyright © Materials Research Society 1999

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