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Novel pot-shaped carbon nanomaterial synthesized in a submarine-style substrate heating CVD method

  • Hiroyuki Yokoi (a1), Kazuto Hatakeyama (a1), Takaaki Taniguchi (a1), Michio Koinuma (a1), Masahiro Hara (a2) and Yasumichi Matsumoto (a2)...
Abstract

We have developed a new synthesis method that includes a chemical vapor deposition process in a chamber settled in organic liquid, and applied its nonequilibrium reaction field to the development of novel carbon nanomaterials. In the synthesis at 1110–1120 K, using graphene oxide as a catalyst support, iron acetate and cobalt acetate as catalyst precursors, and 2-propanol as a carbon source as well as the organic liquid, we succeeded to create carbon nanofiber composed of novel pot-shaped units, named carbon nanopot. A carbon nanopot has a complex and regular nanostructure consisting of several parts made of different layer numbers of graphene and a deep hollow space. Dense graphene edges, hydroxylated presumably, are localized around its closed end. The typical size of a carbon nanopot was 20–40 nm in outer diameter, 5–30 nm in inner diameter, and 100–200 nm in length. A growth model of carbon nanopot and its applications are proposed.

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a) Address all correspondence to this author. e-mail: yokoihr@kumamoto-u.ac.jp
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Journal of Materials Research
  • ISSN: 0884-2914
  • EISSN: 2044-5326
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