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Photocatalytic activity of MTiO3 (M = Ca, Ni, and Zn) nanocrystals for water decomposition to hydrogen

Published online by Cambridge University Press:  04 June 2014

Shuai Liu ,
Yang Qu ,
Rong Li ,
Guofeng Wang  and
Ying Li
Shuai Liu
Affiliation:
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
Yang Qu
Affiliation:
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
Rong Li
Affiliation:
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
Guofeng Wang*
Affiliation:
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
Ying Li
Affiliation:
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China
*
a)Address all correspondence to this author. e-mail: wanggf75@gmail.com
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Abstract

MTiO3 (M = Ca, Ni, and Zn) nanocrystals were prepared via a facile ethylene glycol-mediated synthesis route followed by calcination in air. The structures and morphologies of nanocrystals were characterized by x-ray diffraction, Raman spectroscopy, transmission electron microscopy, and scanning electron microscopy. The results indicated that CaTiO3 and NiTiO3 are orthorhombic phase, while the ZnTiO3 is orthorhombic phase. The activity of the CaTiO3 nanocrystals for water splitting into H2 was obviously higher than those of the NiTiO3 and ZnTiO3 nanocrystals, which could be attributed to the more negative conduction band position of CaTiO3 than NiTiO3 and ZnTiO3. The Brunauer–Emmett–Teller system-based surface areas of samples are 19.03, 21.13, and 4.17 m2/g for CaTiO3, NiTiO3, and ZnTiO3 nanocrystals, respectively. In addition, the activity of the CaTiO3 nanocrystals increased with increase in the sintering temperature of samples.

Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 11 , 14 June 2014 , pp. 1295 - 1301
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Muradov, N. and Veziroğlu, T.: “Green” path from fossil-based to hydrogen economy: An overview of carbon-neutral technologies. Int. J. Hydrogen Energy 33, 6804 (2008).CrossRefGoogle Scholar
Coughlin, R. and Farooque, M.: Hydrogen production from coal, water and electrons. Nature 279, 301 (1979).CrossRefGoogle Scholar
Sato, S., Lin, S., Suzuki, Y., and Hatano, H.: Hydrogen production from heavy oil in the presence of calcium hydroxide. Fuel 82, 561 (2003).CrossRefGoogle Scholar
Cortright, R., Davda, R., and Dumesic, J.: Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water. Nature 418, 964 (2002).CrossRefGoogle ScholarPubMed
Lu, Y., Guo, L., Ji, C., Zhang, X., Hao, X., and Yan, Q.: Hydrogen production by biomass gasification in supercritical water: A parametric study. Int. J. Hydrogen Energy 31, 822 (2006).CrossRefGoogle Scholar
Hao, X., Guo, L., Mao, X., Zhang, X., and Chen, X.: Hydrogen production from glucose used as a model compound of biomass gasified in supercritical water. Int. J. Hydrogen Energy 28, 55 (2003).CrossRefGoogle Scholar
Navarro, R., Pea, M., and Fierro, J.: Hydrogen production reactions from carbon feedstocks: Fossil fuels and biomass. Chem. Rev. 107, 3952 (2007).CrossRefGoogle ScholarPubMed
Sand, H.: On the concentration at the electrodes in a solution, with special reference to the liberation of hydrogen by electrolysis of a mixture of copper sulphate and sulphuric acid. Philos. Mag. 1, 45 (1901).CrossRefGoogle Scholar
Wang, D., Czernik, S., Montane, D., Mann, M., and Chornet, E.: Biomass to hydrogen via fast pyrolysis and catalytic steam reforming of the pyrolysis oil or its fractions. Ind. Eng. Chem. Res. 36, 1507 (1997).CrossRefGoogle Scholar
Fujishima, A. and Honda, K.: Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37 (1972).CrossRefGoogle Scholar
Mao, S. and Chen, X.: Selected nanotechnologies for renewable energy applications. Int. J. Energy Res. 31, 619 (2007).CrossRefGoogle Scholar
Tong, H., Ouyang, S., Bi, Y., Umezawa, N., Oshikiri, M., and Ye, J.: Nano photocatalytic materials: Possibilities and challenges. Adv. Mater. 24, 229–251 (2012).CrossRefGoogle ScholarPubMed
Kubacka, A., Fernández-García, M., and Colón, G.: Advanced nanoarchitectures for solar photocatalytic applications. Chem. Rev. 112, 1555 (2012).CrossRefGoogle ScholarPubMed
Peng, R., Wu, C., Baltrusaitis, J., Dimitrijevic, N., Rajh, T., and Koodali, R.: Ultra-stable CdS incorporated Ti-MCM-48 mesoporous materials for efficient photocatalytic decomposition of water under visible light illumination. Chem. Commun. 49, 3221 (2013).CrossRefGoogle ScholarPubMed
Qu, Y., Zhou, W., Xie, Y., Jiang, L., Wang, J., Tian, G., Ren, Z., Tian, C., and Fu, H.: A novel phase-mixed MgTiO3-MgTi2O5 heterogeneous nanorod for high efficiency photocatalytic hydrogen production. Chem. Commun. 49, 8510 (2013).CrossRefGoogle ScholarPubMed
Chen, X., Shen, S., Guo, L., and Mao, S.: Semiconductor-based photocatalytic hydrogen generation. Chem. Rev. 110, 6503 (2010).CrossRefGoogle ScholarPubMed
Li, Q., Guo, B., Yu, J., Ran, J., Zhang, B., Yan, H., and Gong, J.: Highly efficient visible-light-driven photocatalytic hydrogen production of CdS-cluster-decorated graphene nanosheets. J. Am. Chem. Soc. 133, 10878 (2011).CrossRefGoogle ScholarPubMed
Tanaka, A., Hashimoto, K., Ohtani, B., and Kominami, H.: Non-linear photocatalytic reaction induced by visible-light surface-plasmon resonance absorption of gold nanoparticles loaded on titania particles. Chem. Commun. 49, 3419 (2013).CrossRefGoogle ScholarPubMed
Wang, X., Yin, L., Liu, G., Wang, L., Saito, R., Lu, G., and Cheng, H.: Polar interface-induced improvement in high photocatalytic hydrogen evolution over ZnO-CdS heterostructures. Energy Environ. Sci. 4, 3976 (2011).CrossRefGoogle Scholar
Li, Y., Qu, Y., Wang, G., Pan, K., Yu, D., Liu, S., Feng, L., Cui, J., and Ren, L.: Synthesis, luminescence, and photocatalytic activity of KLa2Ti3O9.5:Er3+ nanocrystals for water decomposition to hydrogen. J. Mater. Res. 27, 2925 (2012).CrossRefGoogle Scholar
Ikeda, S., Hara, M., Kondo, J.N., Domen, K., Takahashi, H., Okubo, T., and Kakihana, M.: Preparation of a high active photocatalyst, K2La2Ti3O10, by polymerized complex method and its photocatalytic activity of water splitting. J. Mater. Res. 13, 852 (1998).CrossRefGoogle Scholar
Domen, K., Takata, T., Ikeda, S., Shinohara, K., Tanaka, A., Hara, M., and Kondo, J.: Ion-exchangeable oxides with layered perovskite structures as photocatalysts for overall water splitting. J. Mater. Res. 454, 177 (1996).Google Scholar
Jitputti, J., Rattanavoravipa, T., Chuangchote, S., Pavasupree, S., Suzuki, Y., and Yoshikawa, S.: Low temperature hydrothermal synthesis of monodispersed flower-like titanate nanosheets. Catal. Commun. 10, 378 (2009).CrossRefGoogle Scholar
Chuangchote, S., Jitputti, J., Sagawa, T., and Yoshikawa, S.: Photocatalytic activity for hydrogen evolution of electrospun TiO2 nanofibers. ACS Appl. Mater. Interfaces 1, 1140 (2009).CrossRefGoogle ScholarPubMed
Jitputti, J., Pavasupree, S., Suzuki, Y., and Yoshikawa, S.: Synthesis of TiO2 nanotubes and its photocatalytic activity for H2 evolution. Jpn. J. Appl. Phys. 47, 751 (2008).CrossRefGoogle Scholar
Jitputti, J., Suzuki, Y., and Yoshikawa, S.: Synthesis of TiO2 nanowires and their photocatalytic activity for hydrogen evolution. Catal. Commun. 9, 1265 (2008).CrossRefGoogle Scholar
Jang, J., Choi, S., Kim, D., Jang, J., Lee, K., and Lee, J.: Enhanced photocatalytic hydrogen production from water–methanol solution by nickel intercalated into titanate nanotube. J. Phys. Chem. C 113, 8990 (2009).CrossRefGoogle Scholar
Chen, X., Li, C., Grätzel, M., Kostecki, R., and Mao, S.: Nanomaterials for renewable energy production and storage. Chem. Soc. Rev. 41, 7909 (2012).CrossRefGoogle ScholarPubMed
Zhou, X., Liu, Y., Li, X., Gao, Q., Liu, X., and Fang, Y.: Topological morphology conversion towards SnO2/SiC hollow sphere nanochains with efficient photocatalytic hydrogen evolution. Chem. Commun. 50, 1070 (2013).CrossRefGoogle Scholar
Mizoguchi, H., Ueda, K., Orita, M., Moon, S., Kajihara, K., Hiranl, M., and Hosono, H.: Decomposition of water by a CaTiO3 photocatalyst under UV light irradiation. Mater. Res. Bull. 37, 2401 (2002).CrossRefGoogle Scholar
Lopes, K., Cavalcante, L., Simões, A., Varela, J., Longo, E., and Leite, E.: NiTiO3 powders obtained by polymeric precursor method: Synthesis and characterization. J. Alloys Compd. 468, 327 (2009).CrossRefGoogle Scholar
Xu, Y. and Schoonen, A.A.: The absolute energy positions of conduction and valence bands of selected semiconducting minerals. Am. Mineral. 85, 543 (2000).CrossRefGoogle Scholar
Jang, J., Borse, P., Lee, J., Lim, K., Jung, Q., Jeong, E., Bae, J., and Kim, H.: Photocatalytic hydrogen production in water-methanol mixture over iron-doped CaTiO3 . Bull. Korean Chem. Soc. 32, 95 (2011).CrossRefGoogle Scholar
Hu, L., Peng, Q., and Li, Y.: Selective synthesis of Co3O nanocrystal with different shape and crystal plane effect on catalytic property for methane combustion. J. Am. Chem. Soc. 130, 16136 (2008).CrossRefGoogle Scholar
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