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Preparation of a solid amine adsorbent based on polypropylene fiber and its performance for CO2 capture

Published online by Cambridge University Press:  16 October 2013

Linzhou Zhuang ,
Shuixia Chen ,
Rijia Lin  and
Xiuzhu Xu
Linzhou Zhuang
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
Shuixia Chen*
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China; and DSAPM Lab, Materials Science Institute, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
Rijia Lin
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
Xiuzhu Xu
Affiliation:
PCFM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: cescsx@mail.sysu.edu.cn
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Abstract

A novel kind of solid amine-containing fibrous adsorbent (PP-GMA-TETA) was prepared through irradiation grafting copolymerization with glycidyl methacrylate (GMA) onto polypropylene (PP) fiber, followed by reacting with triethylenetetramine (TETA) to introduce primary and secondary amine groups on its surface. The effects of the reaction conditions, such as the TETA concentration, temperature, and reaction time on amination degree of PP-GMA-TETA, were investigated. Adsorption capacity of PP-GMA-TETA with 77.7% amination degree could reach 4.72 mmol/g. After adsorption, the spent fiber could be completely regenerated at 100 °C by steam for 20 min and its adsorption behavior kept almost constant within six recycles. The comparison of adsorption capacities of amine fibers aminated with various aminating agents also demonstrated that fibers with higher content of primary amine would obtain faster adsorption rates and higher adsorption capacities.

Keywords

polypropyleneaminecarbon dioxide

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Type
Articles
Information
Journal of Materials Research , Volume 28 , Issue 20 , 28 October 2013 , pp. 2881 - 2889
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

Siriwardane, R.V., Shen, M-S., Fisher, E.P., and Poston, J.A.: Adsorption of CO2 on molecular sieves and activated carbon. Energy Fuels 15, 279 (2001).CrossRefGoogle Scholar
Li, W., Choi, S., Drese, J.H., Hornbostel, M., Krishnan, G., Eisenberger, P.M., and Jones, C.W.: Steam-stripping for regeneration of supported amine-based CO2 adsorbents. ChemSusChem 3, 899 (2010).CrossRefGoogle Scholar
Gray, M.L., Soong, Y., Champagne, K.J., Pennline, H., Baltrus, J.P., Stevens, R.W. Jr., Khatri, R., Chuang, S.S.C., and Filburn, T.: Improved immobilized carbon dioxide capture sorbents. Fuel Process. Technol. 86, 1449 (2005).CrossRefGoogle Scholar
Hicks, J.C., Drese, J.H., Fauth, D.J., Gray, M.L., Qi, G.G., and Jones, C.W.: Designing adsorbents for CO2 capture from flue gas-hyperbranched aminosilicas capable of capturing CO2 reversibly. J. Am. Chem. Soc. 130, 2902 (2008).CrossRefGoogle ScholarPubMed
Zukal, A., Dominguez, I., Mayerova, J., and Cejka, J.: Functionalization of delaminated zeolite ITQ-6 for the adsorption of carbon dioxide. Langmuir 25, 10314 (2009).CrossRefGoogle ScholarPubMed
Cui, Y., Kita, H., and Okamoto, K-I.: Preparation and gas separation performance of zeolite T membrane. J. Mater. Chem. 14, 924 (2004).CrossRefGoogle Scholar
Pevida, C., Plaza, M.G., Arias, B., Fermoso, J., Rubiera, F., and Pis, J.J.: Surface modification of activated carbons for CO2 capture. Appl. Surf. Sci. 254, 7165 (2008).CrossRefGoogle Scholar
Van der vaart, R., Huiskes, C., Bosch, H., and Reith, T.: Single and mixed gas adsorption equilibria of carbon dioxide/methane on activated carbon. Adsorption 6, 311 (2000).CrossRefGoogle Scholar
Drese, J.H., Choi, S., Lively, R.P., Koros, W.J., Fauth, D.J., Gray, M.L., and Jones, C.W.: Synthesis-structure-property relationships for hyperbranched aminosilica CO2 adsorbents. Adv. Funct. Mater. 19, 3821 (2009).CrossRefGoogle Scholar
Knowles, G.P., Graham, J.V., Delaney, S.W., and Chaffee, A.L.: Aminopropyl-functionalized mesoporous silicas as CO2 adsorbents. Fuel Process. Technol. 86, 1435 (2005).CrossRefGoogle Scholar
Zhang, Q., Zhang, S., Chen, S., Li, P., Qin, T., and Yuan, S.: Preparation and characterization of a strong basic anion exchanger by radiation-induced grafting of styrene onto poly(tetrafluoroethylene) fiber. J. Colloid Interface Sci. 322, 421 (2008).CrossRefGoogle Scholar
Yang, Y., Li, H., Chen, S., Zhao, Y., and Li, Q.: Preparation and characterization of a solid amine adsorbent for capturing CO2 by grafting allylamine onto PAN fiber. Langmuir 26, 13897 (2010).CrossRefGoogle ScholarPubMed
Li, P., Ge, B., Zhang, S., Chen, S., Zhang, Q., and Zhao, Y.: CO2 capture by polyethylenimine-modified fibrous adsorbent. Langmuir 24, 6567 (2008).CrossRefGoogle ScholarPubMed
Yang, Y., Ma, N., Zhang, Q., and Chen, S.: Adsorption of Hg2+ on a novel chelating fiber prepared by preirradiation grafting and amination. J. Appl. Polym. Sci. 113, 3638 (2009).CrossRefGoogle Scholar
Gray, M.L., Hoffman, J.S., Hreha, D.C., Fauth, D.J., Hedges, S.W., Champagne, K.J., and Pennline, H.W.: Parametric study of solid amine sorbents for the capture of carbon dioxide. Energy Fuels 23, 4840 (2009).CrossRefGoogle Scholar
Serna-Guerrero, R. and Sayari, A.: Modeling adsorption of CO2 on amine-functionalized mesoporous silica. 2: Kinetics and breakthrough curves. Chem. Eng. J. 161, 182 (2010).CrossRefGoogle Scholar
Zeleňák, V., Badaničová, M., Halamová, D., Čejka, J., Zukal, A., Murafa, N., and Goerigk, G.: Amine-modified ordered mesoporous silica: Effect of pore size on carbon dioxide capture. Chem. Eng. J. 144, 336 (2008).CrossRefGoogle Scholar
Hiyoshi, N., Yogo, K., and Yashima, T.: Adsorption characteristics of carbon dioxide on organically functionalized SBA-15. Microporous Mesoporous Mater. 84, 357 (2005).CrossRefGoogle Scholar
Meth, S., Goeppert, A., Surya Prakash, G.K., and Olah, G.A.: Silica nanoparticles as supports for regenerable CO2 sorbents. Energy Fuels 26, 3082 (2012).CrossRefGoogle Scholar
Ko, Y.G., Shin, S.S., and Choi, U.S.: Primary, secondary, and tertiary amines for CO2 capture: Designing for mesoporous CO2 adsorbents. J. Colloid Interface Sci. 361, 594 (2011).CrossRefGoogle ScholarPubMed
Sartorl, G. and Savage, D.W.: Sterically hindered amines for CO2 removal from gases. Ind. Eng. Chem. Fundam. 22, 239 (1983).CrossRefGoogle Scholar