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Rapid sol–gel synthesis of nanodiamond aerogel

  • Sandeep Manandhar (a1), Paden B. Roder (a1), Jennifer L. Hanson (a1), Matthew Lim (a1), Bennett E. Smith (a2), Austin Mann (a3) and Peter J. Pauzauskie (a4)...
Abstract
Abstract

The rapid sol–gel synthesis of macroscopic quantities of nanodiamond aerogel (NDAG) is reported at standard temperature and pressure using acid-catalyzed covalent crosslinking of air-oxidized detonation nanodiamond (DND) nanocrystals. Acetonitrile acts as a polar, aprotic solvent both to form a colloidal dispersion of DND particles and to conduct acid-catalyzed polycondensation reactions between resorcinol and formaldehyde (RF) small molecule precursors. Several characterization techniques show that nanodiamond grains are connected via covalent bonding with RF molecules to form a porous, three-dimensional network. Solvent exchange into liquid carbon dioxide and subsequent supercritical drying of NDAGs are used to recover low-density (151 mg/cm3), three-dimensional monolithic aerogels that exhibit surface areas in excess of 589 m2/g. The large accessible pore volume from the rapidly synthesized, macroscopic NDAG materials suggests a range of potential applications in catalysis, sensing, energy storage, as well as inert excipients for small-molecule pharmaceuticals.

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a)Address all correspondence to this author. e-mail: peterpz@uw.edu
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This list contains references from the content that can be linked to their source. For a full set of references and notes please see the PDF or HTML where available.

V.N. Mochalin , O. Shenderova , D. Ho , and Y. Gogotsi : The properties and applications of nanodiamonds. Nat. Nanotechnol. 7(1), 11 (2012).

C-C. Fu , H-Y. Lee , K. Chen , T-S. Lim , H-Y. Wu , P-K. Lin , P-K. Wei , P-H. Tsao , H-C. Chang , and W. Fann : Characterization and application of single fluorescent nanodiamonds as cellular biomarkers. Proc. Natl. Acad. Sci. U.S.A. 104(3), 727 (2007).

H-J. Kim , K. Zhang , L. Moore , and D. Ho : Diamond nanogel-embedded contact lenses mediate lysozyme-dependent therapeutic release. ACS Nano 8, 29983005 (2014).

Q. Wang , N. Plylahan , M.V. Shelke , R.R. Devarapalli , M.S. Li , P. Subramanian , T. Djenizian , R. Boukherroub , and S. Szunerits : Nanodiamond particles/reduced graphene oxide composites as efficient supercapacitor electrodes. Carbon 68, 175 (2014).

O. Shenderova , A.M. Panich , S. Moseenkov , S.C. Hens , V. Kuznetsov , and H.M. Vieth : Hydroxylated detonation nanodiamond: FTIR, XPS, and NMR studies. J. Phys. Chem. C 115(39), 19005 (2011).

N. Mohan , Y-K. Tzeng , L. Yang , Y-Y. Chen , Y.Y. Hui , C-Y. Fang , and H-C. Chang : Sub-20-nm fluorescent nanodiamonds as photostable biolabels and fluorescence resonance energy transfer donors. Adv. Mater. 22(7), 843 (2010).

S.J. Yu , M.W. Kang , H.C. Chang , K.M. Chen , and Y.C. Yu : Bright fluorescent nanodiamonds: No photobleaching and low cytotoxicity. J. Am. Chem. Soc. 127(50), 17604 (2005).

Y.R. Chang , H.Y. Lee , K. Chen , C.C. Chang , D.S. Tsai , C.C. Fu , T.S. Lim , Y.K. Tzeng , C.Y. Fang , C.C. Han , H.C. Chang , and W. Fann : Mass production and dynamic imaging of fluorescent nanodiamonds. Nat. Nanotechnol. 3(5), 284 (2008).

F. Neugart , A. Zappe , F. Jelezko , C. Tietz , J.P. Boudou , A. Krueger , and J. Wrachtrup : Dynamics of diamond nanoparticles in solution and cells. Nano Lett. 7(12), 3588 (2007).

D. Zhu , L.H. Zhang , R.E. Ruther , and R.J. Hamers : Photo-illuminated diamond as a solid-state source of solvated electrons in water for nitrogen reduction. Nat. Mater. 12(9), 836 (2013).

K.D. Kim , N.K. Dey , H.O. Seo , Y.D. Kim , D.C. Lim , and M. Lee : Photocatalytic decomposition of toluene by nanodiamond-supported TiO2 prepared using atomic layer deposition. Appl. Catal., A 408(1–2), 148 (2011).

I.I. Vlasov , A.A. Shiryaev , T. Rendler , S. Steinert , S-Y. Lee , D. Antonov , M. Voros , F. Jelezko , A.V. Fisenko , L.F. Semjonova , J. Biskupek , U. Kaiser , O.I. Lebedev , I. Sildos , P.R. Hemmer , V.I. Konov , A. Gali , and J. Wrachtrup : Molecular-sized fluorescent nanodiamonds. Nat. Nanotechnol. 9(1), 54 (2014).

H.C. Chang , K.W. Chen , and S. Kwok : Nanodiamond as a possible carrier of extended red emission. Astrophys. J. 639(2), L63 (2006).

G.K. Ustinova : Production of anomalous Xe in nanodiamond in chondrites during the last supernova explosion predating the origin of the solar system. Geochem. Int. 49(6), 555 (2011).

A.P. Jones : The mineralogy of cosmic dust: Astromineralogy. Eur. J. Mineral. 19(6), 771 (2007).

M.V. Korobov , N.V. Avramenko , A.G. Bogachev , N.N. Rozhkova , and E. Ōsawa : Nanophase of water in nano-diamond gel. J. Phys. Chem. C 111(20), 7330 (2007).

P.J. Pauzauskie , J.C. Crowhurst , M.A. Worsley , T.A. Laurence , A.L.D. Kilcoyne , Y. Wang , T.M. Willey , K.S. Visbeck , S.C. Fakra , W.J. Evans , J.M. Zaug , and J.H. Satcher Jr.: Synthesis and characterization of a nanocrystalline diamond aerogel. Proc. Natl. Acad. Sci. U.S.A. 108(21), 8550 (2011).

M. Mandal and K. Landskron : Synthetic chemistry with periodic mesostructures at high pressure. Acc. Chem. Res. 46(11), 2536 (2013).

D. Brownlee , P. Tsou , J. Aleon , C.M.O. Alexander , T. Araki , S. Bajt , G.A. Baratta , R. Bastien , P. Bland , P. Bleuet , J. Borg , J.P. Bradley , A. Brearley , F. Brenker , S. Brennan , J.C. Bridges , N.D. Browning , J.R. Brucato , E. Bullock , M.J. Burchell , H. Busemann , A. Butterworth , M. Chaussidon , A. Cheuvront , M.F. Chi , M.J. Cintala , B.C. Clark , S.J. Clemett , G. Cody , L. Colangeli , G. Cooper , P. Cordier , C. Daghlian , Z.R. Dai , L. D'Hendecourt , Z. Djouadi , G. Dominguez , T. Duxbury , J.P. Dworkin , D.S. Ebel , T.E. Economou , S. Fakra , S.A.J. Fairey , S. Fallon , G. Ferrini , T. Ferroir , H. Fleckenstein , C. Floss , G. Flynn , I.A. Franchi , M. Fries , Z. Gainsforth , J.P. Gallien , M. Genge , M.K. Gilles , P. Gillet , J. Gilmour , D.P. Glavin , M. Gounelle , M.M. Grady , G.A. Graham , P.G. Grant , S.F. Green , F. Grossemy , L. Grossman , J.N. Grossman , Y. Guan , K. Hagiya , R. Harvey , P. Heck , G.F. Herzog , P. Hoppe , F. Horz , J. Huth , I.D. Hutcheon , K. Ignatyev , H. Ishii , M. Ito , D. Jacob , C. Jacobsen , S. Jacobsen , S. Jones , D. Joswiak , A. Jurewicz , A.T. Kearsley , L.P. Keller , H. Khodja , A.L.D. Kilcoyne , J. Kissel , A. Krot , F. Langenhorst , A. Lanzirotti , L. Le , L.A. Leshin , J. Leitner , L. Lemelle , H. Leroux , M.C. Liu , K. Luening , I. Lyon , G. MacPherson , M.A. Marcus , K. Marhas , B. Marty , G. Matrajt , K. McKeegan , A. Meibom , V. Mennella , K. Messenger , S. Messenger , T. Mikouchi , S. Mostefaoui , T. Nakamura , T. Nakano , M. Newville , L.R. Nittler , I. Ohnishi , K. Ohsumi , K. Okudaira , D.A. Papanastassiou , R. Palma , M.E. Palumbo , R.O. Pepin , D. Perkins , M. Perronnet , P. Pianetta , W. Rao , F.J.M. Rietmeijer , F. Robert , D. Rost , A. Rotundi , R. Ryan , S.A. Sandford , C.S. Schwandt , T.H. See , D. Schlutter , J. Sheffield-Parker , A. Simionovici , S. Simon , I. Sitnitsky , C.J. Snead , M.K. Spencer , F.J. Stadermann , A. Steele , T. Stephan , R. Stroud , J. Susini , S.R. Sutton , Y. Suzuki , M. Taheri , S. Taylor , N. Teslich , K. Tomeoka , N. Tomioka , A. Toppani , J.M. Trigo-Rodriguez , D. Troadec , A. Tsuchiyama , A.J. Tuzzolino , T. Tyliszczak , K. Uesugi , M. Velbel , J. Vellenga , E. Vicenzi , L. Vincze , J. Warren , I. Weber , M. Weisberg , A.J. Westphal , S. Wirick , D. Wooden , B. Wopenka , P. Wozniakiewicz , I. Wright , H. Yabuta , H. Yano , E.D. Young , R.N. Zare , T. Zega , K. Ziegler , L. Zimmerman , E. Zinner , and M. Zolensky : Comet 81P/Wild 2 under a microscope. Science 314(5806), 1711 (2006).

S. Osswald , G. Yushin , V. Mochalin , S.O. Kucheyev , and Y. Gogotsi : Control of sp2/sp3 carbon ratio and surface chemistry of nanodiamond powders by selective oxidation in air. J. Am. Chem. Soc. 128(35), 11635 (2006).

A. Kruger , Y. Liang , G. Jarre , and J. Stegk : Surface functionalisation of detonation diamond suitable for biological applications. J. Mater. Chem. 16(24), 2322 (2006).

T. Gaebel , C. Bradac , J. Chen , J.M. Say , L. Brown , P. Hemmer , and J.R. Rabeau : Size-reduction of nanodiamonds via air oxidation. Diamond Relat. Mater. 21(0), 28 (2012).

S. Yusuf , M. Krahenbuhl , B. Haskins , and M. Hartman : Improving neutron activation analysis accuracy for the measurement of gold in the characterization of heterogeneous catalysts using a TRIGA reactor. J. Radioanal. Nucl. Chem. 296(1), 23 (2013).

S. Mulik , C. Sotiriou-Leventis , and N. Leventis : Time-efficient acid-catalyzed synthesis of resorcinol-formaldehyde aerogels. Chem. Mater. 19(25), 6138 (2007).

D.P. Mitev , A.T. Townsend , B. Paull , and P.N. Nesterenko : Direct sector field ICP-MS determination of metal impurities in detonation nanodiamond. Carbon 60(0), 326 (2013).

S. Ji , T. Jiang , K. Xu , and S. Li : FTIR study of the adsorption of water on ultradispersed diamond powder surface. Appl. Surf. Sci. 133(4), 231 (1998).

T. Jiang and K. Xu : FTIR study of ultradispersed diamond powder synthesized by explosive detonation. Carbon 33(12), 1663 (1995).

V.L. Kuznetsov , M.N. Aleksandrov , I.V. Zagoruiko , A.L. Chuvilin , E.M. Moroz , V.N. Kolomiichuk , V.A. Likholobov , P.M. Brylyakov , and G.V. Sakovitch : Study of ultradispersed diamond powders obtained using explosion energy. Carbon 29(4–5), 665 (1991).

W.S. Yeap , Y.Y. Tan , and K.P. Loh : Using detonation nanodiamond for the specific capture of glycoproteins. Anal. Chem. 80(12), 4659 (2008).

T. Sharda , M.M. Rahaman , Y. Nukaya , T. Soga , T. Jimbo , and M. Umeno : Structural and optical properties of diamond and nano-diamond films grown by microwave plasma chemical vapor deposition. Diamond Relat. Mater. 10(3–7), 561 (2001).

C. Lin and J.A. Ritter : Effect of synthesis pH on the structure of carbon xerogels. Carbon 35(9), 1271 (1997).

M.S. Song , S. Nahm , and Y.J. Oh : Preparation and electrochemical properties of carbon cryogel for supercapacitor. J. Korean Ceram. Soc. 45(11), 662 (2008).

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