Skip to main content
×
Home
    • Aa
    • Aa
  • Get access
    Check if you have access via personal or institutional login
  • Cited by 496
  • Cited by
    This article has been cited by the following publications. This list is generated based on data provided by CrossRef.

    Al-Hussaini, Ayman S. and Eldars, Waleed 2016. Cheap Synthesis, Characterization and Antibacterial Efficacy of New Copoly(o-Nitroaniline-co-o-Phenylenediamine) Emeraldine Base/Bentonite Composites. Journal of Inorganic and Organometallic Polymers and Materials, Vol. 26, Issue. 3, p. 691.


    Ali, Zulfiqar Le, Hai Hong Iqbal, Javed Hussain, Murid Hussain, Hazrat Mahmood, Nasir Nawaz Khan, Ahmad and Radusch, HansJoachim 2016. Dynamics of migration and phase selective localization of nanoclay in HNBR/ENR blends. Journal of Applied Polymer Science, Vol. 133, Issue. 41,


    Blackman, B.R.K. Steininger, H. Williams, J.G. and Zuo, K. 2016. The fatigue behaviour of ZnO nano-particle modified thermoplastics. Composites Science and Technology, Vol. 122, p. 10.


    Dasari, Aravind Yu, Zhong-Zhen and Mai, Yiu-Wing 2016. Polymer Nanocomposites.


    Greesh, Nagi and Ray, Suprakas Sinha 2016. Impact of non-ionic surfactant chemical structure on morphology and stability of polystyrene nanocomposite latex. Colloid and Polymer Science, Vol. 294, Issue. 1, p. 157.


    Hutchinson, John M. 2016. The application of thermal analysis to the study of epoxy–clay nanocomposites. Journal of Thermal Analysis and Calorimetry, Vol. 125, Issue. 2, p. 617.


    Karatrantos, Argyrios Clarke, Nigel and Kröger, Martin 2016. Modeling of Polymer Structure and Conformations in Polymer Nanocomposites from Atomistic to Mesoscale: A Review. Polymer Reviews, Vol. 56, Issue. 3, p. 385.


    Malinová, Lenka Jaksch, Daniel and Brožek, Jiří 2016. Montmorillonite modified with lactim methyl ethers having different ring sizes. Applied Clay Science, Vol. 129, p. 20.


    Mondal, Titash Bhowmick, Anil K. Ghosal, Ranjan and Mukhopadhyay, Rabindra 2016.


    Nie, Yijing Hao, Tongfan Wei, Ya and Zhou, Zhiping 2016. Polymer crystal nucleation with confinement-enhanced orientation dominating the formation of nanohybrid shish-kebabs with multiple shish. RSC Adv., Vol. 6, Issue. 56, p. 50451.


    Rapacz-Kmita, A. Moskała, N. Dudek, M. Gajek, M. and Mandecka-Kamień, L. 2016. Influence of the Organophilisation Process on Properties of the Bentonite Filler and Mechanical Properties of the Clay/Epoxy Nanocomposites. Archives of Metallurgy and Materials, Vol. 61, Issue. 2,


    Shukla, S.K. Govender, P.P. and Tiwari, A. 2016.


    Vivanco, Hector K. and Rodriguez, Efrain E. 2016. The intercalation chemistry of layered iron chalcogenide superconductors. Journal of Solid State Chemistry,


    Xiao, Junfeng Chen, Yangyang Wang, Shaofeng Lu, Ping and Hu, Yuan 2016. Thermal degradation mechanism of polycarbonate/organically modified montmorillonite nanocomposites. Polymer Composites, Vol. 37, Issue. 8, p. 2301.


    Ashhari, Shabnam and Sarabi, Ali Asghar 2015. Effects of organically modified nanoclay particles on the mechanical properties of aliphatic polyurethane/clay nanocomposite coatings. Polymer Composites, p. n/a.


    Balasubramanian, M. and Jawahar, P. 2015. Polymer Nanocomposites Based on Inorganic and Organic Nanomaterials.


    Chao(Wu), Victor Wei-Keh Hsu, Chao-Chen Lu, Wei-Ming Chen, Wen-Jing Naveen, Bunekar and Tsai, Tsung-Yen 2015. Protein-concentration-dependent adsorption behaviour of inorganic layered materials. RSC Adv., Vol. 5, Issue. 15, p. 10936.


    Emre, Fatma Bilge Kesik, Melis Kanik, Fulya Ekiz Akpinar, Hava Zekiye Aslan-Gurel, Evren Rossi, Rene M. and Toppare, Levent 2015. A benzimidazole-based conducting polymer and a PMMA–clay nanocomposite containing biosensor platform for glucose sensing. Synthetic Metals, Vol. 207, p. 102.


    Gelineau, P. Stepień, M. Weigand, S. Cauvin, L. and Bédoui, F. 2015. Elastic properties prediction of nano-clay reinforced polymer using multi-scale modeling based on a multi-scale characterization. Mechanics of Materials, Vol. 89, p. 12.


    Ghasemi Nejhad, Mehrdad N. 2015. Multifunctionality of Polymer Composites.


    ×

Swelling behavior of montmorillonite cation exchanged for ω-amino acids by ∊-caprolactam

  • Arimitsu Usuki (a1), Masaya Kawasumi (a1), Yoshitsugu Kojima (a1), Akane Okada (a1), Toshio Kurauchi (a1) and Osami Kamigaito (a1)
  • DOI: http://dx.doi.org/10.1557/JMR.1993.1174
  • Published online: 01 January 2011
Abstract

Natural Na-montmorillonite was cation exchanged for the ammonium cations of various ω-amino acids [H3N+(CH2)n−1 COOH, n = 2, 3, 4, 5, 6, 8, 11, 12, and 18]. X-ray diffraction (XRD) results suggested that the chain axes of ω-amino acids with a carbon number of eight or less were parallel to the silicate layers, and that the chain axes of those with a carbon number of 11 or more were slanted to the layers. The cation-exchanged montmorillonites form intercalated compounds with ∊-caprolactam at 25 °C. The montmorillonites intercalated with both ω-amino acid and ∊-caprolactam were studied by XRD measurement at room temperature and 100 °C. We propose a model where amino acid molecules were arranged perpendicular to silicate layers and ∊-caprolactam molecules filled the space between them. When the ∊-caprolactam was melted at 100 °C, the basal spacing for the montmorillonite increased, in which the carbon number exceeds 11. This phenomenon will be applicable to obtaining the nylon 6-clay hybrid, a molecular composite of nylon 6 and montmorillonite.

Copyright
Linked references
Hide All

This list contains references from the content that can be linked to their source. For a full set of references and notes please see the PDF or HTML where available.

1K. Norrish , Discuss. Faraday Soc. 18, 120 (1954).

2Y. Fukushima , Clay and Clay Minerals 32, 320 (1984).

4A. Weiss , Angew. Chem. Int. Ed. Eng. 2, 134 (1963).

7G. Lagaly , Angew. Chem. Int. Ed. Eng. 15, 575 (1976).

Recommend this journal

Email your librarian or administrator to recommend adding this journal to your organisation's collection.

Journal of Materials Research
  • ISSN: 0884-2914
  • EISSN: 2044-5326
  • URL: /core/journals/journal-of-materials-research
Please enter your name
Please enter a valid email address
Who would you like to send this to? *
×