Skip to main content
×
×
Home

Synthesis of hyperbranched poly(amine–ester)-protected noble metal nanoparticles in aqueous solution

  • Chunyan Bao (a1), Ming Jin (a1), Ran Lu (a1), Pengchong Xue (a1), Tierui Zhang (a1), Changhui Tan (a1) and Yingying Zhao (a1)...
Abstract

The synthesis of Au and Ag metal nanoparticles stabilized by G4, G5, and G6 hyperbranched poly(amine–ester) (HPAE) is reported. The reduction of hydrogen tetrachloroaurate and silver nitrate in the presence of HPAE resulted in the formation of stable, uniform, water-soluble nanoparticles. The average particle sizes are (2.4 ±0.5)–(4.1 ±0.4) nm for Au and (2.5 ±4.9)–(10.3 ±1.7) nm for Ag, depending on the generation of HPAE and metal ion-to-end tertiary amine of HPAE (M:N) used. All of the obtained colloidal solutions are stable for a long period of time. The results from ultraviolet–visible absorption spectra and Fourier transform infrared absorption spectroscopic investigations confirm the interactions between metal and HPAE.

Copyright
Corresponding author
a)Address all correspondence to this author. e-mail: luran@mail.jlu.edu.cn
References
Hide All
1.Lewis, L.N., Chem. Rev. 93, 2693 (1993).
2.Volokitin, Y., Sinzig, J., Jong, L.J. de, Schmid, G., Vargaftik, M.N., and Moiseev, I.I., Nature 384, 621 (1996).
3.Hache, F., Richard, D., Flytzanis, C., and Kreibig, U., Appl. Phys. A 47, 347 (1988).
4.Wang, M.T. and Zhang, L.D., J. Mater. Res. 16, 765 (2001).
5.Yonezawa, T., Konishi, Y., Hada, H., Yamamoto, K., and Ishida, H., Thin Solid Films 218, 109 (1992).
6.Ware, M.J., J. Photogr. Sci. 42, 157 (1994).
7.Haruta, M., Catal. Today 36, 153 (1997).
8.Ahmadi, T.S., Wang, Z.L., Green, T.C., Henglein, A., and El-Sayed, M.A, Science 272, 1924 (1996).
9.Shi, D.L., He, P., Wang, S.X., Ooij, W.J. Van, Wang, L.M., Zhao, J.G., and Yu, Z., J. Mater. Res. 17, 981 (2002).
10.Zhang, Y.J., Wang, N.L, Gao, S.P., He, R.R., Miao, S., Liu, J., Zhu, J., and Zhang, X., Chem. Mater. 14, 3564 (2002).
11.Armelao, L., Bertoncello, R., Cattaruzza, E., Gialanella, S., Gross, S., Mattei, G., Mazzoldi, P., and Tondello, E., J. Mater. Chem. 12, 2401 (2002).
12.Schmid, G. and Lehnert, A., Angew. Chem., Int. Ed. Engl. 28, 780 (1989).
13.Fink, J., Kiely, C.J., Bethell, D., and Schiffrin, D.J., Chem. Mater. 10, 922 (1998).
14.Nakamoto, M., Yamamoto, M., and Fukusumi, M., Chem. Commun. 1622 (2002).
15.Teranishi, T., Hosoe, M., Tanaka, T., and Miyake, M., J. Phys. Chem. B 103, 3818 (1999).
16.Yonezawa, T. and Toshima, N., J. Chem. Soc., Faraday Trans. 91, 4111 (1995).
17.Esumi, K., Wakabayashi, M., and Torigoe, K., Colloids Surf. 109, 55 (1996).
18.Bradley, J.S., in Clusters and Colloids from Theory to Applications, edited by Schmid, G. (VCH, Weinheim, Germany, 1994), Chap. 6, p. 8.
19.Esumi, K., Sato, N., and Meguro, K., J. Colloid Interface Sci. 149, 295 (1992).
20.Meguro, K., Nakamura, Y., Hayashi, Y., Torizuka, M., and Esumi, K., Bull. Chem. Soc. Jpn. 61, 347 (1988).
21.Nakao, Y. and Kaeriyama, K., J. Colloid Interface Sci. 110, 82 (1986).
22.Zhang, Z.L., Guo, L., and Wang, W.D., J. Mater. Res. 16, 803 (2001).
23.Esumi, K., Suzuki, A., Aihara, N., Usui, K., and Torigoe, K., Langmuir 14, 3157 (1998).
24.Balogh, L., Valluzzi, R., Laverdure, K.S., Gido, S.P., Hagnauer, G.L., and Tomalia, D.A., J. Nanopart. Res. 1, 353 (1999).
25.Hedden, R.C., Bauer, B.J., Smith, A.P., Gro¨hn, F., Amis, E., Polymer 43, 5473 (2002).
26.Lu, Y., Lin, D., Wei, H.Y., and Shi, W.F., Acta Polym. Sin. 4, 411 (2000).
27.Garcia, M.E., Baker, L.A., and Crooks, R.M., Anal. Chem. 71, 256 (1999).
28.Tin, A.H., Regina, V., and Ke, Y., Chem. Mater. 11, 3268 (1999).
29.Emsley, J., The Elements, 3rd ed. (Clarendon Press, Oxford, U.K., 1998), pp. 88, 192.
30.Laibinis, P.E., Whitesides, G.M., Allara, D.L., Tao, Y.T., Parikh, A.N., and Nuzzo, R.G., J. Am. Chem. Soc. 113, 7152 (1991).
31.Brust, M., Fink, J., Bethell, D., Schiffrin, J., and Kiely, C., J. Chem. Soc., Chem. Commun. 1655 (1995).
32.Alvarez, M.M., Khoury, J.T., Schaaff, T.G., Shafigullin, M.N., Vezmer, I., Whetten, R.L., J. Phys. Chem. 97, 5457 (1993).
33.Henglein, A., J. Phys. Chem. 97, 5457 (1993).
34.Beaglehole, D. and Hunderi, O., Phys. Rev. B 2, 390 (1970).
Recommend this journal

Email your librarian or administrator to recommend adding this journal to your organisation's collection.

Journal of Materials Research
  • ISSN: 0884-2914
  • EISSN: 2044-5326
  • URL: /core/journals/journal-of-materials-research
Please enter your name
Please enter a valid email address
Who would you like to send this to? *
×

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 15 *
Loading metrics...

Abstract views

Total abstract views: 84 *
Loading metrics...

* Views captured on Cambridge Core between September 2016 - 23rd July 2018. This data will be updated every 24 hours.