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Synthesis of hyperbranched poly(amine–ester)-protected noble metal nanoparticles in aqueous solution

Published online by Cambridge University Press:  31 January 2011

Chunyan Bao ,
Ming Jin ,
Ran Lu ,
Pengchong Xue ,
Tierui Zhang ,
Changhui Tan  and
Yingying Zhao
Chunyan Bao
Affiliation:
Department of Organic Chemistry, College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, People's Republic of China
Ming Jin
Affiliation:
Department of Organic Chemistry, College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, People's Republic of China
Ran Lu*
Affiliation:
Department of Organic Chemistry, College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, People's Republic of China
Pengchong Xue
Affiliation:
Department of Organic Chemistry, College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, People's Republic of China
Tierui Zhang
Affiliation:
Department of Organic Chemistry, College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, People's Republic of China
Changhui Tan
Affiliation:
Department of Organic Chemistry, College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, People's Republic of China
Yingying Zhao
Affiliation:
Department of Organic Chemistry, College of Chemistry, Jilin University, 119 Jiefang Road, Changchun 130023, People's Republic of China
*
a)Address all correspondence to this author. e-mail: luran@mail.jlu.edu.cn
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Abstract

The synthesis of Au and Ag metal nanoparticles stabilized by G4, G5, and G6 hyperbranched poly(amine–ester) (HPAE) is reported. The reduction of hydrogen tetrachloroaurate and silver nitrate in the presence of HPAE resulted in the formation of stable, uniform, water-soluble nanoparticles. The average particle sizes are (2.4 ±0.5)–(4.1 ±0.4) nm for Au and (2.5 ±4.9)–(10.3 ±1.7) nm for Ag, depending on the generation of HPAE and metal ion-to-end tertiary amine of HPAE (M:N) used. All of the obtained colloidal solutions are stable for a long period of time. The results from ultraviolet–visible absorption spectra and Fourier transform infrared absorption spectroscopic investigations confirm the interactions between metal and HPAE.

Type
Articles
Information
Journal of Materials Research , Volume 18 , Issue 6 , June 2003 , pp. 1392 - 1398
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

1.Lewis, L.N., Chem. Rev. 93, 2693 (1993).CrossRefGoogle Scholar
2.Volokitin, Y., Sinzig, J., Jong, L.J. de, Schmid, G., Vargaftik, M.N., and Moiseev, I.I., Nature 384, 621 (1996).CrossRefGoogle Scholar
3.Hache, F., Richard, D., Flytzanis, C., and Kreibig, U., Appl. Phys. A 47, 347 (1988).CrossRefGoogle Scholar
4.Wang, M.T. and Zhang, L.D., J. Mater. Res. 16, 765 (2001).CrossRefGoogle Scholar
5.Yonezawa, T., Konishi, Y., Hada, H., Yamamoto, K., and Ishida, H., Thin Solid Films 218, 109 (1992).CrossRefGoogle Scholar
6.Ware, M.J., J. Photogr. Sci. 42, 157 (1994).CrossRefGoogle Scholar
7.Haruta, M., Catal. Today 36, 153 (1997).CrossRefGoogle Scholar
8.Ahmadi, T.S., Wang, Z.L., Green, T.C., Henglein, A., and El-Sayed, M.A, Science 272, 1924 (1996).CrossRefGoogle Scholar
9.Shi, D.L., He, P., Wang, S.X., Ooij, W.J. Van, Wang, L.M., Zhao, J.G., and Yu, Z., J. Mater. Res. 17, 981 (2002).CrossRefGoogle Scholar
10.Zhang, Y.J., Wang, N.L, Gao, S.P., He, R.R., Miao, S., Liu, J., Zhu, J., and Zhang, X., Chem. Mater. 14, 3564 (2002).CrossRefGoogle Scholar
11.Armelao, L., Bertoncello, R., Cattaruzza, E., Gialanella, S., Gross, S., Mattei, G., Mazzoldi, P., and Tondello, E., J. Mater. Chem. 12, 2401 (2002).CrossRefGoogle Scholar
12.Schmid, G. and Lehnert, A., Angew. Chem., Int. Ed. Engl. 28, 780 (1989).CrossRefGoogle Scholar
13.Fink, J., Kiely, C.J., Bethell, D., and Schiffrin, D.J., Chem. Mater. 10, 922 (1998).CrossRefGoogle Scholar
14.Nakamoto, M., Yamamoto, M., and Fukusumi, M., Chem. Commun. 1622 (2002).Google Scholar
15.Teranishi, T., Hosoe, M., Tanaka, T., and Miyake, M., J. Phys. Chem. B 103, 3818 (1999).CrossRefGoogle Scholar
16.Yonezawa, T. and Toshima, N., J. Chem. Soc., Faraday Trans. 91, 4111 (1995).CrossRefGoogle Scholar
17.Esumi, K., Wakabayashi, M., and Torigoe, K., Colloids Surf. 109, 55 (1996).CrossRefGoogle Scholar
18.Bradley, J.S., in Clusters and Colloids from Theory to Applications, edited by Schmid, G. (VCH, Weinheim, Germany, 1994), Chap. 6, p. 8.Google Scholar
19.Esumi, K., Sato, N., and Meguro, K., J. Colloid Interface Sci. 149, 295 (1992).CrossRefGoogle Scholar
20.Meguro, K., Nakamura, Y., Hayashi, Y., Torizuka, M., and Esumi, K., Bull. Chem. Soc. Jpn. 61, 347 (1988).CrossRefGoogle Scholar
21.Nakao, Y. and Kaeriyama, K., J. Colloid Interface Sci. 110, 82 (1986).CrossRefGoogle Scholar
22.Zhang, Z.L., Guo, L., and Wang, W.D., J. Mater. Res. 16, 803 (2001).CrossRefGoogle Scholar
23.Esumi, K., Suzuki, A., Aihara, N., Usui, K., and Torigoe, K., Langmuir 14, 3157 (1998).CrossRefGoogle Scholar
24.Balogh, L., Valluzzi, R., Laverdure, K.S., Gido, S.P., Hagnauer, G.L., and Tomalia, D.A., J. Nanopart. Res. 1, 353 (1999).CrossRefGoogle Scholar
25.Hedden, R.C., Bauer, B.J., Smith, A.P., Gro¨hn, F., Amis, E., Polymer 43, 5473 (2002).CrossRefGoogle Scholar
26.Lu, Y., Lin, D., Wei, H.Y., and Shi, W.F., Acta Polym. Sin. 4, 411 (2000).Google Scholar
27.Garcia, M.E., Baker, L.A., and Crooks, R.M., Anal. Chem. 71, 256 (1999).CrossRefGoogle Scholar
28.Tin, A.H., Regina, V., and Ke, Y., Chem. Mater. 11, 3268 (1999).Google Scholar
29.Emsley, J., The Elements, 3rd ed. (Clarendon Press, Oxford, U.K., 1998), pp. 88, 192.Google Scholar
30.Laibinis, P.E., Whitesides, G.M., Allara, D.L., Tao, Y.T., Parikh, A.N., and Nuzzo, R.G., J. Am. Chem. Soc. 113, 7152 (1991).CrossRefGoogle Scholar
31.Brust, M., Fink, J., Bethell, D., Schiffrin, J., and Kiely, C., J. Chem. Soc., Chem. Commun. 1655 (1995).Google Scholar
32.Alvarez, M.M., Khoury, J.T., Schaaff, T.G., Shafigullin, M.N., Vezmer, I., Whetten, R.L., J. Phys. Chem. 97, 5457 (1993).Google Scholar
33.Henglein, A., J. Phys. Chem. 97, 5457 (1993).CrossRefGoogle Scholar
34.Beaglehole, D. and Hunderi, O., Phys. Rev. B 2, 390 (1970).CrossRefGoogle Scholar