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Wood cellulose-based thin gel electrolyte with enhanced ionic conductivity

Published online by Cambridge University Press:  13 June 2019

Aswani Poosapati ,
Karla Negrete ,
Nathaniel Jang ,
Liangbing Hu ,
Yucheng Lan  and
Deepa Madan Open the ORCID record for Deepa Madan [Opens in a new window]
Aswani Poosapati
Affiliation:
Department of Mechanical Engineering, University of Maryland, Baltimore County, MD 21250, USA
Karla Negrete
Affiliation:
Department of Mechanical Engineering, University of Maryland, Baltimore County, MD 21250, USA
Nathaniel Jang
Affiliation:
Department of Materials Science and Engineering, University of Maryland, College Park, MD 20740, USA
Liangbing Hu
Affiliation:
Department of Materials Science and Engineering, University of Maryland, College Park, MD 20740, USA
Yucheng Lan
Affiliation:
Department of Physics, Morgan State University, Baltimore, MD 21251, USA
Deepa Madan*
Affiliation:
Department of Mechanical Engineering, University of Maryland, Baltimore County, MD 21250, USA
*
Address all correspondence to Deepa Madan at deemadan@umbc.edu
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Abstract

Polymeric electrolytes have attracted recent research interest because they offer the advantages of being safe and non-flammable, having no dendrite formation, and having no possibility of leakage. The incorporation of synthetic polymers to gel electrolytes has numerous disadvantages: for instance, the required preparation time for creating gel electrolytes from synthetic polymers is dubious and lengthy. Additionally, the conventional pristine polymer gel electrolyte layer has been reported to have low ionic conductivity. This work is focused on preparing a thin flexible gel electrolyte layer by using a naturally occurring wood-based nanofiber cellulose (NFC) hydrogel, to overcome the energy and time consumption of conventional processes. In addition, we use polyvinyl alcohol (PVA) as an additive to the NFC hydrogel in controlled amounts to fabricate a stable thin gel electrolyte layer. By using x-ray diffraction, optical microscopy, and Fourier transform infrared spectra studies, we were able to further our understanding of the microstructure of the films: i.e., the penetration and cross-linking (changes in the bonding structures) of semi-crystalline PVA and hydrogel to form a flexible gel electrolyte layer. The NFC hydrogel-PVA films resulted in much higher ionic conductivity values when compared to other existing pristine polymer electrolytes. The addition of KOH to the NFC hydrogel-PVA further enhanced the ionic conductivity. The best ionic conductivity recorded was 75 mS/cm for films with thickness in the range of 200–350 µm, which is comparable to the highest reported ionic conductivity values of gel electrolytes.

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Type
Research Letters
Information
MRS Communications , Volume 9 , Issue 3 , September 2019 , pp. 1015 - 1021
Copyright
Copyright © Materials Research Society 2019 

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References

1.Dunn, B., Kamath, H., and Tarascon, J.M.: Electrical energy storage for the grid: a battery of choices. Science 334, 928–935 (2011).Google Scholar
2.Sun, C., Liu, J., Gong, Y., Wilkinson, D.P., and Zhang, J.: Recent advances in all-solid-state rechargeable lithium batteries. Nano Energy 33, 363–386 (2017).Google Scholar
3.Gray, F.M. and Gray, F.M.: Solid Polymer Electrolytes: Fundamentals and Technological Applications (VCH, New York, 1991).Google Scholar
4.Scrosati, B., ed: Applications of Electroactive Polymers, 29–74 (Chapman & Hall, 75, London, 1993).Google Scholar
5.Gray, F. M.: Polymer Electrolytes (Royal Society of Chemistry, VCH, New York, 1997).Google Scholar
6.MacCallum, J. R. and Vincent, C.A., eds: Polymer Electrolyte Reviews (Springer Science & Business Media, (New York), 2, 1989).Google Scholar
7.Meyer, W.H.: Polymer electrolytes for lithium-ion batteries. Adv. Mater. 10 439–448 (1998).Google Scholar
8.Song, J.Y., Wang, Y.Y., and Cv Wan, C.: Review of gel-type polymer electrolytes for lithium-ion batteries. J. Power Sources 77, 183–197 (1999).Google Scholar
9.Armand, M. and Tarascon, J.-M.: Building better batteries. Nature 451, 652 (2008).Google Scholar
10.Goodenough, J.B.: Rechargeable batteries: challenges old and new. J. Solid State Electrochem. 16, 2019–2029 (2012).Google Scholar
11.Tsuchida, E., Ohno, H., and Tsunemi, K.: Conduction of lithium ions in polyvinylidene fluoride and its derivatives—I. Electrochim. Acta 28, 591–595 (1983).Google Scholar
12.Alamgir, M. and Abraham, K.M.: Room temperature rechargeable polymer electrolyte batteries. J. Power Sources 54, 40–45 (1995).Google Scholar
13.Tsunemi, K., Ohno, H., and Tsuchida, E.: A mechanism of ionic conduction of poly (vinylidene fluoride)-lithium perchlorate hybrid films. Electrochim. Acta 28, 833–837 (1983).Google Scholar
14.Fauvarque, J.F., Guinot, S., Bouzir, N., Salmon, E., and Penneau, J.F.: Alkaline poly (ethylene oxide) solid polymer electrolytes. Application to nickel secondary batteries. Electrochim. Acta 40, 2449–2453 (1995).Google Scholar
15.Guinot, S., Salmon, E., Penneau, J.F., and Fauvarque, J.F.: A new class of PEO-based SPEs: structure, conductivity and application to alkaline secondary batteries. Electrochim. Acta 43, 1163–1170 (1998).Google Scholar
16.Yang, C.-C.: Polymer Ni–MH battery based on PEO–PVA–KOH polymer electrolyte. J. Power Sources 109, 22–31 (2002).Google Scholar
17.Yang, C.-C. and Lin, S.-J.: Alkaline composite PEO–PVA–glass-fibre-mat polymer electrolyte for Zn–air battery. J. Power Sources 112, 497–503 (2002).Google Scholar
18.Gilbert, M.: Crystallinity in poly (vinyl chloride). J. Macromol. Sci. Part C: Polym. Rev. 34, 77–135 (1994).Google Scholar
19.Awadhia, A., Patel, S.K., and Agrawal, S.L.: Dielectric investigations in PVA based gel electrolytes. Prog. Cryst. Growth Charact. Mater. 52, 61–68 (2006).Google Scholar
20.Patel, S.K., Awadhia, A., and Agrawal, S.L.: Thermal and electrical studies on composite gel electrolyte system: PEG–PVA–(NH4CH2CO2)2. Phase Transit. 82, 421–432 (2009).Google Scholar
21.Ueberschlag, P.: PVDF piezoelectric polymer. Sens. Rev. 21, 118–126 (2001).Google Scholar
22.Park, J., Park, M., Nam, G., Lee, J.S., and Cho, J.: All-solid-state cable-type flexible Zinc–Air battery. Adv. Mater. 27, 1396–1401 (2015).Google Scholar
23.Fenton, D.E.: Complexes of alkali metal ions with poly (ethylene oxide). Polymer 14, 589 (1973).Google Scholar
24.Wright, P.V.: Electrical conductivity in ionic complexes of poly (ethylene oxide). Br. Polym. J. 7, 319–327 (1975).Google Scholar
25.Armand, M.B., Chabagno, J.M., and Duclot, M.J..: Fast ion transport in solids, edited by Vashishta, P., Mundy, J.N. and Shenoy, G.K., Electrode and electrolytes conference, Materials Science (B2400): United States 23, 771 (1979).Google Scholar
26.Iwakura, C., Nohara, S., Furukawa, N., and Inoue, H.: The possible use of polymer gel electrolytes in nickel/metal hydride battery. Solid State Ionics 148, 487–492 (2002).Google Scholar
27.Wu, G.M., Lin, S.J., and Yang, C.C.: Preparation and characterization of PVA/PAA membranes for solid polymer electrolytes. J. Membr. Sci. 275, 127–133 (2006).Google Scholar
28.Wu, G.M., Lin, S.J., and Yang, C.C.: Alkaline Zn-air and Al-air cells based on novel solid PVA/PAA polymer electrolyte membranes. J. Membr. Sci. 280, 802–808 (2006).Google Scholar
29.Lewandowski, A., Skorupska, K., and Malinska, J.: Novel poly (vinyl alcohol)–KOH–H2O alkaline polymer electrolyte. Solid State Ionics 133, 265–271 (2000).Google Scholar
30.Girish Kumar, G. and Sampath, S.: Electrochemical characterization of poly (vinylidenefluoride)-zinc triflate gel polymer electrolyte and its application in solid-state zinc batteries. Solid State Ionics 160, 289–300 (2003).Google Scholar
31.Poosapati, A., Jang, E., Madan, D., Jang, N., Hu, L., and Lan, Y.: Cellulose hydrogel as a flexible gel electrolyte layer. MRS. Commun. 9, 1–7 (2019).Google Scholar
32.Zhu, H., Fang, Z., Preston, C., Li, Y., and Hu, L.: Transparent paper: fabrications, properties, and device applications. Energy Environ. Sci. 7, 269–287 (2014).Google Scholar
33.Zhu, H., Luo, W., Ciesielski, P.N., Fang, Z., Zhu, J.Y., Henriksson, G., and Hu, L.: Wood-derived materials for green electronics, biological devices, and energy applications. Chem. Rev. 116, 9305–9374 (2016).Google Scholar
34.Agrawal, S.L. and Shukla, P.K..: Structural and electrical characterisation of polymeric electrolytes: PVA-NH 4 SCN system. (2000).Google Scholar
35.Shukla, P.K. and Agrawal, S.L.: Effect of PVAc dispersal into PVA-NH 4 SCN polymer electrolyte. Ionics 6, 312–320 (2000).Google Scholar
36.Chang, W.H., Chang, Y., Lai, P.H., and Sung, H.W.: A genipin-crosslinked gelatin membrane as wound-dressing material: in vitro and in vivo studies. J. Biomater. Sci., Polym. Ed. 14, 481–495 (2003).Google Scholar
37.Toyoshima, K.: Polyvinyl Alcohol-Properties and Applications (John Wiley & Sons, Bristol, Great Britain, 1973), pp. 340–389.Google Scholar
38.Pal, K., Banthia, A.K., and Majumdar, D.K.: Preparation and characterization of polyvinyl alcohol-gelatin hydrogel membranes for biomedical applications. AAPS PharmSciTech. 8, E142–E146 (2007).Google Scholar
39.Mohamad, A.A., Mohamed, N.S., Yahya, M.Z.A., Othman, R., Ramesh, S., Alias, Y., and Arof, A.K.: Ionic conductivity studies of poly (vinyl alcohol) alkaline solid polymer electrolyte and its use in nickel–zinc cells. Solid State Ionics 156, 171–177 (2003).Google Scholar
40.Wang, Z., Wu, Z., Bramnik, N., and Mitra, S.: Fabrication of high-performance flexible alkaline batteries by implementing multiwalled carbon nanotubes and copolymer separator. Adv. Mater. 26, 970–976 (2014).Google Scholar
41.Agrawal, S.L. and Shukla, P.K.: Dielectric studies on PVA–NH4SCN complexes. Physica Status Solidi (a) 163, 247–254 (1997).Google Scholar
42.Patel, S.K., Patel, R.B., Awadhia, A., Chand, N., and Agrawal, S.L.: Role of polyvinyl alcohol in the conductivity behaviour of polyethylene glycol-based composite gel electrolytes. Pramana 69, 467–475 (2007).Google Scholar
43.Dash, R., Marcus, F., and Arthur, J.R.: Improving the mechanical and thermal properties of gelatin hydrogels cross-linked by cellulose nanowhiskers. Carbohydr. Polym. 91, 638–645 (2013).Google Scholar