Hostname: page-component-848d4c4894-p2v8j Total loading time: 0 Render date: 2024-04-30T18:45:44.924Z Has data issue: false hasContentIssue false
  • English
  • Français

Overview on Energetic Polymers

Published online by Cambridge University Press:  10 February 2011

Jacques Boileau
Jacques Boileau*
Affiliation:
Scientific Expert – Direction de la Recherche et de la Technologie (DRET) Délégation Générale pour l'Armement – Paris – France
Get access

Abstract

Energetic materials for missiles, gun munitions or pyrotechnic devices often are mixtures in a biphasic form, with a filler and a binder. To satisfy the user needs, an analysis of functional requirements together with constraints (safety, vulnerability, ageing, environment, disposal, price...) is useful to choose a convenient binder. From this point of view numerous synthetic energetic polymers proposed or developed as binders are reviewed with regard to their syntheses, processing, properties and possible uses. These polymers contain explosophore groups: C-NO2 aliphatic or aromatic, ONO2, NNO2, NF2 and N3.

Some research projects are suggested. Among them in the list of published polymers, following a NIMIC (NATO) suggestion, note the reason of a development interruption. Some dinitropolystyrene – polyvinyl nitrate mixtures or copolymers could exhibit interesting properties. For unknown reasons, some mixtures of crystalline filler- with polymeric binder, generally in a biphasic form, may also be monophasic for a same composition. What properties are modified between the both forms (e.g. combustion mechanisms, erosion, ideal character of the detonation) ? It is also interesting to pursue into a newly open route to thermo-plastic elastomers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 418: Symposium GG – Decomposition, Combustion, and Detonation Chemistry of Energetic Materials , 1995 , 91
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 - Decore, J. M.. Internat – Défense et Technologie (Sept. 1994) (Connection International Publishers – Brussels) p. 16–20; R. S. Miller, pp. 21–27.Google Scholar
2 - Sanderson, A., Kernen, P., Stokes, B., Fitzgerald-Smith, J.. Proceedings of the 1994 NIMIC Workshop (NATO) (22 – 24 June) Brussels – p. 15–44.Google Scholar
3 - Défourneaux, M. – 25 th Intern. Ann. Conf. ICT 1994 p. 2/1–14.Google Scholar
4 - Hoffman, D. M., Hawkins, T. W., Lindsay, G. A., Wardle, R. B., Manser, G. E. – Life Cycle of Energetic Materials – Conf. Dec. 1994 – Proceedings p. 75–90; L. F. Cannizzo, R. B. Wardle, R. S. Hamilton, W. W. Edwards – Ibid pp. 221–225.Google Scholar
5 - Davenas, A. (Ed.), Solid Rocket Propulsion Technology – Pergamon Press – Oxford, New-York (1992).Google Scholar
6 - Klager, K. – 13 th Int. Ann. Conf. ICT 1982, p. 11–30, L. R. Rothstein, pp. 245–256.Google Scholar
7 - Frankel, M. B., Grant, L. R., Flanagan, J. E. – J. Prop. Power 8 (3) 560–3 (1992).Google Scholar
8- Colclough, M. E., Desai, H., Millar, R. W., Paul, N. C., Stewart, M. J., Golding, P., Polym. Advanced Technology 5 554–560 (1994).Google Scholar
9 - Mevrel, R., Poulard, S., Dumiel, J., Vignollet, M. – Rheol. Acta 13 (2) 318–22 (1974).Google Scholar
10 - Reed, R., Brady, V. – ADPA – Proceedings of Joint Int. Symp. 22–24 April 1991 San Diego p. 492–500 Google Scholar
11- Stacer, R. G., Husband, D. M., Prop. Expl. Pyro. 16 167–176 (1991).Google Scholar
12- Mishra, I., Kieft, L. J. van de – 19 th Int. Ann. Conf. ICT 1988, 25/2–9Google Scholar
13- Kalnins, K., Kutsenko, A. D., Kirsh, Yu E., Barba, N. A., Korzh, I. D. – Vysokce.ol. Soedin. Ser. A 32 (6) 1268–75 (1990) – CA 113 132878 f.Google Scholar
14- Pujo, A.M., Boileau, J., Lang, F. M. – Mém Poudres 35 41–50 (1953)Google Scholar
15- Boileau, J. Leneve, L.u (SNPE), French Patent N° 2658505 (21.02.1990).Google Scholar
16 - Redecker, K. H., Hage!, R. – 18 th Int. Ann. Conf. ICT 1987 p. 26/1–10; Prop. Expl. Pyro. 12 196–201 (1987).Google Scholar
17- Berger, B., Haas, B., Reinhard, G. – 26 th Int. Ann. Conf. ICT 1995 p. 2/1–14.Google Scholar
18- Oinuma, S. – Tokyo Kogyo Shik. Hokoku 65 (2) 52–6 (1970) – C. A. 74 141409eGoogle Scholar
19- Pujo, A.M., Boileau, J., Mem Poudres 37, 35–48 (1955).Google Scholar
20- Diepold, W., Explosivst. 18 2 (1970).Google Scholar
21- Urbanski, T. – Chemistry and Technology of Explosives – Pergamon Preas New York. II, (1965) p. 173–4; IV (1984) p. 413–21.Google Scholar
22- Backof, E.- 12 th Int. Ann. Conf. ICT 1981 p. 67–84.Google Scholar
23- Strecker, R.A., Vanderame, F. D. – US Pat 3965081 (22/06/1976).Google Scholar
24- Messina, N.A., Ingram, L. S., Konig, G. F., Summerfield, M., Crawford, W. – Report 1987 PCRL – FR – 87004 – AD – 184178 – CA 108 223920 z.Google Scholar
25- Marans, N.S., Zelinski, R. P. – JACS 72 5330 (1950).Google Scholar
26- Gilbert, E.E. US Pat. 4839420 (13/06/89) – CA 11 15 7031u.Google Scholar
27- Hamel, E.E. – 13 th Int. Ann. Conf. ICT 1982 p. 69–84.Google Scholar
28- Dobratz, B., LLNL Explosives Handbook UCRL 52997 – 16/03/1981.Google Scholar
29- Piteau, M., Becuwe, A., Finck, B. – ADPA Int. Meeting San Diego (22 – 24/04/1991) Proceedings p. 69–79.Google Scholar
30- Adolph, H.G., Cason, D. M.-SmithUS Pat. 5266675 (30/11/1993).Google Scholar
31- Frankel, M.B., Witucki, E. F. (Rockwell), US Pat 3832390 (27/08/1974).Google Scholar
32- Price, R.M. – US Pat – 3781252 (25/12/1973); US Pat 3829336 (27/08/1974).Google Scholar
33- Zhirong, Jiang, Guilin, Xu, Yuanfa, Chen – 21 st Int. Ann. Conf. ICT 1990 p. 52/1–6.Google Scholar
34- Scott, B.A., Koch, L. E.US Pat 5092944 (03/03/1992).Google Scholar
35- Millar, R.W., Colclough, M. E., Golding, P., Honey, P. J., Paul, N. C., Sanderson, A.J., Stewart, M. J., Phil. Tran. R. Soc. London A. 339 305–19 (1992) (Edited by Field, J. E. and Gray, P.).Google Scholar
36- Ahad, E. – 21 st Int. Ann. Conf. ICT 1990, p. 5/1–13; E. Ahad and 15 coil. – 24 th” Int. Ann. Conf. ICT 1993 p. 75/1–12.Google Scholar
37- Frankel, M. B., Grant, L. R., Flanagan, J. E., J. Prop. Flame 8 (3) 560–3 (1992).Google Scholar
38- Nazare, AA. N., Asthana, S. N., Singh, H., J. Energ. Mat. 10 43–63 (1992).Google Scholar
39- Kubota, N., Sonobe, T. – 19 th. Int. Ann. Conf. ICT 1988 p. 2/1–12; Nakashita, G., Kubota, N., Prop. Exp. Pyro. 16 177–81 (1991).Google Scholar
40- Kubota, N. – 6e Congres Internat. de Pyrotechnie – 5–9 June 1995 Tours (France). Proceedings p. 13–17.Google Scholar
41- Schedlbauer, F., Prop. Expl. Pyro 17 164–71 (1992).Google Scholar
42- Keicher, T., Wasmann, F. W. – Prop. Expl. Pyro. 17 182–4 (1992).Google Scholar
43- Manser, G. E. (Aerojet), 21 st Int. Ann. Conf. ICT (1990) p. 50/1–13.Google Scholar
44- Cheun, Young-Gu, Kim, Jin-Seuh, Jo, Byung-Wook (South Korea), 25 th Int. Ann. Conf. ICT (1994) p. 71/1–14.Google Scholar
45- Liu, Ying-Ling, Hsine, Ging-Ho, Chiu, Yie-Shun (Taiwan), J. Appl. Polym. Sci. 58 579–86 (1995).Google Scholar
46- Chen, J. K., Brill, T. B., Comb. Flame 87 157–168 (1991); T. B. Brill, Chemistry in Britain Jan. 1993 p. 34–36.Google Scholar
47- Manser, G., Malik, A., Archibald, T. – Patent PCT. 17/03/1994. C. A. 122 P 82365x; T. Archilbald, R. Carlson, A. Malik, G. Manser, US Pat. 5362848 (08/11/1994).Google Scholar
48- Wardle, R. B., Hinshaw, J. H., Edwards, W. W., Joint Int. Symp. ADPA 22–24 April 1991. San Diego. Proceedings p. 89–96.Google Scholar
49- Cannizzo, L. F., Wardle, R. B., Hamilton, R. S., Edwards, W. W., Life Cycles of Energ. Mat. 1994 Conf. Del Mar. Proceedings p. 221–225.Google Scholar
50- Parthiban, S., Raghunandan, B. N., Jain, S. R., Def. Sci. J. 42 (3) 147–156 (1992).Google Scholar