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Liquid Chromatography and Raman Scattering Spectroscopy Measurements of Lead-Iron Phosphate Glasses

Published online by Cambridge University Press:  25 February 2011

B. C. Sales ,
R. S. Ramsey ,
J. B. Bates  and
L. A. Boatner
B. C. Sales
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831
R. S. Ramsey
Affiliation:
Analytical Chemistry Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831
J. B. Bates
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831
L. A. Boatner
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831
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Due to the limited amount of structural information that can be obtained using traditional techniques of solid state physics (e.g., x-ray or neutron diffraction), the structure of oxide glasses has remained a controversial topic since the introduction of the “random network theory” in 1932. While there are several experimental methods that can provide detailed information about the local structural properties of glasses (e.g., NMR, EXAFS, optical absorption, Mössbauer absorption, and EPR spectroscopy), very little information is available regarding the distribution of intermediate size (∼10–500 Å) structural units.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 61: Symposium P – Defects in Glasses , 1985 , 455
Copyright
Copyright © Materials Research Society 1986

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References

[1] Zachariasen, W., J. Am. Chem. Soc. 54, 3841 (1932).CrossRefGoogle Scholar
[2] Bray, P., The Structure of Glass, Vol. 7, E. ed., Porai-Koshits, E. (Consultant Bureau, New York, 1966).Google Scholar
[3] Greaves, G.N., J. Non-Crystalline Solids 71, 203 (1985).Google Scholar
[4] Paul, A., Chemistry of Glasses (Chapman and Hall, New York, 1982) p.204.Google Scholar
[5] Coey, J.M.D., J. de Phys. 35, C6–89 (1974).Google Scholar
[6] Griscom, D. L., J. Non-Crystalline Solids 40, 211 (1980).CrossRefGoogle Scholar
[7] Biscoe, J., Pincus, A., Smith, C. Jr., and Warren, B., J. Amer. Ceram. Soc. 24, 116 (1941).CrossRefGoogle Scholar
[8] Wignall, G., Rothon, R., Longmann, G., and Woodward, G., J. Mater. Sci. 12, 1039 (1977).Google Scholar
[9] Pauling, L., General Chemistry, (Freeman, San Francisco 1970) p. 501.Google Scholar
[10] Wazer, J.R. Van, Phosphorus and Its Compounds: Chemistry, Vol.1, (Interscience Publishers Inc., New York 1958) p. 754.Google Scholar
[11] Wazer, J.R. Van and Holst, K.A., J. Amer. Chem. Soc. 72, 639 (1950).CrossRefGoogle Scholar
[12] Westman, A.E.R. and Gartaganis, P.A., J. Amer. Cer. Soc. 40, 293 (1957).Google Scholar
[13] Meadowcroft, T.R. and Richardson, F.D., Trans. Farad. Soc. 61, 54 (1965).Google Scholar
[14] Sales, B.C., Abraham, M.M., Bates, J.B., and Boatner, L.A., J. Non-Crystalline Solids 71, 103 (1985).Google Scholar
[15] Sales, B.C. and Boatner, L.A., Science 226, 45 (1984).Google Scholar
[16] Sales, B.C. and Boatner, L.A., J. Non-Crystalline Solids - in press.Google Scholar
[17] Sales, B.C. and Boatner, L.A., ORNL Report 6168, Physical and Chemical Characteristics of Lead-Iron Phosphate Nuclear Waste Classes, Oak Ridge National Laboratory, Oak Ridge, TN 37831, May 1985.Google Scholar
[18] Brazell, R.S., Holmberg, R.W., and Moneyhun, J.H., J. Chromatogr. 290, 163 (1984).Google Scholar
[19] Brazell, R.S., in Advances in Chromatography, ed. J. Calvin Giddings, Marcell-Dekker Inc., N.Y. - in press.Google Scholar
[20] Hirai, Y., Yoza, N., and Ohashi, S., Chem. Lett. 499 (1980).Google Scholar
[21] Bates, J.B., Frech, R., Engstrom, H., Wang, J.C., and Kaneda, T., Solid State Ionics 1, 15 (1980).CrossRefGoogle Scholar
[22] Bates, J.B., Kaneda, T., Wang, J.C., and Engstrom, H., J. Chem. Phys. 73, 1503 (1980).Google Scholar
[23] Bunker, B.C., Arnold, G.W., and Wilder, J.A., J. Non-Crystalline Solids 64, 291 (1984).CrossRefGoogle Scholar
[24] Brixner, L.H. and Foris, C.M., J. Solid State Chem. 7, 149 (1973).CrossRefGoogle Scholar
[25] Argyle, J.F. and Hummel, F.A., J. Amer. Ceram. Soc. 43, 452 (1960).CrossRefGoogle Scholar
[26] Mullica, D.F., Perkins, H.O., Grossie, D.A., Boatner, L.A., and Sales, B.C., J. Solid State Chem. - in press.Google Scholar
[27] Parks, J.R. and Wazer, J.R. Van, J. Am. Chem. Soc. 79 4890 (1957).Google Scholar
[28] Nelson, B.N. and Exarhos, G.J., J. Chem. Phys. 71, 27739 (1979).Google Scholar
[29] Rouse, G.B. Jr., Miller, P.J., and Risen, W.M. Jr., J. Non-Crystalline Solids 28, 193 (1978).Google Scholar
[30] Bobovich, Y.S., Opt. Spectros. USSR 13, 274 (1962).Google Scholar
[31] Bues, W. and Gehrke, H.W., Z. Anorg. All. Chem. 288, 291 (1956); 307.Google Scholar
[32] Sales, B.C., Ramsey, R.S., Bates, J.B., and Boatner, L.A. - to be published.Google Scholar