A high-precision calibration curve, derived from the radiocarbon age determinations of 195 decade samples spanning the AD 1 to 1950 interval, is presented.

Though derived for the Pacific Northwest and California, the curve can be used for a large part of the northern hemisphere. This is proven by the radiocarbon ages of contemporaneous sample pairs which are, in most instances, identical within the quoted precision. Two sets of single-year data reveal no evidence for an 11-year cycle with an amplitude beyond the 12-year measuring precision. This indicates that the calibration curve is also applicable for single-year 14C samples.

Analysis of the Seattle data sets and comparison with those published by the Belfast, La Jolla, and Heidelberg laboratories show that the total variability in a radiocarbon age determination is often larger than that predicted from the quoted errors. Upper limits for the error multiplier (ie, the factor with which the quoted error has to be multiplied to obtain the overall laboratory variability) are estimated at 1.5 for Seattle and Belfast, 1.1 to 1.4 for La Jolla, and 2.0 for Heidelberg.

The comparisons with Belfast, La Jolla, and Heidelberg also reveal offsets with the Seattle calibration curve of, respectively, 4, 27 to 55, and 58 years. These offsets are most likely due to laboratory bias. An improvement of the present calibration curve by combining data sets from other laboratories will only be possible when offsets and error multipliers are precisely known through interlaboratory calibration.

Radiocarbon dating with accelerators requires the manufacture of suitable carbon targets. Carbon yield and 13C fractionation were investigated for the simple and direct pyrolysis of wood and cellulose to charcoal. Under continuous vacuum removal of evolved volatiles, carbon yields of 35 to 40% and δ13C fractionation of −2.5‰ were observed in the pyrolysis of wood to charcoal, whereas yields of 30% and fractionation of −0.8‰ were obtained in the pyrolysis of cellulose to charcoal. Yield and fractionation leveled off at temperatures above 300°C. Yields and fractionations were also measured for pyrolysis of wood and cellulose in a continously-flowing argon atmosphere. Yields were higher and fractionations smaller than for the corresponding vacuum cases. For cellulose sealed in evacuated glass tubes and pyrolized at 550 to 600°C, carbon yields greater than 60% and fractionation of about −0.5‰ were observed. Yields increased and fractionation tended to decrease as the ratio of tube volume/mass of cellulose decreased, ie, as the pressure increased. Reheating of this charcoal under continuous vacuum pumping revealed no loss of mass and no alteration of carbon isotopic composition. Fractionation measurements were additionally performed on wood and the charcoal produced from burning in a fireplace, conditions approximating the “natural“ production of charcoal. Despite the large potential fractionation suggested in the wood pyrolysis experiments, charcoal produced in the fireplace showed very small or no fractionation.

During the last seven years, there has been a concerted effort in eastern Australia to obtain 14C ages from detrital shell samples of prograded sand barriers composed of beach ridges and chenier deposits (Cook and Polach, 1973; Cook and Mayo, 1977; Thom, Polach, and Bowman, 1978; Thom et al, 1981). These ages were used to establish the age sequence of deposition and rates of progradation. This date list is the result of work in two areas of the Gulf of Carpentaria, Queensland, Australia, where 57 shell samples were collected for 14C dating. For details of this research, see Rhodes et al (1980).

The radiocarbon dates reported in this date list cover the measurements carried out in 1979 to 1980. Chemical and counting procedures are the same as reported earlier (R, 1978, v 20, p 398–404). Age calculations are based on the conventional 14C half-life (5570 yr) and on the contemporary value of 95% of the activity of NBS oxalic acid. Errors quoted correspond to 1σ value which takes into account the counting statistics, the uncertainty in the half-life, and the instability of the counting system. The ages are not corrected for isotopic fractionation in nature.

This list reports a portion of the analysis completed on archaeologic and paleo-environmental samples measured in the UCR laboratory between August 1974 and August 1976. Results of measurements made during that period on sample suites which are not as yet completed or lack review by submitters will be reported in a subsequent date list.

The radiocarbon dating laboratory is part of the Department of Earth Sciences, University of Waterloo. The natural level radio-isotope facility, built in the spring of 1974, was built primarily for dating groundwater and a combustion line for organic samples was added in 1975.

Procedures and equipment have been described in previous date lists. Except as otherwise indicated, wood, charcoal and peat samples are pretreated with dilute NaOH–Na4P2O7 and dilute H3PO4 before conversion to the counting gas methane; marls and lake cores are treated with acid only. Very calcareous materials are treated with HCl instead of H3PO4. Pretreatment of bone varies with the condition of the bone sample, solid bone with little deterioration is first cleaned manually and ultrasonically. The bone is treated with 8% HCl for 15 minutes, then dilute NaOH–Na4P2O7 for 3 hours at room temperature, washed until neutral, and the collagen extracted by Longin's method (Longin, 1971). Charred bone is treated with dilute HCl, NaOH–Na4PO7, and then dilute HCl again.