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Droplet settling on solids coated with a soft layer

Published online by Cambridge University Press:  18 January 2022

Stéphane Poulain
Affiliation:
Department of Mathematics, Mechanics Division, University of Oslo, N-0851 Oslo, Norway
Andreas Carlson*
Affiliation:
Department of Mathematics, Mechanics Division, University of Oslo, N-0851 Oslo, Norway
*
Email address for correspondence: acarlson@math.uio.no

Abstract

Gravitational settling of a droplet in air onto a soft substrate is a ubiquitous event relevant to many natural processes and engineering applications. We study this phenomenon by developing a three-phase lubrication model of droplet settling onto a solid substrate coated by a thin soft layer represented by a viscous film, an elastic compressible layer and an elastic sheet supported by a viscous film. By combining scaling analysis, analytical methods and numerical simulations we elucidate how the resulting droplet dynamics is affected by the nature of the soft layer. We show that these soft layers can significantly affect the droplet shape during gravitational settling. When there is a linear response of the deformations of the soft layer, the air layer takes longer to drain as compared with the case of a droplet settling onto a rigid substrate. Our results provide new insight into the coupled interactions between droplets and solids coated by a thin film of a soft material.

Information

Type
JFM Papers
Creative Commons
Creative Common License - CCCreative Common License - BY
This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright
© The Author(s), 2022. Published by Cambridge University Press
Figure 0

Figure 1. (a) Schematic of a droplet of radius $a^\star$, density $\rho _1$, viscosity $\mu_1$, surface tension coefficient $\sigma _1$, suspended in a fluid at rest (typically air) of density $\rho _2$, viscosity $\mu_2$ and settling on a soft material under the influence of the gravity field $-g\boldsymbol {e}_z$. Deformations are not to scale. The inset shows the definition of the droplet profile $h_1^\star (r^\star,t^\star )$, the profile of the soft material $h_2^\star (r^\star,t^\star )$ and the thickness of the air layer $H^\star (r^\star,t^\star )=h_1^\star (r^\star,t^\star )-h_2^\star (r^\star,t^\star )$ between the two. We consider three different soft substrates: (b) a compressible Hookean solid characterized by its Lamé coefficients $G$ and $\lambda$; (c) a thin viscous film with surface tension coefficient $\sigma _3$; (d) an elastic sheet with thickness $d^\star$, Young's modulus $E$, and Poisson's ratio $\nu$, giving a bending stiffness $B=Ed^{\star 3}/12(1-\nu ^2)$. In all cases the height of the undeformed soft layer is $h_s^\star$, and for (c,d) the liquid film has a viscosity $\mu_3$. The dimensional heights denoted by stars ()$^\star$ are non-dimensionalized with the initial air layer thickness at $r^\star =0, H_0^\star$, whilst the radial coordinate $r^\star$ is non-dimensionalized with $(H_0^\star a^\star )^{1/2}$. The dimensional time $t^\star$ is non-dimensionalized with $t_0^\star =\mu_2/{\rm \Delta} \rho g a^\star$.

Figure 1

Table 1. Dimensionless numbers characterizing the settling of a droplet on soft layers. We consider a compressible elastic layer, a viscous liquid film (viscous film, capillary) and an elastic sheet supported by a viscous film (viscous film, elastic). The last column indicates the range of values used in our numerical simulations.

Figure 2

Figure 2. Results from a simulation of (2.1) for droplet settling on a rigid substrate, with $\delta =0.05$. (a) Droplet profile at $t=50$, 150, 400, 1000 and 20 000 in the dimple. The expected dimple radius is $r_d=(2\delta /3)^{1/2}\simeq 0.18$. (b) Evolution of the height at the axis of symmetry, $H(0,t)$, and of the minimum height, $H_{min}(t)$. (c) Profiles of the pressure in the air layer at $t=10$, 100, 1000 and 10000. The dotted profile represents a uniform pressure $2/\delta$ over a region of size $r_d$. The inset shows the time evolution of the pressure at $r=0$, with the dotted lined representing the asymptotic value $2/\delta$.

Figure 3

Figure 3. Profiles of the droplet, $h_1(r,t)$, and of the compressible elastic layer $h_2(r,t)$, at $t=1000$ and with $\delta =0.05$ and (a) $\eta =10^{-5}$, (b) $\eta =10^{-3}$. The initial height of the elastic layer, $h_s$, is only significant in the definition of $\eta$ (3.1b) and $h_2(r,t)$ is translated in the figures so that it is 0 in its undeformed state.

Figure 4

Figure 4. Air layer dynamics during a droplet settling onto a thin compressible elastic layer. (a,b) Time evolution of the air layer thickness $H$ at $r=0$ (a) and at its minimum value (b), for $\delta =0.05$ and $\eta =10^{-7}, 10^{-5}, 10^{-3}, 10^{-1}$. (c) Radius of the neck, $r_{neck}(t)={\rm argmin}_r[H(r,t)]$ at $t=10^3$. (d) Pressure profile in the air layer at $t=10^3$. Solid lines represent the numerical results, the dotted line are the profiles $p_2(r,t)=2/\sqrt {3\eta }-r^2/2\eta$ derived in the text assuming the dynamics is dominated by the elasticity of the compressible layer. The inset shows the pressure at $r=0$ and at the same time for various values of $\eta$.

Figure 5

Figure 5. (a) Deformation profiles of a viscous film under an external load for $\hat {t}=10^{-1}, 10, 10^{3}$ and $10^{7}$ in the linear limit, using an initially flat profile and a confined uniform load defined numerically as $\hat {p}_e(\hat {r})=p_0(1+\text{erf}[c(1-\hat {r})])$ with $c=50, \text{erf}$ the error function, $p_0$ chosen such that $\int _{\mathbb {R}^+} 2{\rm \pi} p_e(\hat {r}) \hat {r}\, {\rm d}\hat {r}=1$. (b,c) Evolution at the axis of symmetry ($\hat {r}=0$) of the (b) height and (c) pressure from simulations of the nonlinear evolution equation (4.5).

Figure 6

Figure 6. Height evolution of the coated liquid film for a droplet settling with $\delta =0.05$. Pressure (a) and deformation (b) of the liquid film at the axis of symmetry ($r=0$) for $\delta =0.05, \lambda =10^{-5}$ with $h_s=0.1, \xi =0.2, 0.05, 0.01$ and $h_s=1, \xi =0.2$, corresponding to $\beta =8.4, 2.1, 0.4$ and 0.8, respectively. (c) Normalized deformation of coated the liquid film shown here for $\lambda =10^{-5}, h_s=0.1, \xi =0.2$, corresponding to $\beta =0.8$, and at times $t=10^2, 10^3, 10^4$ and $10^5$.

Figure 7

Figure 7. Evolution of the air layer for the settling of a droplet with $\delta =0.05$ on a viscous liquid film. (a) Profiles for $\xi =0.2, h_s=1, \lambda =10^{-5}$ of the droplet $h_1(r,t)$ and the liquid film $h_2(r,t)$ at $t=5000$. (b) Air film profile $H(r,t)=h_1(r,t)-h_2(r,t)$ for $\xi =0.05, h_s=1, \lambda =10^{-5}$ at $t=50, 10^2, 10^3, 10^4$ and $10^5$. The neck is predicted to be located at $r=(2(\delta +\xi )/3)^{1/2}\simeq 0.26$. The inset shows the rescaled neck structure near $r=r_d(t)$ with $\ell (t)=(\delta +\xi )^{1/2} t^{-1/4}$. $(c,d)$ Thickness of the air film at $r=0$ (c) and at its minimum ($d$) for $\delta =0.05, \lambda =10^{-5}$ with $h_s=0.1, \xi =0.2, 0.05, 0.01$ and $h_s=1, \xi =0.2$, corresponding to $\beta _{cap}=8.4, 2.1, 0.4$ and 0.8, respectively.

Figure 8

Figure 8. (a) Interface profile of the air layer thickness for a droplet settling on a viscous liquid film at $t=500,$$10^4$ and $10^5$, for $\xi =0.2, h_s=0.1, \lambda =10^{-3}$. (b) Corresponding pressure profiles in the air layer ($p_2$) and in the liquid film ($p_3$) at $t=10^5$. (c) Interface profile of the air layer thickness for a droplet settling on an elastic sheet supported by a thin viscous layer at $t=10\ 000, 20\ 000$ and $40\ 000$, for $\alpha =10, h_s=1, \lambda =10^{-3}$. (d) Corresponding pressure profiles in the air layer ($p_2$) and in the viscous film ($p_3$) at $t=40\ 000$.

Figure 9

Figure 9. Deformation profile of an elastic sheet supported by viscous fluid and exposed to an external load. (a) Solution of the linear evolution equation (5.3) in cylindrical coordinates for (right panel) a narrow load approaching a Dirac distribution, $p_e(\hat {r})=p_0\exp [-(\hat {r}/a)^2]/\hat {r}$ with $a=1/200$ and (left panel) a confined uniform load, $p_e(\hat {r})=p_0(1+\text{erf}[a(1-\hat {r})])$ with $a=50, \text{erf}$ the error function. In both cases $p_0$ is chosen such that $\int _{\mathbb {R}^+} 2{\rm \pi} p_e(\hat {r}) \hat {r} \,{\rm d}\hat {r}=1$. The rescaled solution converges to the self-similar solution (5.5a,b), and faster for the narrow load (right) than for the distributed one (left). (b) Evolution of the deformation at the axis of symmetry ($\hat {r}=0$) from the nonlinear evolution equation (5.2) and for a confined uniform load.

Figure 10

Figure 10. Deformations of an elastic sheet supported by a viscous layer for a droplet settling with $\delta =0.05$. (a) Normalized deformation of the elastic sheet, shown here for $\lambda =10^{-5}, h_s=10$, and (left panel) $\alpha =1$, (right panel) $\alpha =10$. (b) Deformation of the elastic sheet at the axis of symmetry ($r=0$) for $\lambda =10^{-5}$ and various values of $\alpha$ and $h_s$, leading to different values of $\beta _{el}$.

Figure 11

Figure 11. Evolution of the air layer thickness for a droplet settling on an elastic sheet with $\delta =0.05$. (a) Profiles for $\alpha =1, h_s=1, \lambda =10^{-3}$ of the droplet $h_1(r,t)$ and the viscous film $h_2(r,t)$ at $t=250$. We note that the thickness of the elastic sheet is not represented to scale for clarity. (b) Profile of the air layer $H(r,t)=h_1(r,t)-h_2(r,t)$ for $\alpha =1, h_s=1, \lambda =10^{-3}$ and $t=250$, 1000, 5000 and $10^5$. (ce) Evolution of the air layer thickness at the axis of symmetry ($r=0$), at its minimum value, and of the dimple radius for $\lambda =10^{-3}, h_s=1$ and $\alpha =0.01, 0.1, 1, 10$. (fh) Likewise for $\alpha =1$ and various values of $\lambda$ and $h_s$ The dashed lines in (d) and (e) show the height and radius at the local minimum corresponding to the dimple neck, for $\alpha =10$ and $t\simeq 10^4$ the minimum radius is not located anymore at the neck.

Figure 12

Figure 12. Evolution of the minimum air layer thickness for droplet deposition on a viscous film and various values of $\xi, \lambda$ and $h_s$. The parameter $\delta$ is set to 0.05. The system of equations solved consists of (2.1b). Equations (4.13) and (2.1c), and either (solid lines) accounting for the full stress balance using (4.1a) and (4.1b), or (dashed lines) using the simplified equations (2.1a) and (4.3).

Figure 13

Figure 13. Evolution of the liquid film height at the axis of symmetry ($r=0$) for droplet deposition on a viscous film and various values of $\xi, \lambda$ and $h_s$. The parameter $\delta$ is set to 0.05. The system of equations solved consists of (2.1b). Equations (4.13) and (2.1c), and either (solid lines) accounting for the full stress balance using (4.1a) and (4.1b), or (dashed lines) using the simplified equations (2.1a) and (4.3).