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A study of temperature and pressure induced structural and electronic changes in SbCl5 intercalated graphite: Part II. Experimental data for c-axis resistivity

Published online by Cambridge University Press:  31 January 2011

O.E. Andersson ,
B. Sundqvist ,
E. McRae ,
J.F. Marêché  and
M. Lelaurain
O.E. Andersson
Affiliation:
Department of Experimental Physics, Umeå University, S-90187 Umeå, Sweden
B. Sundqvist
Affiliation:
Department of Experimental Physics, Umeå University, S-90187 Umeå, Sweden
E. McRae
Affiliation:
Université de Nancy I, Laboratoire de Chimie du Solide Minéral, U.R.A. C.N.R.S. 158, Service de Chimie Minérale Appliquée, B. P. 239, 54506 Vandoeuvre-lès-Nancy Cédex, France
J.F. Marêché
Affiliation:
Université de Nancy I, Laboratoire de Chimie du Solide Minéral, U.R.A. C.N.R.S. 158, Service de Chimie Minérale Appliquée, B. P. 239, 54506 Vandoeuvre-lès-Nancy Cédex, France
M. Lelaurain
Affiliation:
Université de Nancy I, Laboratoire de Chimie du Solide Minéral, U.R.A. C.N.R.S. 158, Service de Chimie Minérale Appliquée, B. P. 239, 54506 Vandoeuvre-lès-Nancy Cédex, France
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Abstract

We present experimental data for the c-axis resistivity ρc of stage s = 2, 3, 4, 5, and 8, SbCl5 intercalated graphite, over the temperature range 40 to 300 K and the pressure range 0 to 0.8 GPa (0–8 kbar). For most specimens studied, resistance anomalies are observed below 230 K at atmospheric pressure and at pressures up to 0.5 GPa at 293 K. These anomalies are explained in terms of structural changes from a disordered or partly crystallized in-plane intercalate structure at atmospheric pressure and T > 230 K to an almost completely crystallized structure below this temperature, or at elevated pressures, as discussed in a companion paper. In the crystallized phases ρc is approximately linear in T except for stage 8, for which a nonlinear behavior, with a negative temperature coefficient of resistivity below 200 K, is observed. The results are compared with previously available literature data, and the p-T phase diagram is briefly discussed.

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Journal of Materials Research , Volume 7 , Issue 11 , November 1992 , pp. 2989 - 3000
Copyright
Copyright © Materials Research Society 1992

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References

1Intercalated Layered Materials, edited by Lévy, F. (D. Reidel, Dordrecht, Holland, 1979).CrossRefGoogle Scholar
2Dresselhaus, M. S. and Dresselhaus, G., Adv. Phys. 30, 139 (1981).CrossRefGoogle Scholar
3Graphite Intercalation Compounds I: Structure and Dynamics, edited by Zabel, H. and Solin, S.A. (Springer-Verlag, Berlin, Germany, 1990).CrossRefGoogle Scholar
4Proc. 5th Int. Symp. on Graphite Intercalation Compounds, Berlin, May 1989, published in Synth. Metals 34 (1989).Google Scholar
5Proc. 6th Int. Symp. on Intercalation Compounds, Orléans, France, May 1991, published in Mater. Sci. Forum 91-93 (1992).Google Scholar
6Vogel, F. L., J. Mater. Sci. 12, 982 (1977)CrossRefGoogle Scholar
Vogel, F. L., Foley, G. M. T., Zeller, C., Falardeau, E. R., and Gan, J., Mater. Sci. Eng. 31, 261 (1977)CrossRefGoogle Scholar
Foley, G.M.T., Zeller, C., Falardeau, E.R., and Vogel, F.L., Solid State Commun. 24, 371 (1977).CrossRefGoogle Scholar
7Lelaurain, M., Marêché, J. F., McRae, E., Andersson, O.E., and Sundqvist, B., J. Mater. Res. 7, pg. 2978 (1992).CrossRefGoogle Scholar
8Wortmann, G., Godler, F., Perscheid, B., Kaindl, G., and Schlogl, R., Synth. Metals 26, 109 (1988).CrossRefGoogle Scholar
9Salamanca-Riba, L., Roth, G., Gibson, J. M., Kortan, A. R., Dresselhaus, G., and Birgenau, R. J., Phys. Rev. B 33, 2738 (1986).CrossRefGoogle Scholar
10Elzinga, M., Morelli, D.T., and Uher, C., Phys. Rev. B 26, 3312 (1982).CrossRefGoogle Scholar
11Blinowski, J., Hau, N. Hy, Rigaux, C., and Vieren, J.P., J. Phys. Soc. Jpn. 49, Suppl. A, 915 (1980).Google Scholar
12Blinowski, J., Hau, N. Hy, Rigaux, C., Vieren, J.P., Toullec, R. Le, Furdin, G., Hérold, A., and Mélin, J., J. Phys. (France) 41, 47 (1980).CrossRefGoogle Scholar
13Takahashi, O., lye, Y., and Tanuma, S., Solid State Commun. 37, 863 (1981).CrossRefGoogle Scholar
14Zaleski, H., Ummat, P.K., and Datars, W.R., J. Phys. C 17, 3167 (1984); ibid., Phys. Rev. B 35, 2958 (1987).Google Scholar
15Wang, G., Zaleski, H., Ummat, P. K., and Datars, W. R., Phys. Rev. B 37, 9029 (1988).CrossRefGoogle Scholar
16Hwang, D.M. and Nicolaides, G., Solid State Commun. 49, 483 (1984).CrossRefGoogle Scholar
17Hwang, D. M., in Intercalated Graphite, edited by Dresselhaus, M. S., Dresselhaus, G., Fischer, J. E., and Moran, M. J. (Mater. Res. Soc. Symp. Proc. 20, Elsevier, New York, 1983), p. 295.Google Scholar
18Groot, K. de, Maurer, D., Müller, V., Geiser, V., and Güntherodt, H J., Synth. Metals 34, 335 (1989).CrossRefGoogle Scholar
19Rolla, S., Walmsley, L., Suematsu, H., Torriani, I., Rettori, C., and Yosida, Y., Solid State Commun. 58, 333 (1986).CrossRefGoogle Scholar
20Clarke, R., Elzinga, M., Gray, J. N., Homma, H., Morelli, D. T., Winokur, M. J., and Uher, C., Phys. Rev. B 26, 5250 (1982).CrossRefGoogle Scholar
21Morelli, D.T. and Uher, C., Phys. Rev. B 27, 2477 (1983).CrossRefGoogle Scholar
22Uher, C. and Morelli, D. T., in Intercalated Graphite, edited by Dresselhaus, M. S., Dresselhaus, G., Fischer, J. E., and Moran, M. J. (Mater. Res. Soc. Symp. Proc. 20, Elsevier, New York, 1983), p. 163.Google Scholar
23Piraux, L., Issi, J P., and Eklund, P. C., Solid State Commun. 56, 413 (1985).CrossRefGoogle Scholar
24Avdeev, V.V., Brandt, N.B., Ionov, S.G., Kuvshinnikov, S.V., Mukhanov, V. A., and Semenenko, K. N., Inorg. Mater. 21, 1065 (1985).Google Scholar
25Bittner, D.N. and Bretz, M., Phys. Rev. B 31, 1060 (1985).CrossRefGoogle Scholar
26Yosida, Y. and Tanuma, S., J. Phys. Soc. Jpn. 54, 650 (1985).CrossRefGoogle Scholar
27Clarke, R. and Uher, C., Adv. Phys. 33, 469 (1984).CrossRefGoogle Scholar
28Houser, B., Homma, H., and Clarke, R., Phys. Rev. B 30, 4802 (1984).CrossRefGoogle Scholar
29Sundqvist, B. and Lundberg, B., J. Phys. C 19, 6915 (1986).Google Scholar
30lye, Y., Takahashi, O., Tanuma, S., Tsuji, K., and Minomura, S., Physica B 105, 185 (1981); ibid., J. Phys. Soc. Jpn. 51, 475 (1982).Google Scholar
31Andersson, G. and Sundqvist, B., Solid State Commun. 65, 735 (1988).CrossRefGoogle Scholar
32Sundqvist, B., Synth. Metals 23, 345 (1988).CrossRefGoogle Scholar
33Andersson, O.E., Lelaurain, M., Marêché, J.F., McRae, E., and Sundqvist, B., Synth. Metals 34, 187 (1989).CrossRefGoogle Scholar
34Andersson, O.E., Lelaurain, M., Marêché, J.F., McRae, E., and Sundqvist, B., Mater. Sci. Forum 91-93, 301 (1992).CrossRefGoogle Scholar
35Syassen, K., Sonnenschein, R., Hanfland, M., and Beister, M. J., Synth. Metals 34, 293 (1989).CrossRefGoogle Scholar
36Alzyab, B., Perry, C.H., Zahopoulos, C., Pringle, O.A., and Nicklow, R.M., Phys. Rev. B 38, 1544 (1988).CrossRefGoogle Scholar
37Andersson, O.E., McRae, E., Sundqvist, B., Marêché, J.F., and Lelaurain, M. (in preparation).Google Scholar
38Andersson, O., Sundqvist, B., and Bäckstrom, G., High Pressure Res. (1992, in press).Google Scholar
39Sundqvist, B., J. Phys. E 20, 984 (1987).Google Scholar
40Spain, I. L., in Physics and Chemistry of Carbon, edited by Walker, P. L. and Thrower, P. A. (Marcel Dekker, New York, 1981), Vol. 16, p. 120.Google Scholar
41Soule, D.E. and McClure, J. W., J. Phys. Chem. Solids 8, 29 (1959).CrossRefGoogle Scholar
42Ono, S., J. Phys. Soc. Jpn. 40, 498 (1976).CrossRefGoogle Scholar
43Kawamura, K., Ouchi, Y., Oshima, H., and Tsuzuku, T., J. Phys. Soc. Jpn. 46, 587 (1979).CrossRefGoogle Scholar
44Tsuzuku, T., Carbon 17, 293 (1979).CrossRefGoogle Scholar
45Uher, C., Hockey, R.L., and Ben-Jacob, E., Phys. Rev. B 35, 4483 (1987).CrossRefGoogle Scholar
46Matsubara, K., Sugihara, K., and Tsuzuku, T., Phys. Rev. B 41, 969 (1990).CrossRefGoogle Scholar
47Bevington, P. R., Data Reduction and Error Analysis for the Physical Sciences (McGraw-Hill, New York, 1969), p. 198.Google Scholar
48Rossiter, P. L., The Electrical Resistivity of Metals and Alloys (Cambridge Univ. Press, Cambridge, U. K., 1987).CrossRefGoogle Scholar
49Onn, D.G., Foley, G.M.T., and Fischer, J.E., Phys. Rev. B 19, 6474 (1979)CrossRefGoogle Scholar
Lundberg, B. and Sundqvist, B., Solid State Commun. 58, 747 (1986).CrossRefGoogle Scholar
50McRae, E. and Marêché, J. F., J. Mater. Res. 3, 75 (1988).CrossRefGoogle Scholar