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Superhydrophobic surfaces with recirculating interfacial flow due to surfactants are ‘effectively’ immobilized

Published online by Cambridge University Press:  30 January 2023

Henry Rodriguez-Broadbent*
Affiliation:
Department of Mathematics, Imperial College London, 180 Queen's Gate, London SW7 2AZ, UK
Darren G. Crowdy
Affiliation:
Department of Mathematics, Imperial College London, 180 Queen's Gate, London SW7 2AZ, UK
*
Email address for correspondence: h.rodriguez-broadbent20@imperial.ac.uk

Abstract

At high surface Péclet numbers, it is common to associate the presence of surfactants with surface immobilization, where a free surface becomes indistinguishable from a no-slip surface. A different mechanism has recently been proposed for longitudinal shear flow along a unidirectional trench (Baier & Hardt, J. Fluid Mech., vol. 949, 2022, A34) wherein, at high Marangoni numbers, the meniscus spanning the finite-length trench becomes a constant-shear-stress surface due to contamination by incompressible surfactant. That model predicts recirculating interfacial flows on the meniscus, a phenomenon that has been observed experimentally (Song et al., Phys. Rev. Fluids, vol. 3, issue 3, 2018, 033303). By finding an explicit solution to the constant-shear-stress model at all protrusion angles and calculating the effective slip length for a dilute mattress of such surfactant-laden trenches, we show that those effective slip lengths are almost indistinguishable from those for a surface whose menisci have the same deflection but have been completely immobilized (i.e. they are no-slip surfaces). This means that, despite the presence of non-trivial recirculating vortical flows on the menisci, the aggregate slip characteristics of such surfaces are that they have been effectively immobilized. This surprising result underscores the need for caution in comparing theory with experiments based on effective slip properties alone.

Information

Type
JFM Rapids
Creative Commons
Creative Common License - CCCreative Common License - BY
This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution and reproduction, provided the original article is properly cited.
Copyright
© The Author(s), 2023. Published by Cambridge University Press
Figure 0

Figure 1. (a) A single trench with a surfactant-contaminated protruding meniscus. (b) The non-dimensional boundary value problem for the longitudinal velocity away from the ends of the trench.

Figure 1

Figure 2. Graph of $\mathcal {C}(\theta )$ against $\theta$. The dashed line shows the small-angle results of Baier & Hardt (2022).

Figure 2

Figure 3. Velocity contours for (a) $\theta =0.2$, (b) $\theta =0.6$, (c) $\theta =-0.2$, (d) $\theta =1.2$ and (e$\theta =-1.2$. Panels (a)–(c) retrieve figures 3(a), 3(c) and 3(d), respectively, of Baier & Hardt (2022). The dotted contour corresponds to $w=0$.

Figure 3

Figure 4. Velocity along the meniscus, $w|_{\mathcal {M}}$, plotted against $x$. Panel (a) replicates figure 4(a) in Baier & Hardt (2022), while panel (b) extends this to menisci with larger protrusion angles. Note that the graphs are multivalued for $\theta >{{\rm \pi} }/{2}$, as the meniscus ‘bulges’ so much that it hangs over the adjacent edge of the no-slip surface.

Figure 4

Figure 5. Normalized effective slip length, $\lambda /(\delta c)$, as a function of $\theta$ assuming no-shear menisci following Crowdy (2010), no-slip menisci and constant-shear-stress menisci. The last two remain close across the range of protrusion angles.